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Registro Completo |
Biblioteca(s): |
Embrapa Agroindústria Tropical; Embrapa Alimentos e Territórios. |
Data corrente: |
30/04/2024 |
Data da última atualização: |
30/04/2024 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Autoria: |
PAIVA, E. M. DE; MATTOS, A. L. A.; SILVA, G. S. DA; CANUTO, K. M.; LEITAO, R. C.; ALVES, J. L. F.; BRITO, E. S. de. |
Afiliação: |
EVANICE MEDEIROS DE PAIVA, FEDERAL UNIVERSITY OF CEARÁ; ADRIANO LINCOLN ALBUQUERQUE MATTOS, CNPAT; GISELE SILVESTRE DA SILVA; KIRLEY MARQUES CANUTO, CNPAT; RENATO CARRHA LEITAO, CNPAT; JOSE LUIZ FRANCISCO ALVES, FEDERAL UNIVERSITY OF PARAÍBA; EDY SOUSA DE BRITO, CNAT. |
Título: |
Valorizing cashew nutshell residue for sustainable lignocellulosic panels using a bio-based phenolic resin as a circular economy solution. |
Ano de publicação: |
2024 |
Fonte/Imprenta: |
Industrial Crops and Products, 212, 118379, 2024. |
Idioma: |
Inglês Português |
Conteúdo: |
he motivation for this study stems from the significant annual amount of cashew nutshells produced worldwide, which has raised growing concerns about proper environmental disposal. One alternative is to utilize the nutshells to produce particleboards and eco-friendly resin, thereby contributing to the circular economy. The present study proposes an innovation by providing the first insights into particleboard production, utilizing pressed cashew nutshell and a phenolic resin derived from the reaction of cashew nutshell liquid (CNSL) with formaldehyde. The mass proportions of CNSL to formaldehyde were varied at 1:0.25, 1:0.5, and 1:0.75 (w/w) without the necessity for isolating chemical compounds at 105 °C. The resin was characterized using rheology, DSC, FTIR, HPLC, and NMR techniques. The mechanical properties of the particleboard were evaluated through density, tensile, flexural, water absorption, and thickness swelling tests. The formaldehyde emission and biodegradability content of the particleboards were also evaluated. Eco-friendly phenol-formaldehyde resin promoted the modulus of elasticity (MOE) from 707 to 1866 MPa and the modulus of rupture (MOR) from 6.4 to 14.3 MPa. In addition, using adhesive with CNSL to formaldehyde mass ratios of 1:0.25 and 1:0.50 resulted in particleboards of class E1 in terms of formaldehyde emissions. The biodegradability of panels PB25, PB50 and PB75 was 30%, 21% and 20%, respectively, in 30 days. These findings demonstrate the potential of cashew nutshell biomass and eco-friendly resin as an adhesive in the particleboard industry. Menoshe motivation for this study stems from the significant annual amount of cashew nutshells produced worldwide, which has raised growing concerns about proper environmental disposal. One alternative is to utilize the nutshells to produce particleboards and eco-friendly resin, thereby contributing to the circular economy. The present study proposes an innovation by providing the first insights into particleboard production, utilizing pressed cashew nutshell and a phenolic resin derived from the reaction of cashew nutshell liquid (CNSL) with formaldehyde. The mass proportions of CNSL to formaldehyde were varied at 1:0.25, 1:0.5, and 1:0.75 (w/w) without the necessity for isolating chemical compounds at 105 °C. The resin was characterized using rheology, DSC, FTIR, HPLC, and NMR techniques. The mechanical properties of the particleboard were evaluated through density, tensile, flexural, water absorption, and thickness swelling tests. The formaldehyde emission and biodegradability content of the particleboards were also evaluated. Eco-friendly phenol-formaldehyde resin promoted the modulus of elasticity (MOE) from 707 to 1866 MPa and the modulus of rupture (MOR) from 6.4 to 14.3 MPa. In addition, using adhesive with CNSL to formaldehyde mass ratios of 1:0.25 and 1:0.50 resulted in particleboards of class E1 in terms of formaldehyde emissions. The biodegradability of panels PB25, PB50 and PB75 was 30%, 21% and 20%, respectively, in 30 days. These findings demonstrate the potential ... Mostrar Tudo |
Palavras-Chave: |
Adesivo ecológico; Biodegradabilidade; CNSL; Eco-friendly adhesive; Emissão de formaldeído; Formaldehyde emission; LNC; Propriedades mecânicas. |
Thesagro: |
Desperdício. |
Thesaurus Nal: |
Biodegradability; Mechanical properties; Wastes. |
Categoria do assunto: |
-- W Química e Física |
Marc: |
LEADER 02615naa a2200337 a 4500 001 2164004 005 2024-04-30 008 2024 bl uuuu u00u1 u #d 100 1 $aPAIVA, E. M. DE 245 $aValorizing cashew nutshell residue for sustainable lignocellulosic panels using a bio-based phenolic resin as a circular economy solution.$h[electronic resource] 260 $c2024 520 $ahe motivation for this study stems from the significant annual amount of cashew nutshells produced worldwide, which has raised growing concerns about proper environmental disposal. One alternative is to utilize the nutshells to produce particleboards and eco-friendly resin, thereby contributing to the circular economy. The present study proposes an innovation by providing the first insights into particleboard production, utilizing pressed cashew nutshell and a phenolic resin derived from the reaction of cashew nutshell liquid (CNSL) with formaldehyde. The mass proportions of CNSL to formaldehyde were varied at 1:0.25, 1:0.5, and 1:0.75 (w/w) without the necessity for isolating chemical compounds at 105 °C. The resin was characterized using rheology, DSC, FTIR, HPLC, and NMR techniques. The mechanical properties of the particleboard were evaluated through density, tensile, flexural, water absorption, and thickness swelling tests. The formaldehyde emission and biodegradability content of the particleboards were also evaluated. Eco-friendly phenol-formaldehyde resin promoted the modulus of elasticity (MOE) from 707 to 1866 MPa and the modulus of rupture (MOR) from 6.4 to 14.3 MPa. In addition, using adhesive with CNSL to formaldehyde mass ratios of 1:0.25 and 1:0.50 resulted in particleboards of class E1 in terms of formaldehyde emissions. The biodegradability of panels PB25, PB50 and PB75 was 30%, 21% and 20%, respectively, in 30 days. These findings demonstrate the potential of cashew nutshell biomass and eco-friendly resin as an adhesive in the particleboard industry. 650 $aBiodegradability 650 $aMechanical properties 650 $aWastes 650 $aDesperdício 653 $aAdesivo ecológico 653 $aBiodegradabilidade 653 $aCNSL 653 $aEco-friendly adhesive 653 $aEmissão de formaldeído 653 $aFormaldehyde emission 653 $aLNC 653 $aPropriedades mecânicas 700 1 $aMATTOS, A. L. A. 700 1 $aSILVA, G. S. DA 700 1 $aCANUTO, K. M. 700 1 $aLEITAO, R. C. 700 1 $aALVES, J. L. F. 700 1 $aBRITO, E. S. de 773 $tIndustrial Crops and Products, 212, 118379, 2024.
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Embrapa Agroindústria Tropical (CNPAT) |
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| Acesso ao texto completo restrito à biblioteca da Embrapa Florestas. Para informações adicionais entre em contato com cnpf.biblioteca@embrapa.br. |
Registro Completo
Biblioteca(s): |
Embrapa Florestas. |
Data corrente: |
21/06/2016 |
Data da última atualização: |
21/06/2016 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Circulação/Nível: |
A - 1 |
Autoria: |
OLIVEIRA, H. R.; SILVA, F. F.; SIQUEIRA, O. H. G. B. D.; SOUZA, N. O.; JUNQUEIRA, V. S.; RESENDE, M. D. V. de; BORQUIS, R. R. A.; RODRIGUES, M. T. |
Afiliação: |
H. R. Oliveira, UFV; F. F. Silva, UFV; O. H. G. B. D. Siqueira, UFV; N. O. Souza, UFV; V. S. Junqueira, UFV; MARCOS DEON VILELA DE RESENDE, CNPF; R. R. A. Borquis, UNESP; M. T. Rodrigues, UFV. |
Título: |
Combining different functions to describe milk, fat, and protein yield in goats using Bayesian multiple-trait random regression models. |
Ano de publicação: |
2016 |
Fonte/Imprenta: |
Journal of Animal Science, v. 94 n. 5, p. 1865-1874, May 2016. |
DOI: |
10.2527/jas2015-0150 |
Idioma: |
Inglês |
Conteúdo: |
We proposed multiple-trait random regression models (MTRRM) combining different functions to describe milk yield (MY) and fat (FP) and protein (PP) percentage in dairy goat genetic evaluation by using Bayesian inference. A total of 3,856 MY, FP, and PP test-day records, measured between 2000 and 2014, from 535 first lactations of Saanen and Alpine goats, including their cross, were used in this study. The initial analyses were performed using the following single-trait random regression models (STRRM): third- and fifth-order Legendre polynomials (Leg3 and Leg5), linear B-splines with 3 and 5 knots, the Ali and Schaeffer function (Ali), and Wilmink function. Heterogeneity of residual variances was modeled considering 3 classes. After the selection of the best STRRM to describe each trait on the basis of the deviance information criterion (DIC) and posterior model probabilities (PMP), the functions were combined to compose the MTRRM. All combined MTRRM presented lower DIC values and higher PMP, showing the superiority of these models when compared to other MTRRM based only on the same function assumed for all traits. Among the combined MTRRM, those considering Ali to describe MY and PP and Leg5 to describe FP (Ali_Leg5_Ali model) presented the best fit. From the Ali_Leg5_Ali model, heritability estimates over time for MY, FP. and PP ranged from 0.25 to 0.54, 0.27 to 0.48, and 0.35 to 0.51, respectively. Genetic correlation between MY and FP, MY and PP, and FP and PP ranged from −0.58 to 0.03, −0.46 to 0.12, and 0.37 to 0.64, respectively. We concluded that combining different functions under a MTRRM approach can be a plausible alternative for joint genetic evaluation of milk yield and milk constituents in goats. MenosWe proposed multiple-trait random regression models (MTRRM) combining different functions to describe milk yield (MY) and fat (FP) and protein (PP) percentage in dairy goat genetic evaluation by using Bayesian inference. A total of 3,856 MY, FP, and PP test-day records, measured between 2000 and 2014, from 535 first lactations of Saanen and Alpine goats, including their cross, were used in this study. The initial analyses were performed using the following single-trait random regression models (STRRM): third- and fifth-order Legendre polynomials (Leg3 and Leg5), linear B-splines with 3 and 5 knots, the Ali and Schaeffer function (Ali), and Wilmink function. Heterogeneity of residual variances was modeled considering 3 classes. After the selection of the best STRRM to describe each trait on the basis of the deviance information criterion (DIC) and posterior model probabilities (PMP), the functions were combined to compose the MTRRM. All combined MTRRM presented lower DIC values and higher PMP, showing the superiority of these models when compared to other MTRRM based only on the same function assumed for all traits. Among the combined MTRRM, those considering Ali to describe MY and PP and Leg5 to describe FP (Ali_Leg5_Ali model) presented the best fit. From the Ali_Leg5_Ali model, heritability estimates over time for MY, FP. and PP ranged from 0.25 to 0.54, 0.27 to 0.48, and 0.35 to 0.51, respectively. Genetic correlation between MY and FP, MY and PP, and FP and PP ranged fro... Mostrar Tudo |
Palavras-Chave: |
Ali and Schaeffer function; B-splines; Deviance information criterion; Legendre polynomials; Posterior model probabilities; Wilmink function. |
Thesagro: |
Cabra leiteira; Leite; Método estatístico. |
Thesaurus NAL: |
Dairy goats; Milk yield; Statistical analysis. |
Categoria do assunto: |
X Pesquisa, Tecnologia e Engenharia |
Marc: |
LEADER 02889naa a2200361 a 4500 001 2047576 005 2016-06-21 008 2016 bl uuuu u00u1 u #d 024 7 $a10.2527/jas2015-0150$2DOI 100 1 $aOLIVEIRA, H. R. 245 $aCombining different functions to describe milk, fat, and protein yield in goats using Bayesian multiple-trait random regression models.$h[electronic resource] 260 $c2016 520 $aWe proposed multiple-trait random regression models (MTRRM) combining different functions to describe milk yield (MY) and fat (FP) and protein (PP) percentage in dairy goat genetic evaluation by using Bayesian inference. A total of 3,856 MY, FP, and PP test-day records, measured between 2000 and 2014, from 535 first lactations of Saanen and Alpine goats, including their cross, were used in this study. The initial analyses were performed using the following single-trait random regression models (STRRM): third- and fifth-order Legendre polynomials (Leg3 and Leg5), linear B-splines with 3 and 5 knots, the Ali and Schaeffer function (Ali), and Wilmink function. Heterogeneity of residual variances was modeled considering 3 classes. After the selection of the best STRRM to describe each trait on the basis of the deviance information criterion (DIC) and posterior model probabilities (PMP), the functions were combined to compose the MTRRM. All combined MTRRM presented lower DIC values and higher PMP, showing the superiority of these models when compared to other MTRRM based only on the same function assumed for all traits. Among the combined MTRRM, those considering Ali to describe MY and PP and Leg5 to describe FP (Ali_Leg5_Ali model) presented the best fit. From the Ali_Leg5_Ali model, heritability estimates over time for MY, FP. and PP ranged from 0.25 to 0.54, 0.27 to 0.48, and 0.35 to 0.51, respectively. Genetic correlation between MY and FP, MY and PP, and FP and PP ranged from −0.58 to 0.03, −0.46 to 0.12, and 0.37 to 0.64, respectively. We concluded that combining different functions under a MTRRM approach can be a plausible alternative for joint genetic evaluation of milk yield and milk constituents in goats. 650 $aDairy goats 650 $aMilk yield 650 $aStatistical analysis 650 $aCabra leiteira 650 $aLeite 650 $aMétodo estatístico 653 $aAli and Schaeffer function 653 $aB-splines 653 $aDeviance information criterion 653 $aLegendre polynomials 653 $aPosterior model probabilities 653 $aWilmink function 700 1 $aSILVA, F. F. 700 1 $aSIQUEIRA, O. H. G. B. D. 700 1 $aSOUZA, N. O. 700 1 $aJUNQUEIRA, V. S. 700 1 $aRESENDE, M. D. V. de 700 1 $aBORQUIS, R. R. A. 700 1 $aRODRIGUES, M. T. 773 $tJournal of Animal Science$gv. 94 n. 5, p. 1865-1874, May 2016.
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