| |
|
|
 | Acesso ao texto completo restrito à biblioteca da Embrapa Instrumentação. Para informações adicionais entre em contato com cnpdia.biblioteca@embrapa.br. |
|
Registro Completo |
|
Biblioteca(s): |
Embrapa Instrumentação. |
|
Data corrente: |
13/10/2020 |
|
Data da última atualização: |
11/12/2024 |
|
Tipo da produção científica: |
Artigo em Periódico Indexado |
|
Autoria: |
BONDANCIA, T. J.; AGUIAR, J.; BATISTA, G.; CRUZ, A. J. G.; MARCONCINI, J. M.; MATTOSO, L. H. C.; FARINAS, C. S. |
|
Afiliação: |
JOSE MANOEL MARCONCINI, CNPDIA; LUIZ HENRIQUE CAPPARELLI MATTOSO, CNPDIA; CRISTIANE SANCHEZ FARINAS, CNPDIA. |
|
Título: |
Production of nanocellulose using citric acid in a biorefinery concept: Effect of the hydrolysis reaction time and techno-economic analysis. |
|
Ano de publicação: |
2020 |
|
Fonte/Imprenta: |
Industrial & Engineering Chemistry Research, v. 59, 2020. |
|
Páginas: |
11505?11516 |
|
DOI: |
https://dx.doi.org/10.1021/acs.iecr.0c01359 |
|
Idioma: |
Inglês |
|
Conteúdo: |
Nanocellulosic materials, either as cellulose nanofibrils (CNF) or cellulose nanocrystals (CNC), have a wide range of potential applications in different industrial sectors, due to their renewable nature and remarkable properties. Here, a sustainable and environmentally friendly method to obtain nanocellulose was evaluated using hydrolysis with citric acid, an organic acid that can be obtained as a biorefinery product. This approach resulted in a single-step extraction of nanocellulose, with carboxyl functionalization of the surface varying according to hydrolysis reaction times from 1.5 to 6 h, at 120°C, as evidenced using NMR to measure the degree of substitution. The charged surface groups of CNC and CNF resulted in improved colloidal stability, with ζ-potential values from −36 to −48 mV. Both CNC and CNF extracted using different reaction times were thermally stable, but the increase of carboxyl groups reduced the degradation temperature. Techno-economic analysis (TEA) showed that the cost of citric acid had the greatest influence on the minimum product selling price (MPSP) of the nanocellulose, indicating that the production of citric acid within the biorefinery could be an interesting way to make this approach feasible. |
|
Palavras-Chave: |
Biorefinery product; Cellulose nanocrystals; Cellulose nanofibrils. |
|
Categoria do assunto: |
-- |
|
Marc: |
LEADER 02089naa a2200253 a 4500
001 2125471
005 2024-12-11
008 2020 bl uuuu u00u1 u #d
024 7 $ahttps://dx.doi.org/10.1021/acs.iecr.0c01359$2DOI
100 1 $aBONDANCIA, T. J.
245 $aProduction of nanocellulose using citric acid in a biorefinery concept$bEffect of the hydrolysis reaction time and techno-economic analysis.$h[electronic resource]
260 $c2020
300 $a11505?11516
520 $aNanocellulosic materials, either as cellulose nanofibrils (CNF) or cellulose nanocrystals (CNC), have a wide range of potential applications in different industrial sectors, due to their renewable nature and remarkable properties. Here, a sustainable and environmentally friendly method to obtain nanocellulose was evaluated using hydrolysis with citric acid, an organic acid that can be obtained as a biorefinery product. This approach resulted in a single-step extraction of nanocellulose, with carboxyl functionalization of the surface varying according to hydrolysis reaction times from 1.5 to 6 h, at 120°C, as evidenced using NMR to measure the degree of substitution. The charged surface groups of CNC and CNF resulted in improved colloidal stability, with ζ-potential values from −36 to −48 mV. Both CNC and CNF extracted using different reaction times were thermally stable, but the increase of carboxyl groups reduced the degradation temperature. Techno-economic analysis (TEA) showed that the cost of citric acid had the greatest influence on the minimum product selling price (MPSP) of the nanocellulose, indicating that the production of citric acid within the biorefinery could be an interesting way to make this approach feasible.
653 $aBiorefinery product
653 $aCellulose nanocrystals
653 $aCellulose nanofibrils
700 1 $aAGUIAR, J.
700 1 $aBATISTA, G.
700 1 $aCRUZ, A. J. G.
700 1 $aMARCONCINI, J. M.
700 1 $aMATTOSO, L. H. C.
700 1 $aFARINAS, C. S.
773 $tIndustrial & Engineering Chemistry Research$gv. 59, 2020.
Download
Esconder MarcMostrar Marc Completo |
|
Registro original: |
Embrapa Instrumentação (CNPDIA) |
|
|
Nenhum exemplar cadastrado para este documento. |
Voltar
|
|
|
| Registros recuperados : 2 | |
| 1. |  | CARVALHO, M. da C. S.; FERRANTE, A. A.; SANTOS, F. C.; ALBUQUERQUE FILHO, M. R. Resposta do algodoeiro irrigado à adubação NPK em sistema plantio direto no Cerrado. In: REUNIÃO BRASILEIRA DE FERTILIDADE DO SOLO E NUTRIÇÃO DE PLANTAS, 28., REUNIÃO BRASILEIRA SOBRE MICORRIZAS, 12., SIMPÓSIO BRASILEIRO DE MICROBIOLOGIA DO SOLO, 10., REUNIÃO BRASILEIRA DE BIOLOGIA DO SOLO, 7., 2008, Londrina, PR. Desafios para o uso do solo com eficiência e qualidade ambiental: anais... Londrina: SBCS: Embrapa Soja, 2008.| Tipo: Artigo em Anais de Congresso / Nota Técnica |
| Biblioteca(s): Embrapa Algodão; Embrapa Cerrados. |
|   |
| 2. | | BASSO, M. F.; CONTALDI, F.; CELSO, F. lo; BARATTO, C. M.; SA, M. F. G. de; BARONE, G.; FERRANTE, A.; MARTINELLI, F. Identification and expression profile of the SMAX/SMXL family genes in chickpea and lentil provide important players of biotechnological interest involved in plant branching. Planta, v. 259, 2024. 1. Na publicação: Maria Fatima Grossi?de?Sa.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Recursos Genéticos e Biotecnologia. |
|  |
| Registros recuperados : 2 | |
|
| Nenhum registro encontrado para a expressão de busca informada. |
|
|
