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Registro Completo |
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Biblioteca(s): |
Embrapa Meio Ambiente. |
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Data corrente: |
21/07/1999 |
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Data da última atualização: |
15/04/2019 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
AGBENIN, J. O.; ABREU, C. A. de; RAIJ, B. van. |
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Afiliação: |
JOHN O. AGBENIN; CLEIDE A. DE ABREU, IAC/CAMPINAS; BERNARDO VAN RAIJ, CNPMA. |
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Título: |
Extraction of phytoavailable trace metals from tropical soils by mixed ion exchange resin modified with inorganic and organic ligands. |
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Ano de publicação: |
1999 |
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Fonte/Imprenta: |
Science of the Total Environment, v.227, p.187-196, 1999. |
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Idioma: |
Inglês |
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Conteúdo: |
Chelating agents and organic acid ligands readily solubilize trace and heavy metals in soils. We compared Fe, Mn, Cu and Zn extracted from 16 soils by a mixed ion exchange resin (Amberlite IRA-120 + Amberlite IRA-400) modified with six simple inorganic and organic acid ligands with a conventional chelating agent (DTPA) and biossay. The mixed cation-anion exchange resins were saturated with Na-salts of chloride (R-CHL), bicarbonate (R-BIC), fluoride (R-FLU), acetate (R-ACT), citrate (R-CIT) and tartrate (R-TAR). Solubilization and adsorption of Fe and Cu from the soils By resin-ligand systems decreased in the order R-CIT >_ R-FLU >_ R-TAR = R-ACT > R-CHL = R-BIC reflecting differential stability of Fe- and Cu-organic/inorganic complexes. The R-CHL solubilized and adsorbed more Mn and Zn than other resin-ligand systems because of the relatively low pH maintained by the R-CHL-soil suspension. Extraction with DTPA gave similar amounts of Fe and Mn as resin-ligand systems, but DTPA extracted two to three times more Cu and Zn than resin. Resin-extractable Fe, Mn and Cu correlated with the corresponding DTPA-extractable metal contents, while both resin- and DTPA-extractable Cu correlated with the bioassay results. The R-ACT and R-TAR extractable Zn correlated more strongly with the biossay results than DTPA-extractable Zn. Mixed ion exchange resin is apparently feasible for characterizing plant available Fe, Mn, Cu and Zn in soils. |
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Palavras-Chave: |
Bioassay; Chemical extraction; Effect; Resin extraction. |
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Thesaurus Nal: |
agriculture; soil properties. |
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Categoria do assunto: |
-- |
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Marc: |
LEADER 02131naa a2200217 a 4500
001 1013137
005 2019-04-15
008 1999 bl uuuu u00u1 u #d
100 1 $aAGBENIN, J. O.
245 $aExtraction of phytoavailable trace metals from tropical soils by mixed ion exchange resin modified with inorganic and organic ligands.$h[electronic resource]
260 $c1999
520 $aChelating agents and organic acid ligands readily solubilize trace and heavy metals in soils. We compared Fe, Mn, Cu and Zn extracted from 16 soils by a mixed ion exchange resin (Amberlite IRA-120 + Amberlite IRA-400) modified with six simple inorganic and organic acid ligands with a conventional chelating agent (DTPA) and biossay. The mixed cation-anion exchange resins were saturated with Na-salts of chloride (R-CHL), bicarbonate (R-BIC), fluoride (R-FLU), acetate (R-ACT), citrate (R-CIT) and tartrate (R-TAR). Solubilization and adsorption of Fe and Cu from the soils By resin-ligand systems decreased in the order R-CIT >_ R-FLU >_ R-TAR = R-ACT > R-CHL = R-BIC reflecting differential stability of Fe- and Cu-organic/inorganic complexes. The R-CHL solubilized and adsorbed more Mn and Zn than other resin-ligand systems because of the relatively low pH maintained by the R-CHL-soil suspension. Extraction with DTPA gave similar amounts of Fe and Mn as resin-ligand systems, but DTPA extracted two to three times more Cu and Zn than resin. Resin-extractable Fe, Mn and Cu correlated with the corresponding DTPA-extractable metal contents, while both resin- and DTPA-extractable Cu correlated with the bioassay results. The R-ACT and R-TAR extractable Zn correlated more strongly with the biossay results than DTPA-extractable Zn. Mixed ion exchange resin is apparently feasible for characterizing plant available Fe, Mn, Cu and Zn in soils.
650 $aagriculture
650 $asoil properties
653 $aBioassay
653 $aChemical extraction
653 $aEffect
653 $aResin extraction
700 1 $aABREU, C. A. de
700 1 $aRAIJ, B. van
773 $tScience of the Total Environment$gv.227, p.187-196, 1999.
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| 1. |  | CARVALHO, L. R.; LEMOS, L. A.; VICENTE, M. P.; PINTO, D. dos S. C.; ORLANDI, L. O.; COELHO, M. C.; PIRES, M. de F. A.; SALES, J. N. de S.; CARVALHO, B. C. de. Oocyte quality of lactating dairy cows submitted to feed restriction and heat stress. Animal Reproduction, v. 21, n. 3, p. 100, 2024. Edição dos resumos da 37ª Annual Meeting of the Brazilian Embryo Technology Society, 2024, Atibaia, SP.| Tipo: Resumo em Anais de Congresso |
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