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Registro Completo |
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Biblioteca(s): |
Embrapa Agroenergia. |
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Data corrente: |
01/11/2022 |
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Data da última atualização: |
03/11/2022 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
JENSEN, A. T.; GAMBETTA, R.; MACHADO, F. |
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Afiliação: |
ALAN THYAGO JENSEN, UNIVERSIDADE DE BRASÍLIA; ROSSANO GAMBETTA, CNPAE; FABRICIO MACHADO, UNIVERSIDADE DE BRASÍLIA. |
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Título: |
A novel polyHIPE-like catalyst for esterification reactions: on the synthesis of sulfonated poly(styrene-co-n-acylglycerol) and its use for efficient conversion of oleic acid to methyl oleate. |
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Ano de publicação: |
2022 |
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Fonte/Imprenta: |
Macromolecular Reaction Engineering, 2200055, 2022. |
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DOI: |
10.1002/mren.202200055 |
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Idioma: |
Inglês |
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Conteúdo: |
The current work describes the synthesis of a new polyHIPE-like sulfonated poly(styrene-co-n-acylglycerol) and its use as an efficient heterogeneous catalyst to convert oleic acid into methyl oleate in esterification reactions. This new environmentally friendly polymer incorporates n-acylglycerol macromonomer as a versatile strategy for glycerol valorization. Macroporous micrometric polymer particles are synthesized through suspension polymerization process without using porogenic agents. polyHIPE-like copolymers formed with different feed compositions of styrene and n-acylglycerol are chemically modified via sulfonation reactions to form a highly efficient catalyst for esterification of oleic acid to methyl oleate, exhibiting conversions lying in the interval from 52% to 96%, depending mainly on the amount of n-acylglycerol macromonomer into the copolymer chains. The experimental results indicate the great potential of this new heterogeneous catalyst based on modified poly(styrene-co-n-acylglycerol) to be successfully employed in esterification reactions of vegetable oils intended for the production of long chain alkyl esters of carboxylic acids, widely used as biofuels. |
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Thesagro: |
Desenvolvimento Sustentável; Óleo Vegetal. |
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Thesaurus Nal: |
Biodiesel; Oleic acid; Vegetable oil. |
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Categoria do assunto: |
-- |
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Marc: |
LEADER 01939naa a2200217 a 4500
001 2147971
005 2022-11-03
008 2022 bl uuuu u00u1 u #d
024 7 $a10.1002/mren.202200055$2DOI
100 1 $aJENSEN, A. T.
245 $aA novel polyHIPE-like catalyst for esterification reactions$bon the synthesis of sulfonated poly(styrene-co-n-acylglycerol) and its use for efficient conversion of oleic acid to methyl oleate.$h[electronic resource]
260 $c2022
520 $aThe current work describes the synthesis of a new polyHIPE-like sulfonated poly(styrene-co-n-acylglycerol) and its use as an efficient heterogeneous catalyst to convert oleic acid into methyl oleate in esterification reactions. This new environmentally friendly polymer incorporates n-acylglycerol macromonomer as a versatile strategy for glycerol valorization. Macroporous micrometric polymer particles are synthesized through suspension polymerization process without using porogenic agents. polyHIPE-like copolymers formed with different feed compositions of styrene and n-acylglycerol are chemically modified via sulfonation reactions to form a highly efficient catalyst for esterification of oleic acid to methyl oleate, exhibiting conversions lying in the interval from 52% to 96%, depending mainly on the amount of n-acylglycerol macromonomer into the copolymer chains. The experimental results indicate the great potential of this new heterogeneous catalyst based on modified poly(styrene-co-n-acylglycerol) to be successfully employed in esterification reactions of vegetable oils intended for the production of long chain alkyl esters of carboxylic acids, widely used as biofuels.
650 $aBiodiesel
650 $aOleic acid
650 $aVegetable oil
650 $aDesenvolvimento Sustentável
650 $aÓleo Vegetal
700 1 $aGAMBETTA, R.
700 1 $aMACHADO, F.
773 $tMacromolecular Reaction Engineering, 2200055, 2022.
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Registro original: |
Embrapa Agroenergia (CNPAE) |
