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Registro Completo
Biblioteca(s): |
Embrapa Pecuária Sudeste. |
Data corrente: |
04/09/2017 |
Data da última atualização: |
05/01/2018 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Circulação/Nível: |
A - 1 |
Autoria: |
MACHADO, R. C.; AMARAL, C. D. B. do; SCHIAVO, D.; NOBREGA, J. de A.; NOGUEIRA, A. R. de A. |
Afiliação: |
Raquel Cardoso Machado, UFSCar; Clarice Dias Britto do Amaral, UFSCar; Daniela Schiavo, Agilent Technologies; Joaquim de Araújo Nobrega, UFSCar; ANA RITA DE ARAUJO NOGUEIRA, CPPSE. |
Título: |
Complex samples and spectral interferences in ICP-MS: evaluation of tandem mass spectrometry for interference-free determination of cadmium, tin and platinum group elements. |
Ano de publicação: |
2017 |
Fonte/Imprenta: |
Microchemical Journal, v. 130, p. 271-275, 2017. |
DOI: |
https://doi.org/10.1016/j.microc.2016.09.011 |
Idioma: |
Inglês |
Conteúdo: |
An analytical method was developed for determination of Cd, Sn, Pd, Pt and Rh in sediments, fertilizer and sludge samples by inductively coupled plasma tandem mass spectrometry (ICP-MS/MS). The performance of ICP-MS/MS using oxygen into the octopole reaction system (ORS3) and MS/MS mode, on mass and shift mass, was evaluated to overcome spectral interferences. Addition and recovery experiments in sediments, fertilizer and sludge samples at three concentration levels, 0.5, 1.0 and 5.0 μg L− 1, were carried out to evaluate the accuracy of the developed procedure. Quantitative recoveries, from 80 to 113% for 112Cd+, 120Sn+ and 106Pd+ were reached using MS/MS in on mass operation mode. For Pt and Rh, recoveries ranged from 81 to 117% by monitoring 195Pt16O+ and 103Rh16O+ in MS/MS (shift mass mode) with 0.3 mL min− 1 oxygen gas flow rate pressurized into the ORS3. Limits of detection of the developed method were 15, 2.5, 1.8, 9.0 and 9.9 μg kg− 1 for 195Pt16O+, 103Rh16O+, 112Cd+, 120Sn+, and 106Pd+, respectively. All analytes were simultaneously interference-free determined by ICP-MS/MS, which demonstrates the potential of this instrumental analytical strategy for Cd, Sn, Pd, Pt, and Rh determination in complex samples. |
Palavras-Chave: |
Mass shift mode; Spectral interferences. |
Thesaurus NAL: |
tandem mass spectrometry. |
Categoria do assunto: |
W Química e Física |
Marc: |
LEADER 02045naa a2200217 a 4500 001 2074928 005 2018-01-05 008 2017 bl uuuu u00u1 u #d 024 7 $ahttps://doi.org/10.1016/j.microc.2016.09.011$2DOI 100 1 $aMACHADO, R. C. 245 $aComplex samples and spectral interferences in ICP-MS$bevaluation of tandem mass spectrometry for interference-free determination of cadmium, tin and platinum group elements.$h[electronic resource] 260 $c2017 520 $aAn analytical method was developed for determination of Cd, Sn, Pd, Pt and Rh in sediments, fertilizer and sludge samples by inductively coupled plasma tandem mass spectrometry (ICP-MS/MS). The performance of ICP-MS/MS using oxygen into the octopole reaction system (ORS3) and MS/MS mode, on mass and shift mass, was evaluated to overcome spectral interferences. Addition and recovery experiments in sediments, fertilizer and sludge samples at three concentration levels, 0.5, 1.0 and 5.0 μg L− 1, were carried out to evaluate the accuracy of the developed procedure. Quantitative recoveries, from 80 to 113% for 112Cd+, 120Sn+ and 106Pd+ were reached using MS/MS in on mass operation mode. For Pt and Rh, recoveries ranged from 81 to 117% by monitoring 195Pt16O+ and 103Rh16O+ in MS/MS (shift mass mode) with 0.3 mL min− 1 oxygen gas flow rate pressurized into the ORS3. Limits of detection of the developed method were 15, 2.5, 1.8, 9.0 and 9.9 μg kg− 1 for 195Pt16O+, 103Rh16O+, 112Cd+, 120Sn+, and 106Pd+, respectively. All analytes were simultaneously interference-free determined by ICP-MS/MS, which demonstrates the potential of this instrumental analytical strategy for Cd, Sn, Pd, Pt, and Rh determination in complex samples. 650 $atandem mass spectrometry 653 $aMass shift mode 653 $aSpectral interferences 700 1 $aAMARAL, C. D. B. do 700 1 $aSCHIAVO, D. 700 1 $aNOBREGA, J. de A. 700 1 $aNOGUEIRA, A. R. de A. 773 $tMicrochemical Journal$gv. 130, p. 271-275, 2017.
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