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| Registros recuperados : 273 | |
| 86. |  | SONG, G.; NOVOTNY, E. H.; AZEVEDO, E. R. de; BONAGAMBA, T. J. Composition of the humin fraction and coarse char of Terra Preta de Índios soils by NMR, multivariate curve resolution and scanning electron microscopy. In: ANNUAL INTERNATIONAL MEETING OF THE INTERNATIONAL BIOCHAR INITIATIVE, 2., 2008, Newcastle. Biochar, sustainability and security in a changing climate. Newcastle: International Biochar Initiative, 2008. p. 27-28. Ref. B21.| Biblioteca(s): Embrapa Solos. |
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| 89. | | GUIOTOKU, M.; HANSEL, F. A.; NOVOTNY, E. H.; MAIA, C. M. B. de F. Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose. Pesquisa Agropecuária Brasileira, Brasília, DF, v. 47, n. 5, p. 687-692, maio 2012.| Biblioteca(s): Embrapa Florestas; Embrapa Solos; Embrapa Unidades Centrais. |
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| 90. | | SMIDT, E.; TINTNER, J.; NELLE, O.; OLIVEIRA, R. R.; PATZLAFF, R.; NOVOTNY, E. H.; KLEMM, S. Infrared spectroscopy refines chronological assessment, depositional environment and pyrolysis conditions of archeological charcoals. Scientific Reports, v. 10, 12427, 2020.| Biblioteca(s): Embrapa Solos. |
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| 92. | | NOVOTNY, E. H.; MADARI, B. E.; MAIA, C. M. B. de F.; MANGRICH, A. S. O potencial do biocarvão (carbono pirogênico) no sequestro de carbono; na ciclagem de nutrientes; no crescimento das plantas e no estímulo de processos microbiológicos. In: REUNIÃO BRASILEIRA DE FERTILIDADE DO SOLO E NUTRIÇÃO DE PLANTAS, 30.; REUNIÃO BRASILEIRA SOBRE MICORRIZAS, 14.; SIMPÓSIO BRASILEIRO DE MICROBIOLOGIA DO SOLO, 12.; REUNIÃO BRASILEIRA DE BIOLOGIA DO SOLO, 9.; SIMPÓSIO SOBRE SELÊNIO NO BRASIL, 1., 2012, Maceió. A responsabilidade socioambiental da pesquisa agrícola: anais. Viçosa, MG: SBCS, 2012. 1 CD-ROM. Fertbio 2012.| Biblioteca(s): Embrapa Arroz e Feijão; Embrapa Florestas; Embrapa Solos. |
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| 94. | | MELLIGAN, F.; AUCCAISE, R.; NOVOTNY, E. H.; LEAHY, J. J.; HAYES, M. H. B.; KWAPINSKI, W. Pressurised pyrolysis of Miscanthus using a fixed bed reactor. Bioresource Technology, v. 102, n. 3, p. 3466-3470, Feb. 2011.| Biblioteca(s): Embrapa Solos. |
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| 95. | | CRUZ, J. C.; PEREIRA FILHO, I. A.; ALVARENGA, R. C.; COELHO, A. M.; NOVOTNY, E. H. Escolha da semente. Revista Brasileira de Agropecuária, São Paulo, v. 3, n. 17, p. 17-19, [2002].| Biblioteca(s): Embrapa Milho e Sorgo. |
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| 96. | | CRUZ, J. C.; PEREIRA FILHO, I. A.; ALVARENGA, R. C.; COELHO, A. M.; NOVOTNY, E. H. Espaçamento e densidade de plantio: fazendo sua lavoura render! Revista Brasileira de Agropecuária, São Paulo, v. 3, n. 17, p. 21, [2002].| Biblioteca(s): Embrapa Milho e Sorgo. |
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| 99. | | NOVOTNY, E. H.; HAYES, M. H. B.; SONG, G.; AZEVEDO, E. R. de; BONAGAMBA, T. Extraction and characterisation of humin fraction from Amazonian anthropogenic dark earth soils ("Terra Preta de Indios"). In: INTERNATIONAL MEETING OF THE INTERNATIONAL HUMIC SUBSTANCES SOCIETY, 14., 2008, Saint Petersburg. From molecular understanding to innovative applications of humic substances: proceedings... Moscow: Lomonosov Moscow State University, 2008. v. 1, p. 105-108.| Biblioteca(s): Embrapa Solos. |
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| 100. | | MCINERNEV, R.; STUART, J.; NOVOTNY, E. H.; HAYES, M. H. B.; YOUNG, K. Extraction and characterization of organic fractions isolated from a China Ball Clay quarried in Devon Sout West England. In: INTERNATIONAL MEETING OF THE INTERNATIONAL HUMIC SUBSTANCES SOCIETY, 14., 2008, Saint Petersburg. From molecular understanding to innovative applications of humic substances: proceedings... Moscow: Lomonosov Moscow State University, 2008. v. 2, p. 567-570.| Biblioteca(s): Embrapa Solos. |
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| Registros recuperados : 273 | |
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 | Acesso ao texto completo restrito à biblioteca da Embrapa Solos. Para informações adicionais entre em contato com cnps.biblioteca@embrapa.br. |
Registro Completo
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Biblioteca(s): |
Embrapa Solos. |
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Data corrente: |
20/10/2021 |
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Data da última atualização: |
20/10/2021 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
NOVOTNY, E. H.; KNICKER, H.; COLNAGO, L. A.; MARTIN NETO, L. |
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Afiliação: |
ETELVINO HENRIQUE NOVOTNY, CNPS; HEIKE KNICKER; LUIZ ALBERTO COLNAGO, CNPDIA; LADISLAU MARTIN NETO, CNPDIA. |
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Título: |
Effect of residual vanadyl on the spectroscopic analysis of humic acids. |
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Ano de publicação: |
2006 |
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Fonte/Imprenta: |
Organic Geochemistry, v. 37, n. 11, p. 1562-1572, Nov. 2006. |
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DOI: |
https://doi.org/10.1016/j.orggeochem.2006.06.015 |
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Idioma: |
Inglês |
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Notas: |
Na publicação: Ladislau Martin-Neto. |
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Conteúdo: |
The effect of residual vanadyl (VO2+) on data derived from the analysis of humic acids (HAs) by means of fluorescence spectroscopy, solid-state 13C nuclear magnetic resonance spectroscopy (NMR) and UV-Vis spectroscopy was examined in order to reveal potential organic groups involved in metal complexation. The HAs were extracted from agricultural soils from an experimental station in Campinas, Brazil. Their paramagnetic ion content was determined using electron paramagnetic resonance (EPR). Because of the well-resolved EPR signal, the VO2+ ion content was used for the correlation studies. The latter clearly demonstrated that residual VO2+ affects the spectroscopic data and that, besides the intrinsic structural characteristic of HAs, the impact of paramagnetic ions must be considered for careful interpretation of such data. On the other hand, analysis of these effects can give additional structural information. With respect to the UV-Vis spectra, the positive correlation between VO2+ content and the absorption at 665 nm (E6) was attributed to the presence of VO2+ complexes. Further support for metal-humic substance binding was extracted by way of a reduction in the fluorescence intensity with increasing VO2+ concentration for both excitation and emission. A relationship between the suppression of the intensity of the O-alkyl, di-O-alkyl and carboxyl C signals in the solid-state 13C NMR spectra and the VO2+ content demonstrated the involvement of carbohydrates in metal complexation, probably in the uronic acid form. No clear correlation was observed with respect to the O-aryl C signal, which may be due to a low accessibility of the metallic ion to methyl- substituted O-aryl groups as they occur in lignin derivatives. MenosThe effect of residual vanadyl (VO2+) on data derived from the analysis of humic acids (HAs) by means of fluorescence spectroscopy, solid-state 13C nuclear magnetic resonance spectroscopy (NMR) and UV-Vis spectroscopy was examined in order to reveal potential organic groups involved in metal complexation. The HAs were extracted from agricultural soils from an experimental station in Campinas, Brazil. Their paramagnetic ion content was determined using electron paramagnetic resonance (EPR). Because of the well-resolved EPR signal, the VO2+ ion content was used for the correlation studies. The latter clearly demonstrated that residual VO2+ affects the spectroscopic data and that, besides the intrinsic structural characteristic of HAs, the impact of paramagnetic ions must be considered for careful interpretation of such data. On the other hand, analysis of these effects can give additional structural information. With respect to the UV-Vis spectra, the positive correlation between VO2+ content and the absorption at 665 nm (E6) was attributed to the presence of VO2+ complexes. Further support for metal-humic substance binding was extracted by way of a reduction in the fluorescence intensity with increasing VO2+ concentration for both excitation and emission. A relationship between the suppression of the intensity of the O-alkyl, di-O-alkyl and carboxyl C signals in the solid-state 13C NMR spectra and the VO2+ content demonstrated the involvement of carbohydrates in metal complex... Mostrar Tudo |
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Thesaurus NAL: |
humic acids. |
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Categoria do assunto: |
P Recursos Naturais, Ciências Ambientais e da Terra |
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Marc: |
LEADER 02368naa a2200193 a 4500
001 2135467
005 2021-10-20
008 2006 bl uuuu u00u1 u #d
024 7 $ahttps://doi.org/10.1016/j.orggeochem.2006.06.015$2DOI
100 1 $aNOVOTNY, E. H.
245 $aEffect of residual vanadyl on the spectroscopic analysis of humic acids.$h[electronic resource]
260 $c2006
500 $aNa publicação: Ladislau Martin-Neto.
520 $aThe effect of residual vanadyl (VO2+) on data derived from the analysis of humic acids (HAs) by means of fluorescence spectroscopy, solid-state 13C nuclear magnetic resonance spectroscopy (NMR) and UV-Vis spectroscopy was examined in order to reveal potential organic groups involved in metal complexation. The HAs were extracted from agricultural soils from an experimental station in Campinas, Brazil. Their paramagnetic ion content was determined using electron paramagnetic resonance (EPR). Because of the well-resolved EPR signal, the VO2+ ion content was used for the correlation studies. The latter clearly demonstrated that residual VO2+ affects the spectroscopic data and that, besides the intrinsic structural characteristic of HAs, the impact of paramagnetic ions must be considered for careful interpretation of such data. On the other hand, analysis of these effects can give additional structural information. With respect to the UV-Vis spectra, the positive correlation between VO2+ content and the absorption at 665 nm (E6) was attributed to the presence of VO2+ complexes. Further support for metal-humic substance binding was extracted by way of a reduction in the fluorescence intensity with increasing VO2+ concentration for both excitation and emission. A relationship between the suppression of the intensity of the O-alkyl, di-O-alkyl and carboxyl C signals in the solid-state 13C NMR spectra and the VO2+ content demonstrated the involvement of carbohydrates in metal complexation, probably in the uronic acid form. No clear correlation was observed with respect to the O-aryl C signal, which may be due to a low accessibility of the metallic ion to methyl- substituted O-aryl groups as they occur in lignin derivatives.
650 $ahumic acids
700 1 $aKNICKER, H.
700 1 $aCOLNAGO, L. A.
700 1 $aMARTIN NETO, L.
773 $tOrganic Geochemistry$gv. 37, n. 11, p. 1562-1572, Nov. 2006.
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