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| Registros recuperados : 54 | |
| 14. |  | ANDRADE, L. P. de; XAVIER, C. P.; BETONI, V.; KOMORI, O. M.; PADOVAN, M. P. Curso Superior de Tecnologia em Agroecologia em Mato Grosso do Sul: formação de profissionais para harmonizar o desenvolvimento à conservação e melhoria ambiental. In: SEMINÁRIO DE AGROECOLOGIA DE MATO GROSSO DO SUL, 3.; ENCONTRO DE PRODUTORES AGROECOLÓGICOS DE MS, 2., 2010, Corumbá. Construindo um futuro sustentável e solidário: anais. Dourados: Embrapa Agropecuária Oeste; Corumbá: Embrapa Pantanal; Campo Grande: Embrapa Gado de Corte, 2010. Editado por: Milton Parron Padovan, Ivo de Sá Motta, Hamilton Kikuti, Aurélio V. Borsato, Rogério Ferreira da Silva, Adalgiza Inês Campolim, Alzira Salet Menegat, Alberto Faiden. 1 CD-ROM.| Biblioteca(s): Embrapa Agropecuária Oeste. |
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| 16. | | XAVIER, C. E. O.; BRANCO, J. E. H.; CARVALHO, L. B. de; CAIXETA FILHO, J. V. País deve superar gargalos logísticos para ganhar competitividade. Visão Agrícola, Piracicaba, v. 5, n. 8, p. 104-108, jan./jun., 2008.| Biblioteca(s): Embrapa Semiárido. |
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| 20. | | GUIMARÃES, M. J. M.; GOMES JUNIOR, F. de A.; OLIVEIRA, U. da S.; XAVIER, C. S.; COELHO FILHO, M. A. Área foliar de bananeira (MUSA SPP): uma comparação de métodos. In: REUNIÃO ANUAL DE CIÊNCIA, TECNOLOGIA, INOVAÇÃO E CULTURA NO RECÔNCAVO DA BAHIA - RECONCITEC, 2., 2012, Cruz das Almas. Energias Renováveis, Educação, Tecnologia e Sociedade. Cruz das Almas, BA: UFRB, 2012.| Biblioteca(s): Embrapa Mandioca e Fruticultura. |
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Registro Completo
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
20/07/2023 |
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Data da última atualização: |
15/01/2024 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Circulação/Nível: |
A - 4 |
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Autoria: |
XAVIER, C.; LOPES, B. R.; LIMA. C. S.; RIBEIRO, C.; AZEVEDO, E. B. |
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Afiliação: |
University of São Paulo (USP); , Federal University of São Carlos (UFSCar); University of São Paulo (USP); CAUE RIBEIRO DE OLIVEIRA, CNPDIA; University of São Paulo (USP). |
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Título: |
Using a Surface-Response Approach to Optimize the Photocatalytic Activity of rGO/g-C3N4 for Bisphenol A Degradation. |
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Ano de publicação: |
2023 |
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Fonte/Imprenta: |
Catalysts, v. 13, 1069, 2023. |
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Páginas: |
14 p. |
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DOI: |
https://doi.org/10.3390/catal13071069 |
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Idioma: |
Inglês |
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Conteúdo: |
Although environmental and clean energy research has identified graphitic carbon nitride impregnated with reduced graphene oxide (rGO/g-C3N4 ) as a potential, efficient non-metallic photocatalyst, its efficacy against Contaminants of Emerging Concern (CECs) is relatively unknown. This study reports an optimized photocatalyst (response surface methodology, RSM) to remove the plasticizer and endocrine disruptor bisphenol A (BPA) from water. The synthetic procedure included sonication of prepared particles of g-C3N4 and graphite oxide (rGO), followed by reduction with hydrazine (24 h reflux), increasing specific surface areas, and improving synthesis reproducibility. In optimal conditions, the produced photocatalyst (50 mg L?1) removed 90% of BPA (100 mL, 100 µg L−1) in 90 min (30 min in the dark + 60 min irradiated) using a UV source (centered at 365 nm, 26 W) and exhibiting pseudo-first-order kinetics. For comparison purposes, under the same experimental conditions, pure g-C3N4 removed 50% of the BPA solution. Radical scavenging tests identified the superoxide radical as the main reactive oxygen species involved in the degradation. Two major degradation products were identified by mass spectrometry, both of them less ecotoxic than BPA to a variety of test organisms, according to in silico estimations (ECOSAR 2.0). |
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Palavras-Chave: |
G-C3N4; Heterogeneous photocatalysis; RGO. |
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Categoria do assunto: |
-- |
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URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/doc/1155085/1/P-Using-a-Surface-Response-Approach-to-Optimize-the.pdf
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Marc: |
LEADER 02015naa a2200229 a 4500
001 2155085
005 2024-01-15
008 2023 bl uuuu u00u1 u #d
024 7 $ahttps://doi.org/10.3390/catal13071069$2DOI
100 1 $aXAVIER, C.
245 $aUsing a Surface-Response Approach to Optimize the Photocatalytic Activity of rGO/g-C3N4 for Bisphenol A Degradation.$h[electronic resource]
260 $c2023
300 $a14 p.
520 $aAlthough environmental and clean energy research has identified graphitic carbon nitride impregnated with reduced graphene oxide (rGO/g-C3N4 ) as a potential, efficient non-metallic photocatalyst, its efficacy against Contaminants of Emerging Concern (CECs) is relatively unknown. This study reports an optimized photocatalyst (response surface methodology, RSM) to remove the plasticizer and endocrine disruptor bisphenol A (BPA) from water. The synthetic procedure included sonication of prepared particles of g-C3N4 and graphite oxide (rGO), followed by reduction with hydrazine (24 h reflux), increasing specific surface areas, and improving synthesis reproducibility. In optimal conditions, the produced photocatalyst (50 mg L?1) removed 90% of BPA (100 mL, 100 µg L−1) in 90 min (30 min in the dark + 60 min irradiated) using a UV source (centered at 365 nm, 26 W) and exhibiting pseudo-first-order kinetics. For comparison purposes, under the same experimental conditions, pure g-C3N4 removed 50% of the BPA solution. Radical scavenging tests identified the superoxide radical as the main reactive oxygen species involved in the degradation. Two major degradation products were identified by mass spectrometry, both of them less ecotoxic than BPA to a variety of test organisms, according to in silico estimations (ECOSAR 2.0).
653 $aG-C3N4
653 $aHeterogeneous photocatalysis
653 $aRGO
700 1 $aLOPES, B. R.
700 1 $aLIMA. C. S.
700 1 $aRIBEIRO, C.
700 1 $aAZEVEDO, E. B.
773 $tCatalysts$gv. 13, 1069, 2023.
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