01543naa a2200265 a 450000100080000000500110000800800410001902400560006010000200011624501720013626000090030852006580031765000140097565000140098965000170100365000330102065000100105365000120106365300460107565300260112170000210114770000190116870000180118777300720120521741132025-03-21 2025 bl uuuu u00u1 u #d7 ahttps://doi.org/10.1016/j.ijhydene.2025.03.1312DOI1 aSORTO, J. E. P. aHydrogen-rich syngas from model biogas steam reforming over a Ni–Pr/hydrotalcite-derived catalystbAn RSM-central composite rotational design.h[electronic resource] c2025 aA five-level Central Composite Rotational Design (CCRD 23, with 3 central (0) and six axial points) was performed to optimize hydrogen production via the continuous-flow-steam biogas reforming (SBR) reaction over a nickel-based catalyst, composed of Mg–Al oxides derived from hydrotalcite and containing 10 % of Ni and 1 % of praseodymium. The design included 17 long-term (24 h) runs, from which nonlinear regression models were fitted to the data. Five responses were measured under varying conditions: hydrogen selectivity (Y1), yield (Y2), and concentration at the reactor output (Y3). Also, the H2/CO molar ratio (Y4) and methane conversion (Y5). aBioenergy aCatalysts aHydrotalcite aResponse surface methodology aSteam aBiogás aCentral composite rotatable design (CCRD) aNiMgAlPr mixed oxides1 aMENDONÇA, I. F.1 aSCHULTZ, E. L.1 aSOARES, I. P. tInternational Journal of Hydrogen Energygv. 118, p. 179-194, 2025.