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Registro Completo |
Biblioteca(s): |
Embrapa Florestas. |
Data corrente: |
12/11/2015 |
Data da última atualização: |
03/02/2016 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Autoria: |
MATTOS, B. D.; CADEMARTORI, P. H. G. de; MISSIO, A. L.; GATTO, D. A.; MAGALHAES, W. L. E. |
Afiliação: |
BRUNO D. MATTOS, Universidade Federal do Parana; PEDRO H. G. DE CADEMARTORI, Universidade Federal do Paraná; ANDRE L. MISSIO, Universidade Federal de Santa Maria; DARCI A. GATTO, Universidade Federal de Pelotas; WASHINGTON LUIZ ESTEVES MAGALHAES, CNPF. |
Título: |
Wood-polymer composites prepared by free radical in situ polymerization of methacrylate monomers into fast-growing pinewood. |
Ano de publicação: |
2015 |
Fonte/Imprenta: |
Wood Science and Technology, v. 49, n. 6, p. 1281-1294, Nov. 2015. |
DOI: |
10.1007/s00226-015-0761-5 |
Idioma: |
Inglês |
Conteúdo: |
The aim of this study was to evaluate treatability, morphology and mechanical resistance of composites prepared by in situ polymerization of methyl methacrylate on Pinus taeda wood using glycidyl methacrylate and methacrylic acid as cross-linkers. Treatment consisted of impregnation by vacuum/pressure and polymerization at 90 C for 10 h using heat catalyst. The treatability was characterized by loads of monomers, conversion of monomers to polymers, weight percent gain, permanent swelling, and densification. The morphology was characterized by SEM images, X-ray diffraction, confocal Raman microscopy, and mechanical properties by static bending, shore D hardness and brittleness tests. Composites with cross-linkers showed the highest monomers retention, and the highest conversion. Brittleness of the composites increased significantly, modulus of elasticity increased from 17 to 32 %, flexural strength increased by 22.4?45.3 %, and shore D hardness increased between 60.2 and 89.6 %. The GMA cross-linker provided the highest increments for mechanical resistance. |
Palavras-Chave: |
In situ polymerization; Metacrilato; Methacrylate; Pinewood; Polimerização in situ; Polímero; Tratamento de madeira; Wood polymer. |
Thesagro: |
Madeira; Pinus Taeda. |
Thesaurus Nal: |
wood treatment. |
Categoria do assunto: |
-- |
Marc: |
LEADER 02029naa a2200313 a 4500 001 2028471 005 2016-02-03 008 2015 bl uuuu u00u1 u #d 024 7 $a10.1007/s00226-015-0761-5$2DOI 100 1 $aMATTOS, B. D. 245 $aWood-polymer composites prepared by free radical in situ polymerization of methacrylate monomers into fast-growing pinewood.$h[electronic resource] 260 $c2015 520 $aThe aim of this study was to evaluate treatability, morphology and mechanical resistance of composites prepared by in situ polymerization of methyl methacrylate on Pinus taeda wood using glycidyl methacrylate and methacrylic acid as cross-linkers. Treatment consisted of impregnation by vacuum/pressure and polymerization at 90 C for 10 h using heat catalyst. The treatability was characterized by loads of monomers, conversion of monomers to polymers, weight percent gain, permanent swelling, and densification. The morphology was characterized by SEM images, X-ray diffraction, confocal Raman microscopy, and mechanical properties by static bending, shore D hardness and brittleness tests. Composites with cross-linkers showed the highest monomers retention, and the highest conversion. Brittleness of the composites increased significantly, modulus of elasticity increased from 17 to 32 %, flexural strength increased by 22.4?45.3 %, and shore D hardness increased between 60.2 and 89.6 %. The GMA cross-linker provided the highest increments for mechanical resistance. 650 $awood treatment 650 $aMadeira 650 $aPinus Taeda 653 $aIn situ polymerization 653 $aMetacrilato 653 $aMethacrylate 653 $aPinewood 653 $aPolimerização in situ 653 $aPolímero 653 $aTratamento de madeira 653 $aWood polymer 700 1 $aCADEMARTORI, P. H. G. de 700 1 $aMISSIO, A. L. 700 1 $aGATTO, D. A. 700 1 $aMAGALHAES, W. L. E. 773 $tWood Science and Technology$gv. 49, n. 6, p. 1281-1294, Nov. 2015.
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1. |  | GIACOMINI, J. P.; GALON, L.; CAVALETTI, D. C.; HENZ NETO, O. D.; SILVA, A. F. da; SENHORI, V. M.; HABOSKI, D. A.; PERIN, G. F. Interference and level of economic damage of soybean voluntary plants infesting bean. Advances in Weed Science, v. 42, e020240072, 2024.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 2 |
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