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Registro Completo |
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Biblioteca(s): |
Embrapa Pecuária Sudeste. |
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Data corrente: |
28/08/2000 |
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Data da última atualização: |
17/01/2022 |
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Tipo da produção científica: |
Resumo em Anais de Congresso |
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Autoria: |
KAMOGAWA, M. Y.; NOGUEIRA, A. R. de A.; ARTIGAS, J.; ALONSO, J. |
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Afiliação: |
MARCOS Y. KAMOGAWA, UFSCAR; ANA RITA DE ARAUJO NOGUEIRA, CPPSE; JUDIT ARTIGAS, UNIVERSITAT AUTNNOMA DE BARCELONA; JULIÁN ALONSO, UNIVERSITAT AUTNNOMA DE BARCELONA. |
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Título: |
Soil calcareous efficiency using pervaporation coupled to a sequential injection system. |
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Ano de publicação: |
2000 |
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Fonte/Imprenta: |
In: INTERNATIONAL CONFERENCE ON FLOW ANALYSIS, 8., 2000, Warsaw. Warsaw: Polish Chemical Society, 2000. p.147. |
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Idioma: |
Português |
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Conteúdo: |
Acid soils normally require an amount of calcareous or other base to neutralise tlse acidity from the initial acidity occurs to selected less acidity. The following between theacidity components; with the enhanced amounts of exchangeable calcium and magnesium, an inactivation of exchangeable aluminium and the increase of the pH occur, giving most favourable plant growth. It is attained with the calcareous application. Huwever, the use of excessive doses of calcium carbonate, associated with the bad distribution and incorporation, can result in the decrease of other nutrients' readiness or the occurrence of some diseases. It is also sometime altered on the basis of economic con-siderations. The disolution of carbonate in acid and determination of the evolved CO> is one of the proposed methods for determining residual calcareous. In this work a sequential injection system coupled to a pervaporation unit for the CO ondutimetric determination is proposed. With the use of the pervaporation unit it was possible the use of soljQ samples without previous treatment. The proposed system was constructed with the use of a six way solenoid valve, a conductivity meter with an RS 232 connection and a PC microcomputer for data acquisition and externa! controls. The pre-concentration of the CO> evolved from the solid samples with the injection of 5.0 mL of 1.0 mol L ' HCI was done after passing through a Teflon" hydrophobic membrane. The COz was then captured by a water acceptor stream and directed to the detector. Amounts of 3.0 g of dry samples were directly weighted in the donor compartment of the pervaporation chamber. The CO~ amounts in the samples were determined with an analytical curve from 5.0x10 ' to 5.0x10' mol L ' of CO>. This curve was constructed with the matrix matching approach and showed a linear regression y=13.58+5S4.77x(R'=0.9962). Eleven soils with different lime amounts were analysed by the proposed methodology and the results were in accordance (slope 1.02+0.03; intersection 6+7) with the official method, that uses calcium difference between the total, extracted with HCI 1.0 mol L ' and exchangeable, extracted with the KCI 1.0 mol L '. The proposed method presented analytical frequency of 17 samples h ', detection lirnit of 8.0x10 ' mol L' of CO> and rsd < 3%, and the possibility of the residual calcareMenosAcid soils normally require an amount of calcareous or other base to neutralise tlse acidity from the initial acidity occurs to selected less acidity. The following between theacidity components; with the enhanced amounts of exchangeable calcium and magnesium, an inactivation of exchangeable aluminium and the increase of the pH occur, giving most favourable plant growth. It is attained with the calcareous application. Huwever, the use of excessive doses of calcium carbonate, associated with the bad distribution and incorporation, can result in the decrease of other nutrients' readiness or the occurrence of some diseases. It is also sometime altered on the basis of economic con-siderations. The disolution of carbonate in acid and determination of the evolved CO> is one of the proposed methods for determining residual calcareous. In this work a sequential injection system coupled to a pervaporation unit for the CO ondutimetric determination is proposed. With the use of the pervaporation unit it was possible the use of soljQ samples without previous treatment. The proposed system was constructed with the use of a six way solenoid valve, a conductivity meter with an RS 232 connection and a PC microcomputer for data acquisition and externa! controls. The pre-concentration of the CO> evolved from the solid samples with the injection of 5.0 mL of 1.0 mol L ' HCI was done after passing through a Teflon" hydrophobic membrane. The COz was then captured by a water acceptor stream and d... Mostrar Tudo |
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Palavras-Chave: |
Injeção seqüencial; Sequential injection; Sistema; Soil Calcareous; System. |
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Thesagro: |
Calcário; Solo. |
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Categoria do assunto: |
W Química e Física |
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URL: |
https://www.alice.cnptia.embrapa.br/alice/bitstream/doc/45116/1/digitalizar0003.pdf
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Marc: |
LEADER 03137nam a2200229 a 4500
001 1045116
005 2022-01-17
008 2000 bl uuuu u00u1 u #d
100 1 $aKAMOGAWA, M. Y.
245 $aSoil calcareous efficiency using pervaporation coupled to a sequential injection system.$h[electronic resource]
260 $aIn: INTERNATIONAL CONFERENCE ON FLOW ANALYSIS, 8., 2000, Warsaw. Warsaw: Polish Chemical Society, 2000. p.147.$c2000
520 $aAcid soils normally require an amount of calcareous or other base to neutralise tlse acidity from the initial acidity occurs to selected less acidity. The following between theacidity components; with the enhanced amounts of exchangeable calcium and magnesium, an inactivation of exchangeable aluminium and the increase of the pH occur, giving most favourable plant growth. It is attained with the calcareous application. Huwever, the use of excessive doses of calcium carbonate, associated with the bad distribution and incorporation, can result in the decrease of other nutrients' readiness or the occurrence of some diseases. It is also sometime altered on the basis of economic con-siderations. The disolution of carbonate in acid and determination of the evolved CO> is one of the proposed methods for determining residual calcareous. In this work a sequential injection system coupled to a pervaporation unit for the CO ondutimetric determination is proposed. With the use of the pervaporation unit it was possible the use of soljQ samples without previous treatment. The proposed system was constructed with the use of a six way solenoid valve, a conductivity meter with an RS 232 connection and a PC microcomputer for data acquisition and externa! controls. The pre-concentration of the CO> evolved from the solid samples with the injection of 5.0 mL of 1.0 mol L ' HCI was done after passing through a Teflon" hydrophobic membrane. The COz was then captured by a water acceptor stream and directed to the detector. Amounts of 3.0 g of dry samples were directly weighted in the donor compartment of the pervaporation chamber. The CO~ amounts in the samples were determined with an analytical curve from 5.0x10 ' to 5.0x10' mol L ' of CO>. This curve was constructed with the matrix matching approach and showed a linear regression y=13.58+5S4.77x(R'=0.9962). Eleven soils with different lime amounts were analysed by the proposed methodology and the results were in accordance (slope 1.02+0.03; intersection 6+7) with the official method, that uses calcium difference between the total, extracted with HCI 1.0 mol L ' and exchangeable, extracted with the KCI 1.0 mol L '. The proposed method presented analytical frequency of 17 samples h ', detection lirnit of 8.0x10 ' mol L' of CO> and rsd < 3%, and the possibility of the residual calcare<ius determination without samples pre-treatment.
650 $aCalcário
650 $aSolo
653 $aInjeção seqüencial
653 $aSequential injection
653 $aSistema
653 $aSoil Calcareous
653 $aSystem
700 1 $aNOGUEIRA, A. R. de A.
700 1 $aARTIGAS, J.
700 1 $aALONSO, J.
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Registro original: |
Embrapa Pecuária Sudeste (CPPSE) |
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| Registros recuperados : 13 | |
| 2. |  | LEMOS, S. G.; NOGUEIRA, A. R. A.; TORRE NETO, A.; ARTIGAS, J.; ALONSO, J. Estudos preliminares sobre o desenvolvimento e aplicação de sensores potenciométricos em análise de solos IN-SITU. In: ENCONTRO NACIONAL DE QUÍIMICA ANALÍTICA, 11., 2001, Campinas, SP. Desafios da química analítica no século XXI - anais. Campinas : ENQA, 2001. SR-3.| Biblioteca(s): Embrapa Instrumentação. |
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| 3. | | LEMOS, S. G.; NOGUEIRA, A. R. de A.; TORRE NETO, A.; ARTIGAS, J.; ALONSO, J. Estudos preliminares sobre o desenvolvimento e aplicação de sensores potenciométricos em análise de solos in-situ. In: ENCONTRO NACIONAL DE QUÍIMICA ANALÍTICA, 11., 2001, Campinas, SP. Desafios da química analítica no século XXI. Anais... Campinas: ENQA, 2001. SR-3.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Pecuária Sudeste. |
|  |
| 7. | | LEMOS, S. G.; NOGUEIRA, A. R. A.; FERREIRA, M. M. C.; TORRE-NETO, A.; ARTIGAS, J.; ALONSO, J. Emprego de sensores eletroquímicos no desenvolvimento de uma sonda para análise "in situ" de nitrato em solo. In: WORKSHOP DE PÓS-GRADUAÇÃO, 8., 2002, São Carlos. Livro de resumos... São Carlos: USP-IQSC, 2002. p. 73.| Biblioteca(s): Embrapa Instrumentação. |
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| 8. | | LEMOS, S. G.; NOGUEIRA, A. R. de A.; FERREIRA, M. M.; TORRE NETO, A.; ARTIGAS, J.; ALONSO, J. Emprego de sensores eletroquímicos no desenvolvimento de uma sonda para análise "in situ" de nitrato em solo. In: WORKSHOP DE PÓS-GRADUAÇÃO, 8., 2002, São Carlos, SP. Resumos... São Carlos: USP-IQSC, 2002. p.73.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Pecuária Sudeste. |
| |
| 9. | | LEMOS, S. G.; NOGUEIRA, A. R. de A.; TORRE NETO, A.; FERREIRA, M. M.; ARTIGAS, J.; ALONSO, J. Desenvolvimento e avaliação de protótipo empregando sensores potenciométricos na determinação de nitrato em solo. In: CONGRESSO BRASILEIRO DE CIÊNCIA DO SOLO, 29., 2003, Ribeirão Preto. Anais... Ribeirão Preto: UNESP: SBCS, 2003. 4 p. 1CD-ROM.| Tipo: Artigo em Anais de Congresso |
| Biblioteca(s): Embrapa Pecuária Sudeste. |
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| 10. | | LEMOS, S. J.; NOGUEIRA, A. R. A.; TORRE NETO, A.; FERREIRA, M. M. C.; ARTIGAS, J.; ALONSO, J. Desenvolvimento e avaliação de protótipo empregando sensores potenciométricos na determinação de nitrato em solo. In: CONGRESSO BRASILEIRO DE CIÊNCIA DO SOLO, 29., 2003, Ribeirão Preto. Solo: alicerce dos sistemas de produção. Ribeirão Preto: UNESP, 2003. 4 f. 1 CD-Rom.| Biblioteca(s): Embrapa Instrumentação. |
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| 11. | | ARTIGAS, J.; JIMENEZ, C.; LEMOS, S. G.; NOGUEIRA, A. R. de A.; TORRE NETO, A.; ALONSO, J. Development of a screen-printed thick film nitrate sensor based on a graphite-epoxy composite for agricultural applications. Sensors and Actuators part B, v. 88, n. 3, p. 337-344, 2003.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: Internacional - A |
| Biblioteca(s): Embrapa Pecuária Sudeste. |
|  |
| 13. | | LEMOS, S. G.; NOGUEIRA, A. R. de A.; TORRE NETO, A.; PARRA, A.; ARTIGAS, J.; ALONSO, J. In-soil potassium sensor system. Journal of Food Chemistry, v.52, n.19, p.5810-5815, 2004.| Tipo: Artigo em Periódico Indexado |
| Biblioteca(s): Embrapa Pecuária Sudeste. |
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| Registros recuperados : 13 | |
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| Nenhum registro encontrado para a expressão de busca informada. |
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