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 | Acesso ao texto completo restrito à biblioteca da Embrapa Instrumentação. Para informações adicionais entre em contato com cnpdia.biblioteca@embrapa.br. |
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Registro Completo |
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
20/04/2023 |
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Data da última atualização: |
20/04/2023 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
GEOVO, J. D. C.; TORRES, J. A.; GIROTO, A. S.; ROCHA, F. C. N.; GARCIA, M. M.; SILVA, G. T. S. T.; SOUZA, J. R. C.; OLIVEIRA, J. A. de; RIBEIRO, C.; NOGUEIRA, A. E. |
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Afiliação: |
CAUE RIBEIRO DE OLIVEIRA, CNPDIA. |
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Título: |
Evaluation of the activity and selectivity of mesoporous composites of MCM-41 and CuO in the CO2 photoreduction process. |
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Ano de publicação: |
2023 |
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Fonte/Imprenta: |
Journal of Photochemistry & Photobiology, A: Chemistry, v. 439, 114631, 2023. |
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ISSN: |
1010-6030 |
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DOI: |
https://doi.org/10.1016/j.jphotochem.2023.114631 |
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Idioma: |
Inglês |
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Conteúdo: |
The conversion of CO2 into valuable chemical feedstock through photocatalysis is considered an effective strategy to mitigate global warming and energy supply problems. Among the challenges for CO2 photoreduction are the design and synthesis of active photocatalysts with high affinity for the CO2 molecule and suitable reduction potentials of valence and conduction bands to promote the reduction of the CO2 molecule. Molecular sieves (MCM-41) with semiconductors, such as copper oxide, are alternatives to the traditional semiconductors (TiO2 and ZnO) with high CO2 adsorption capacity, high specific surface area, and good stability, making them perfect candidates for photocatalysis. Therefore, in this work, mesoporous composite materials based on MCM-41 and CuO were synthesized via the impregnation method. The synthesized materials were chemically, structurally, and morphologically characterized by XRD, SEM, FTIR, XPS, DRS, N2 adsorption and desorption, and atomic absorption spectroscopy techniques, and the photocatalytic activity in the reduction of CO2 was evaluated under visible radiation. We show that MCM-41 and the composite MCM-41/CuO have significant potential for use in the CO2 photoreduction process, where the composition and different active sites in the photocatalysts play an important role in the activity and selectivity of the products formed. The results showed that the MCM-41 and the composite with 1 % (w/w%) CuO presented high selectivity and production of methanol, with 585.88 and 267.05 μmol.gcatalyst -1 , respectively. Thus, the findings demonstrated the versatility of the MCM-41 to form composites with semiconductors, as well as the need to comprehend the main aspects that influence CO2 photoreduction activities and the selectivity of the composites, including their surface, structural, and electrical features. MenosThe conversion of CO2 into valuable chemical feedstock through photocatalysis is considered an effective strategy to mitigate global warming and energy supply problems. Among the challenges for CO2 photoreduction are the design and synthesis of active photocatalysts with high affinity for the CO2 molecule and suitable reduction potentials of valence and conduction bands to promote the reduction of the CO2 molecule. Molecular sieves (MCM-41) with semiconductors, such as copper oxide, are alternatives to the traditional semiconductors (TiO2 and ZnO) with high CO2 adsorption capacity, high specific surface area, and good stability, making them perfect candidates for photocatalysis. Therefore, in this work, mesoporous composite materials based on MCM-41 and CuO were synthesized via the impregnation method. The synthesized materials were chemically, structurally, and morphologically characterized by XRD, SEM, FTIR, XPS, DRS, N2 adsorption and desorption, and atomic absorption spectroscopy techniques, and the photocatalytic activity in the reduction of CO2 was evaluated under visible radiation. We show that MCM-41 and the composite MCM-41/CuO have significant potential for use in the CO2 photoreduction process, where the composition and different active sites in the photocatalysts play an important role in the activity and selectivity of the products formed. The results showed that the MCM-41 and the composite with 1 % (w/w%) CuO presented high selectivity and production of methan... Mostrar Tudo |
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Palavras-Chave: |
Artificial photosynthesis; CO2 photoreduction; Mechanism; Molecular sieves. |
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Categoria do assunto: |
-- |
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Marc: |
LEADER 02825naa a2200301 a 4500
001 2153292
005 2023-04-20
008 2023 bl uuuu u00u1 u #d
022 $a1010-6030
024 7 $ahttps://doi.org/10.1016/j.jphotochem.2023.114631$2DOI
100 1 $aGEOVO, J. D. C.
245 $aEvaluation of the activity and selectivity of mesoporous composites of MCM-41 and CuO in the CO2 photoreduction process.$h[electronic resource]
260 $c2023
520 $aThe conversion of CO2 into valuable chemical feedstock through photocatalysis is considered an effective strategy to mitigate global warming and energy supply problems. Among the challenges for CO2 photoreduction are the design and synthesis of active photocatalysts with high affinity for the CO2 molecule and suitable reduction potentials of valence and conduction bands to promote the reduction of the CO2 molecule. Molecular sieves (MCM-41) with semiconductors, such as copper oxide, are alternatives to the traditional semiconductors (TiO2 and ZnO) with high CO2 adsorption capacity, high specific surface area, and good stability, making them perfect candidates for photocatalysis. Therefore, in this work, mesoporous composite materials based on MCM-41 and CuO were synthesized via the impregnation method. The synthesized materials were chemically, structurally, and morphologically characterized by XRD, SEM, FTIR, XPS, DRS, N2 adsorption and desorption, and atomic absorption spectroscopy techniques, and the photocatalytic activity in the reduction of CO2 was evaluated under visible radiation. We show that MCM-41 and the composite MCM-41/CuO have significant potential for use in the CO2 photoreduction process, where the composition and different active sites in the photocatalysts play an important role in the activity and selectivity of the products formed. The results showed that the MCM-41 and the composite with 1 % (w/w%) CuO presented high selectivity and production of methanol, with 585.88 and 267.05 μmol.gcatalyst -1 , respectively. Thus, the findings demonstrated the versatility of the MCM-41 to form composites with semiconductors, as well as the need to comprehend the main aspects that influence CO2 photoreduction activities and the selectivity of the composites, including their surface, structural, and electrical features.
653 $aArtificial photosynthesis
653 $aCO2 photoreduction
653 $aMechanism
653 $aMolecular sieves
700 1 $aTORRES, J. A.
700 1 $aGIROTO, A. S.
700 1 $aROCHA, F. C. N.
700 1 $aGARCIA, M. M.
700 1 $aSILVA, G. T. S. T.
700 1 $aSOUZA, J. R. C.
700 1 $aOLIVEIRA, J. A. de
700 1 $aRIBEIRO, C.
700 1 $aNOGUEIRA, A. E.
773 $tJournal of Photochemistry & Photobiology, A: Chemistry$gv. 439, 114631, 2023.
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Registro original: |
Embrapa Instrumentação (CNPDIA) |
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Biblioteca |
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Origem |
Tipo/Formato |
Classificação |
Cutter |
Registro |
Volume |
Status |
URL |
Voltar
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Registro Completo
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Biblioteca(s): |
Embrapa Acre. |
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Data corrente: |
24/09/1996 |
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Data da última atualização: |
04/05/2023 |
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Tipo da produção científica: |
Comunicado Técnico/Recomendações Técnicas |
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Autoria: |
CAMPOS, I. S.; GOMES, T. C. de A.; PAZ, F. das C. A. |
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Afiliação: |
IVANDIR SOARES CAMPOS, CPAF-AC; TAMARA CLAUDIA DE ARAUJO GOMES, CPAF-AC; FRANCISCO DAS CHAGAS ÁVILLA PAZ, CPAF-AC. |
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Título: |
Plantio direto do feijão na palha do arroz: alternativa para controle da "Mela do Feijoeiro". |
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Ano de publicação: |
1990 |
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Fonte/Imprenta: |
Rio Branco, AC: Embrapa-UEPAE Rio Branco, 1990. |
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Páginas: |
4 p. |
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Série: |
(Embrapa-UEPAE Rio Branco. Comunicado técnico, 54). |
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ISSN: |
0100-8668 |
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Idioma: |
Português |
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Conteúdo: |
Este trabalho avalia a eficiência do plantio direto do feijão na palha do arroz como alternativa para controle da "Mela do Feijoeiro". |
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Palavras-Chave: |
Acre; Amazonia Occidental; Amazônia Ocidental; Cero labranza; Enfermedades y desórdenes de las plantas; Frijoles; Marchitez; Mela do feijoeiro; Paja de arroz; Western Amazon. |
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Thesagro: |
Doença de planta; Feijão; Fungo; Palha de arroz; Phaseolus vulgaris; Plantio direto; Thanatephorus cucumeris. |
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Thesaurus NAL: |
Beans; Blight; Fungi; No-tillage; Plant diseases and disorders; Rice straw. |
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Categoria do assunto: |
F Plantas e Produtos de Origem Vegetal |
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URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/item/173386/1/931.pdf
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Marc: |
LEADER 01397nam a2200445 a 4500
001 1492178
005 2023-05-04
008 1990 bl uuuu u0uu1 u #d
022 $a0100-8668
100 1 $aCAMPOS, I. S.
245 $aPlantio direto do feijão na palha do arroz$balternativa para controle da "Mela do Feijoeiro".$h[electronic resource]
260 $aRio Branco, AC: Embrapa-UEPAE Rio Branco$c1990
300 $a4 p.
490 $a(Embrapa-UEPAE Rio Branco. Comunicado técnico, 54).
520 $aEste trabalho avalia a eficiência do plantio direto do feijão na palha do arroz como alternativa para controle da "Mela do Feijoeiro".
650 $aBeans
650 $aBlight
650 $aFungi
650 $aNo-tillage
650 $aPlant diseases and disorders
650 $aRice straw
650 $aDoença de planta
650 $aFeijão
650 $aFungo
650 $aPalha de arroz
650 $aPhaseolus vulgaris
650 $aPlantio direto
650 $aThanatephorus cucumeris
653 $aAcre
653 $aAmazonia Occidental
653 $aAmazônia Ocidental
653 $aCero labranza
653 $aEnfermedades y desórdenes de las plantas
653 $aFrijoles
653 $aMarchitez
653 $aMela do feijoeiro
653 $aPaja de arroz
653 $aWestern Amazon
700 1 $aGOMES, T. C. de A.
700 1 $aPAZ, F. das C. A.
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Embrapa Acre (CPAF-AC) |
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