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Registro Completo |
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
20/04/2023 |
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Data da última atualização: |
28/11/2024 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
GEOVO, J. D. C.; TORRES, J. A.; GIROTO, A. S.; ROCHA, F. C. N.; GARCIA, M. M.; SILVA, G. T. S. T.; SOUZA, J. R. C.; OLIVEIRA, J. A. de; RIBEIRO, C.; NOGUEIRA, A. E. |
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Afiliação: |
JOSE D.C. GEOVO, FEDERAL UNIVERSITY OF OURO PRETO-UFO; JULIANA A. TORRES; AMANDA SOARES GIROTO, UNIVERSIDADE FEDERAL DE SÃO CARLOS (UFSCAR); FERNANDA C.N. ROCHA A,, FEDERAL UNIVERSITY OF OURO PRETO - UFOP; MARÍLIA M. GARCIA, FEDERAL UNIVERSITY OF OURO PRETO-UFOP; GELSON T. S. T. SILVA, UNIVERSIDADE FEDERAL DE SÃO CARLOS (UFSCAR ); JOELMA R.C. SOUZA, FEDERAL UNIVERSITY OF OURO PRETO - UFOP; JESSICA A. DE OLIVEIRA, UNIVERSIDADE FEDERAL DE ALFENAS (UNIFAL-MG); CAUE RIBEIRO DE OLIVEIRA, CNPDIA; ANDRE E. NOGUEIRA A, FEDERAL UNIVERSITY OF OURO PRETO-UFOP. |
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Título: |
Evaluation of the activity and selectivity of mesoporous composites of MCM-41 and CuO in the CO2 photoreduction process. |
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Ano de publicação: |
2023 |
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Fonte/Imprenta: |
Journal of Photochemistry & Photobiology, A: Chemistry, v. 439, 114631, 2023. |
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ISSN: |
1010-6030 |
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DOI: |
https://doi.org/10.1016/j.jphotochem.2023.114631 |
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Idioma: |
Inglês |
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Conteúdo: |
The conversion of CO2 into valuable chemical feedstock through photocatalysis is considered an effective strategy to mitigate global warming and energy supply problems. Among the challenges for CO2 photoreduction are the design and synthesis of active photocatalysts with high affinity for the CO2 molecule and suitable reduction potentials of valence and conduction bands to promote the reduction of the CO2 molecule. Molecular sieves (MCM-41) with semiconductors, such as copper oxide, are alternatives to the traditional semiconductors (TiO2 and ZnO) with high CO2 adsorption capacity, high specific surface area, and good stability, making them perfect candidates for photocatalysis. Therefore, in this work, mesoporous composite materials based on MCM-41 and CuO were synthesized via the impregnation method. The synthesized materials were chemically, structurally, and morphologically characterized by XRD, SEM, FTIR, XPS, DRS, N2 adsorption and desorption, and atomic absorption spectroscopy techniques, and the photocatalytic activity in the reduction of CO2 was evaluated under visible radiation. We show that MCM-41 and the composite MCM-41/CuO have significant potential for use in the CO2 photoreduction process, where the composition and different active sites in the photocatalysts play an important role in the activity and selectivity of the products formed. The results showed that the MCM-41 and the composite with 1 % (w/w%) CuO presented high selectivity and production of methanol, with 585.88 and 267.05 μmol.gcatalyst -1 , respectively. Thus, the findings demonstrated the versatility of the MCM-41 to form composites with semiconductors, as well as the need to comprehend the main aspects that influence CO2 photoreduction activities and the selectivity of the composites, including their surface, structural, and electrical features. MenosThe conversion of CO2 into valuable chemical feedstock through photocatalysis is considered an effective strategy to mitigate global warming and energy supply problems. Among the challenges for CO2 photoreduction are the design and synthesis of active photocatalysts with high affinity for the CO2 molecule and suitable reduction potentials of valence and conduction bands to promote the reduction of the CO2 molecule. Molecular sieves (MCM-41) with semiconductors, such as copper oxide, are alternatives to the traditional semiconductors (TiO2 and ZnO) with high CO2 adsorption capacity, high specific surface area, and good stability, making them perfect candidates for photocatalysis. Therefore, in this work, mesoporous composite materials based on MCM-41 and CuO were synthesized via the impregnation method. The synthesized materials were chemically, structurally, and morphologically characterized by XRD, SEM, FTIR, XPS, DRS, N2 adsorption and desorption, and atomic absorption spectroscopy techniques, and the photocatalytic activity in the reduction of CO2 was evaluated under visible radiation. We show that MCM-41 and the composite MCM-41/CuO have significant potential for use in the CO2 photoreduction process, where the composition and different active sites in the photocatalysts play an important role in the activity and selectivity of the products formed. The results showed that the MCM-41 and the composite with 1 % (w/w%) CuO presented high selectivity and production of methan... Mostrar Tudo |
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Palavras-Chave: |
Artificial photosynthesis; CO2 photoreduction; Mechanism; Molecular sieves. |
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Categoria do assunto: |
-- |
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Marc: |
LEADER 02825naa a2200301 a 4500
001 2153292
005 2024-11-28
008 2023 bl uuuu u00u1 u #d
022 $a1010-6030
024 7 $ahttps://doi.org/10.1016/j.jphotochem.2023.114631$2DOI
100 1 $aGEOVO, J. D. C.
245 $aEvaluation of the activity and selectivity of mesoporous composites of MCM-41 and CuO in the CO2 photoreduction process.$h[electronic resource]
260 $c2023
520 $aThe conversion of CO2 into valuable chemical feedstock through photocatalysis is considered an effective strategy to mitigate global warming and energy supply problems. Among the challenges for CO2 photoreduction are the design and synthesis of active photocatalysts with high affinity for the CO2 molecule and suitable reduction potentials of valence and conduction bands to promote the reduction of the CO2 molecule. Molecular sieves (MCM-41) with semiconductors, such as copper oxide, are alternatives to the traditional semiconductors (TiO2 and ZnO) with high CO2 adsorption capacity, high specific surface area, and good stability, making them perfect candidates for photocatalysis. Therefore, in this work, mesoporous composite materials based on MCM-41 and CuO were synthesized via the impregnation method. The synthesized materials were chemically, structurally, and morphologically characterized by XRD, SEM, FTIR, XPS, DRS, N2 adsorption and desorption, and atomic absorption spectroscopy techniques, and the photocatalytic activity in the reduction of CO2 was evaluated under visible radiation. We show that MCM-41 and the composite MCM-41/CuO have significant potential for use in the CO2 photoreduction process, where the composition and different active sites in the photocatalysts play an important role in the activity and selectivity of the products formed. The results showed that the MCM-41 and the composite with 1 % (w/w%) CuO presented high selectivity and production of methanol, with 585.88 and 267.05 μmol.gcatalyst -1 , respectively. Thus, the findings demonstrated the versatility of the MCM-41 to form composites with semiconductors, as well as the need to comprehend the main aspects that influence CO2 photoreduction activities and the selectivity of the composites, including their surface, structural, and electrical features.
653 $aArtificial photosynthesis
653 $aCO2 photoreduction
653 $aMechanism
653 $aMolecular sieves
700 1 $aTORRES, J. A.
700 1 $aGIROTO, A. S.
700 1 $aROCHA, F. C. N.
700 1 $aGARCIA, M. M.
700 1 $aSILVA, G. T. S. T.
700 1 $aSOUZA, J. R. C.
700 1 $aOLIVEIRA, J. A. de
700 1 $aRIBEIRO, C.
700 1 $aNOGUEIRA, A. E.
773 $tJournal of Photochemistry & Photobiology, A: Chemistry$gv. 439, 114631, 2023.
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Embrapa Instrumentação (CNPDIA) |
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| Registros recuperados : 4 | |
| 1. |  | BRAZ, E. M.; FERREIRA, L. A.; SOUZA, J. M. A. de; SILVA, Z. A. G. P. da G. e; FIGUEIREDO, E. O.; OLIVEIRA, L. C. de. Manejo dos produtos florestais não madeireiros na Floresta Estadual do Antimari, AC. In: SIVIERO, A.; MING, L. C.; SILVEIRA, M.; DALY, D. C.; WALLACE, R. H. (org.). Etnobotânica e botânica econômica do Acre. Rio Branco, AC: Edufac, 2016. cap. 6. p. 96-110.| Tipo: Capítulo em Livro Técnico-Científico |
| Biblioteca(s): Embrapa Acre; Embrapa Florestas. |
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| 2. | | BRAZ, E. M.; FIGUEIREDO, E. O.; FERREIRA, L. A.; OLIVEIRA, L. C. de; GAMA e SILVA, Z. A. G. P. da; SOUZA, J. M. A. de. Manejo dos produtos florestais não madeireiros da Floresta Estadual do Antimary: a busca de um modelo. In: CONGRESSO IBERO-AMERICANO DE PESQUISA E DESENVOLVIMENTO DE PRODUTOS FLORESTAIS, 2.; SEMINÁRIO EM TECNOLOGIA DA MADEIRA E PRODUTOS FLORESTAIS NÃO MADEIRÁVEIS, 1., 2002, Curitiba. Aproveitamento tecnológico da floresta ibero-americana: fonte de suprimento para o mundo: anais. Curitiba: Universidade Federal do Paraná: Fundação de Pesquisas Florestais do Paraná, 2002. 15 p. 1 CD-ROM.| Tipo: Artigo em Anais de Congresso |
| Biblioteca(s): Embrapa Acre. |
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| 3. | | LAROCA, J. V. dos S.; SOUZA, J. M. A. de; PIRES, G. C.; PIRES, G. J. C.; PACHECO, L. P.; SILVA, F. D. da; WRUCK, F. J.; CARNEIRO, M. A. C.; SILVA, L. S.; SOUZA, E. D. de. Soil quality and soybean productivity in crop-livestock integrated system in no-tillage. Pesquisa Agropecuária Brasileira, Brasília, DF, v. 53, n. 11, p. 1248-1258, Nov. 2018. Título em Português: Qualidade do solo e produtividade de soja em sistema de integração lavoura-pecuária em plantio direto.| Biblioteca(s): Embrapa Unidades Centrais. |
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| 4. | | VALENTIM, J. F.; CAVALCANTI, F. J. B.; SOTHERS, C. A.; BRAZ, E. M.; CALOURO, A. M.; SILVA, Z. A. G. P. da G. e; SILVA, J. A.; SOUZA, J. C. N. de; SOUTO, A. M.; SOUZA, J. M. A. de; PEREIRA, A. M. B.; KRANZ, R.; LOTUFO, U. D.; ARAUJO, H. J. B. de; SANT'ANA, H. M.; DIÓGENES, M. B.; MEDEIROS, M. da F. e S. T. The Acre project: an ITTO action to promote sustainable management of forests and development in the Amazon. Rio Branco, AC: FUNTAC, 1999. 77 p.| Tipo: Autoria/Organização/Edição de Livros |
| Biblioteca(s): Embrapa Acre. |
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| Registros recuperados : 4 | |
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| Nenhum registro encontrado para a expressão de busca informada. |
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