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Registro Completo |
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
20/04/2023 |
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Data da última atualização: |
20/04/2023 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
GEOVO, J. D. C.; TORRES, J. A.; GIROTO, A. S.; ROCHA, F. C. N.; GARCIA, M. M.; SILVA, G. T. S. T.; SOUZA, J. R. C.; OLIVEIRA, J. A. de; RIBEIRO, C.; NOGUEIRA, A. E. |
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Afiliação: |
CAUE RIBEIRO DE OLIVEIRA, CNPDIA. |
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Título: |
Evaluation of the activity and selectivity of mesoporous composites of MCM-41 and CuO in the CO2 photoreduction process. |
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Ano de publicação: |
2023 |
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Fonte/Imprenta: |
Journal of Photochemistry & Photobiology, A: Chemistry, v. 439, 114631, 2023. |
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ISSN: |
1010-6030 |
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DOI: |
https://doi.org/10.1016/j.jphotochem.2023.114631 |
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Idioma: |
Inglês |
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Conteúdo: |
The conversion of CO2 into valuable chemical feedstock through photocatalysis is considered an effective strategy to mitigate global warming and energy supply problems. Among the challenges for CO2 photoreduction are the design and synthesis of active photocatalysts with high affinity for the CO2 molecule and suitable reduction potentials of valence and conduction bands to promote the reduction of the CO2 molecule. Molecular sieves (MCM-41) with semiconductors, such as copper oxide, are alternatives to the traditional semiconductors (TiO2 and ZnO) with high CO2 adsorption capacity, high specific surface area, and good stability, making them perfect candidates for photocatalysis. Therefore, in this work, mesoporous composite materials based on MCM-41 and CuO were synthesized via the impregnation method. The synthesized materials were chemically, structurally, and morphologically characterized by XRD, SEM, FTIR, XPS, DRS, N2 adsorption and desorption, and atomic absorption spectroscopy techniques, and the photocatalytic activity in the reduction of CO2 was evaluated under visible radiation. We show that MCM-41 and the composite MCM-41/CuO have significant potential for use in the CO2 photoreduction process, where the composition and different active sites in the photocatalysts play an important role in the activity and selectivity of the products formed. The results showed that the MCM-41 and the composite with 1 % (w/w%) CuO presented high selectivity and production of methanol, with 585.88 and 267.05 μmol.gcatalyst -1 , respectively. Thus, the findings demonstrated the versatility of the MCM-41 to form composites with semiconductors, as well as the need to comprehend the main aspects that influence CO2 photoreduction activities and the selectivity of the composites, including their surface, structural, and electrical features. MenosThe conversion of CO2 into valuable chemical feedstock through photocatalysis is considered an effective strategy to mitigate global warming and energy supply problems. Among the challenges for CO2 photoreduction are the design and synthesis of active photocatalysts with high affinity for the CO2 molecule and suitable reduction potentials of valence and conduction bands to promote the reduction of the CO2 molecule. Molecular sieves (MCM-41) with semiconductors, such as copper oxide, are alternatives to the traditional semiconductors (TiO2 and ZnO) with high CO2 adsorption capacity, high specific surface area, and good stability, making them perfect candidates for photocatalysis. Therefore, in this work, mesoporous composite materials based on MCM-41 and CuO were synthesized via the impregnation method. The synthesized materials were chemically, structurally, and morphologically characterized by XRD, SEM, FTIR, XPS, DRS, N2 adsorption and desorption, and atomic absorption spectroscopy techniques, and the photocatalytic activity in the reduction of CO2 was evaluated under visible radiation. We show that MCM-41 and the composite MCM-41/CuO have significant potential for use in the CO2 photoreduction process, where the composition and different active sites in the photocatalysts play an important role in the activity and selectivity of the products formed. The results showed that the MCM-41 and the composite with 1 % (w/w%) CuO presented high selectivity and production of methan... Mostrar Tudo |
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Palavras-Chave: |
Artificial photosynthesis; CO2 photoreduction; Mechanism; Molecular sieves. |
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Categoria do assunto: |
-- |
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Marc: |
LEADER 02825naa a2200301 a 4500
001 2153292
005 2023-04-20
008 2023 bl uuuu u00u1 u #d
022 $a1010-6030
024 7 $ahttps://doi.org/10.1016/j.jphotochem.2023.114631$2DOI
100 1 $aGEOVO, J. D. C.
245 $aEvaluation of the activity and selectivity of mesoporous composites of MCM-41 and CuO in the CO2 photoreduction process.$h[electronic resource]
260 $c2023
520 $aThe conversion of CO2 into valuable chemical feedstock through photocatalysis is considered an effective strategy to mitigate global warming and energy supply problems. Among the challenges for CO2 photoreduction are the design and synthesis of active photocatalysts with high affinity for the CO2 molecule and suitable reduction potentials of valence and conduction bands to promote the reduction of the CO2 molecule. Molecular sieves (MCM-41) with semiconductors, such as copper oxide, are alternatives to the traditional semiconductors (TiO2 and ZnO) with high CO2 adsorption capacity, high specific surface area, and good stability, making them perfect candidates for photocatalysis. Therefore, in this work, mesoporous composite materials based on MCM-41 and CuO were synthesized via the impregnation method. The synthesized materials were chemically, structurally, and morphologically characterized by XRD, SEM, FTIR, XPS, DRS, N2 adsorption and desorption, and atomic absorption spectroscopy techniques, and the photocatalytic activity in the reduction of CO2 was evaluated under visible radiation. We show that MCM-41 and the composite MCM-41/CuO have significant potential for use in the CO2 photoreduction process, where the composition and different active sites in the photocatalysts play an important role in the activity and selectivity of the products formed. The results showed that the MCM-41 and the composite with 1 % (w/w%) CuO presented high selectivity and production of methanol, with 585.88 and 267.05 μmol.gcatalyst -1 , respectively. Thus, the findings demonstrated the versatility of the MCM-41 to form composites with semiconductors, as well as the need to comprehend the main aspects that influence CO2 photoreduction activities and the selectivity of the composites, including their surface, structural, and electrical features.
653 $aArtificial photosynthesis
653 $aCO2 photoreduction
653 $aMechanism
653 $aMolecular sieves
700 1 $aTORRES, J. A.
700 1 $aGIROTO, A. S.
700 1 $aROCHA, F. C. N.
700 1 $aGARCIA, M. M.
700 1 $aSILVA, G. T. S. T.
700 1 $aSOUZA, J. R. C.
700 1 $aOLIVEIRA, J. A. de
700 1 $aRIBEIRO, C.
700 1 $aNOGUEIRA, A. E.
773 $tJournal of Photochemistry & Photobiology, A: Chemistry$gv. 439, 114631, 2023.
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Embrapa Instrumentação (CNPDIA) |
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| 83. |  | EUCLIDES, V. P. B.; MACEDO, M. C. M.; COSTA, J. A.; FERNANDES, W. Beef cattle performance on Panicum maximum pastures under two levels of fertilization in Brasil. In: INTERNATIONAL GRASSLAND CONGRESS, 21.; INTERNATIONAL RANGELAND CONGRESS, 8., 2008, Huhhot, China. Multifunctional grasslands in a changing world: proceedings. Guangzhou: Guangdong People´s Publishing House, 2008. v.1 p. 480| Tipo: Artigo em Anais de Congresso / Nota Técnica |
| Biblioteca(s): Embrapa Gado de Corte. |
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| 86. | | KICHEL, A. N.; MIRANDA, C. H. B.; MACEDO, M. C. M. Conventional and multiple cropping systems of upland rice for reclamation degraded Brachiaria decumbens pastures. In: SIMPÓSIO SOBRE O CERRADO, 8.; INTERNATIONAL SYMPOSIUM ON TROPICAL SAVANNAS, 1., 1996, Brasília, DF. Biodiversidade e produção sustentável de alimentos e fibras nos cerrados: anais. Planaltina, DF: EMBRAPA-CPAC, 1996. p. 443-445. CNPGC. Editores: Roberto Carvalho Pereira, Luiz Carlos Bhering.| Biblioteca(s): Embrapa Gado de Corte. |
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| 91. | | KANNO, T.; SAITO, M.; ANDO, Y.; MACEDO, M. C. M.; NAKAMURA, T.; MIRANDA, C. H. B. Importance of indigenous arbuscular mycorrhiza for growth and phosphorus uptake in tropical forage grasses growing on na acid, intertile soil from the Brazilian savannas. Tropical Grasslands, Brisbane, v. 40, n. 2, p. 94-101, 2006.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: Internacional - A |
| Biblioteca(s): Embrapa Gado de Corte. |
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| 92. | | SCARIOT, E. M.; SILVA, E. J.; MACEDO, M. C. M.; EUCLIDES, V. P. B. Efeito do pastejo animal nas propriedades fisicas do solo sob pastagens do capim-marandu e capim-xaraés. In: JORNADA CIENTÍFICA DA EMBRAPA GADO DE CORTE, 6., 2010, Campo Grande, MS. Ética na pesquisa científica: [Anais da ...]. Campo Grande, MS: Embrapa Gado de Corte, 2010. 1 CD-ROM. Coordenadora: Vanessa Felipe de Souza 1 p.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Gado de Corte. |
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| 93. | | MALDONADO, E. C.; NETO, A. T. A.; GONSALES, A. S.; MACEDO, M. C. M. Efeito da calagem nas propriedades químicas de um latossolo do cerrado de Mato Grosso do Sul. In: JORNADA CIENTÍFICA EMBRAPA GADO DE CORTE, 8., 2012, Campo Grande, MS. [Anais da..]. Campo Grande, MS: Embrapa Gado de Corte, 2012. 2 p. (Embrapa Gado de Corte. Documentos, 198).| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Gado de Corte. |
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| 97. | | ZIMMER, A. H.; VALLE, C. B. do; MACEDO, M. C. M.; KICHEL, A. N. Diversificação e estabelecimento de pastagens. In: CURSO DE FORMAÇÃO, RECUPERAÇÃO E MANEJO DE PASTAGENS, Programa Repasto - Seprotur, turma 5 - 1. etapa, 2003, Campo Grande, MS. Palestras apresentadas. Campo Grande, MS: Embrapa Gado de Corte, 2003. p. 27-57.| Biblioteca(s): Embrapa Gado de Corte. |
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| Registros recuperados : 390 | |
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