01492naa a2200313 a 450000100080000000500110000800800410001910000200006024500640008026000090014430000170015352005960017065000170076665300190078365300150080265300110081765300220082865300220085065300070087265300160087965300160089570000180091170000220092970000190095170000190097070000170098970000270100677301450103310269511999-12-22       1995    bl uuuu     u00u1 u    #d1 aRIUL JUNIOR, A.  aFabricacao de filmes Langmuir-Blodgett (LB) de polianilina.  c1995  ap.1255-1258.  aUltra-thin films of parent polyaniline were fabricated with the Langmuir-Blodgett technique using the concept of counter-ion-induced processibility. A functionalized acid was used, namely camphor sulfonic acid, in chloroform solutions. The films produced were characterized by ultraviolet-visible spectroscopy, electrical conductivity measurements and ellipsometry. When spread on acid subphases the films are readily obtained in the doped state. The presence of m-cresol promotes secondary doping effects as demonstrated by a lower energy excitonic transition due to polaron delocalization.  aspectroscopy  aEspectroscopia  aFabricacao  aFilmes  afilmes ultrafinos  aLangmuir-Blodgett  aLB  aPolianilina  aPolyaniline1 aTELLES, G. D.1 aMATTOSO, L. H. C.1 aPEREIRA, M. R.1 aTICIANELLI, E.1 aFARIA, R. M.1 aOLIVEIRA JUNIOR, O. N.  tIn: CONGRESSO BRASILEIRO DE POLIMEROS, 3., nov. 1995, Rio de Janeiro, RJ. Anais... Rio de Janeiro: Associacao Brasileira de Polimeros, 1995.