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Registro Completo |
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Biblioteca(s): |
Embrapa Agroenergia. |
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Data corrente: |
11/11/2013 |
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Data da última atualização: |
21/09/2017 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
ABDELNUR, P. V.; VAZ, B. G.; ROCHA, J. D.; ALMEIDA, M. B. B. de; TEIXEIRA, M. A. G.; PEREIRA, R. C. L. |
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Afiliação: |
PATRICIA VERARDI ABDELNUR, CNPAE; Boniek G. Vaz, Universidade Federal do Goiás; JOSE DILCIO ROCHA, CNPAE; Marlon B. B. de Almeida, Petrobrás; Marco Antonio G. Teixeira, Petrobrás; Rosana C. L. Pereira, Petrobras. |
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Título: |
Characterization of bio-oils from different pyrolysis process steps and biomass using high-resolution mass spectrometry. |
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Ano de publicação: |
2013 |
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Fonte/Imprenta: |
Energy & Fuels, v. 27, n. 11, p. 6646-6654, 2013. |
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DOI: |
10.1021/ef400788v |
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Idioma: |
Inglês |
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Conteúdo: |
Next-generation biofuels have been widely investigated because they have particular advantages compared to first-generation biofuels. Pyrolysis is an example of a thermochemical route extensively used in oil and coal industries worldwide to produce these biofuels. Strategies for low-cost upgrading are among the biggest challenges facing the adoption of bio-oils in the development of commercial biofuels. Specific biomass sources could be the best option for generating bio-oil with the required properties. For this, it is necessary to understand the composition of these biomasses and their bio-oils. Here, we analyzed bio-oil samples from the fast pyrolysis of different biomasses collected during two different steps of the process by direct-infusion high-resolution mass spectrometry. First, a comparative study of two common high-resolution mass spectrometers, quadrupole time-of-flight mass spectrometry (Q-TOF MS) and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS), was performed to validate the methodology and to investigate the differences in mass discrimination and resolution. FT-ICR MS showed the best performance because of its unsurpassed resolution and accuracy. We apply the common petroleomics tools to interpret the mass spectra obtained. The FT-ICR MS analysis reveals that bio-oils are dominated by Ox species. The class profile of bio-oils was strongly affected by the biomass and steps of the pyrolysis process. |
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Palavras-Chave: |
Bio-oils. |
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Thesaurus Nal: |
biofuels; biomass. |
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Categoria do assunto: |
-- |
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Marc: |
LEADER 02155naa a2200229 a 4500
001 1970901
005 2017-09-21
008 2013 bl uuuu u00u1 u #d
024 7 $a10.1021/ef400788v$2DOI
100 1 $aABDELNUR, P. V.
245 $aCharacterization of bio-oils from different pyrolysis process steps and biomass using high-resolution mass spectrometry.$h[electronic resource]
260 $c2013
520 $aNext-generation biofuels have been widely investigated because they have particular advantages compared to first-generation biofuels. Pyrolysis is an example of a thermochemical route extensively used in oil and coal industries worldwide to produce these biofuels. Strategies for low-cost upgrading are among the biggest challenges facing the adoption of bio-oils in the development of commercial biofuels. Specific biomass sources could be the best option for generating bio-oil with the required properties. For this, it is necessary to understand the composition of these biomasses and their bio-oils. Here, we analyzed bio-oil samples from the fast pyrolysis of different biomasses collected during two different steps of the process by direct-infusion high-resolution mass spectrometry. First, a comparative study of two common high-resolution mass spectrometers, quadrupole time-of-flight mass spectrometry (Q-TOF MS) and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS), was performed to validate the methodology and to investigate the differences in mass discrimination and resolution. FT-ICR MS showed the best performance because of its unsurpassed resolution and accuracy. We apply the common petroleomics tools to interpret the mass spectra obtained. The FT-ICR MS analysis reveals that bio-oils are dominated by Ox species. The class profile of bio-oils was strongly affected by the biomass and steps of the pyrolysis process.
650 $abiofuels
650 $abiomass
653 $aBio-oils
700 1 $aVAZ, B. G.
700 1 $aROCHA, J. D.
700 1 $aALMEIDA, M. B. B. de
700 1 $aTEIXEIRA, M. A. G.
700 1 $aPEREIRA, R. C. L.
773 $tEnergy & Fuels$gv. 27, n. 11, p. 6646-6654, 2013.
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Embrapa Agroenergia (CNPAE) |
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| 1. |  | HUARTE-BONNET, C.; PAIXÃO, F. R. S. da; MASCARIN, G. M.; SANTANA, M.; FERNANDES, E. K. K.; PEDRINI, N. The entomopathogenic fungus Beauveria bassiana produces microsclerotia-like pellets mediated by oxidative stress and peroxisome biogenesis. Environmental Microbiology Reports, v. 11, n. 4, p. 518?524, 2019.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 2. | | PAIXÃO, F. R. S. da; HUARTE BONNET, C.; RIBEIRO-SILVA, C. de S.; MASCARIN, G. M.; FERNANDES, E. K. K.; PEDRINI, N. Tolerance to abiotic factors of microsclerotia and mycelial pellets from Metarhizium robertsii, and molecular and ultrastructural changes during microsclerotial differentiation. Frontiers in Fungal Biology, v. 2, Article 654737, 2021.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 4 |
| Biblioteca(s): Embrapa Meio Ambiente. |
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