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 | Acesso ao texto completo restrito à biblioteca da Embrapa Pecuária Sudeste. Para informações adicionais entre em contato com cppse.biblioteca@embrapa.br. |
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Registro Completo |
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Biblioteca(s): |
Embrapa Pecuária Sudeste. |
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Data corrente: |
24/11/2004 |
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Data da última atualização: |
31/05/2022 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
FERNANDES, K. G.; NOGUEIRA, A. R. de A.; GOMES NETO, J. A.; NÓBREGA, J. A. |
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Afiliação: |
KELLY G. FERNANDES, UFSCAR; ANA RITA DE ARAUJO NOGUEIRA, CPPSE; JOSÉ A. GOMES NETO, UNESP; JOAQUIM A. NÓBREGA, UFSCAR. |
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Título: |
Determination of vanadium in urine by electrothermal atomic absorption spectrometry using hot injection and preconcentration into the graphite tube. |
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Ano de publicação: |
2004 |
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Fonte/Imprenta: |
Journal of Braziliand Chemical Society, v.15, n.5, p.676-681, 2004. |
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Idioma: |
Inglês |
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Conteúdo: |
In this work it was developed a procedure for the determination of vanadium in urine samples by electrothermal atomic absorption spectrometry using successive injections for preconcentration into a preheated graphite tube. Three 60?L volumes were sequentially injected into the atomizer preheated to a temperature of 110 ºC. Drying and pyrolysis steps were carried out after each injection. A chemical modifier, barium difluoride (100 mg L-1), and a surfactant, Triton X-100 (0.3% v v-1), were added to the urine sample. When injecting into a hot graphite tube, the sample flow-rate was 0.5?L s-1. The limits of detection and quantification were 0.54 and 1.82 without preconcentration, and 0.11 and 0.37 ?g L-1 with preconcentration, respectively. The accuracy of the procedure was evaluated by an addition-recovery experiment employing urine samples. Recoveries varied from 96.0 to 103% for additions ranging from 0.8 to 3.5 ?g L -1 V. The developed procedure allows the determination of vanadium in urine without any sample pretreatment and with minimal dilution of the sample. |
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Palavras-Chave: |
ETAAS; Hot injecction; Preconcentration. |
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Thesaurus Nal: |
urine; vanadium. |
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Categoria do assunto: |
W Química e Física |
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Marc: |
LEADER 01782naa a2200217 a 4500
001 1046881
005 2022-05-31
008 2004 bl uuuu u00u1 u #d
100 1 $aFERNANDES, K. G.
245 $aDetermination of vanadium in urine by electrothermal atomic absorption spectrometry using hot injection and preconcentration into the graphite tube.$h[electronic resource]
260 $c2004
520 $aIn this work it was developed a procedure for the determination of vanadium in urine samples by electrothermal atomic absorption spectrometry using successive injections for preconcentration into a preheated graphite tube. Three 60?L volumes were sequentially injected into the atomizer preheated to a temperature of 110 ºC. Drying and pyrolysis steps were carried out after each injection. A chemical modifier, barium difluoride (100 mg L-1), and a surfactant, Triton X-100 (0.3% v v-1), were added to the urine sample. When injecting into a hot graphite tube, the sample flow-rate was 0.5?L s-1. The limits of detection and quantification were 0.54 and 1.82 without preconcentration, and 0.11 and 0.37 ?g L-1 with preconcentration, respectively. The accuracy of the procedure was evaluated by an addition-recovery experiment employing urine samples. Recoveries varied from 96.0 to 103% for additions ranging from 0.8 to 3.5 ?g L -1 V. The developed procedure allows the determination of vanadium in urine without any sample pretreatment and with minimal dilution of the sample.
650 $aurine
650 $avanadium
653 $aETAAS
653 $aHot injecction
653 $aPreconcentration
700 1 $aNOGUEIRA, A. R. de A.
700 1 $aGOMES NETO, J. A.
700 1 $aNÓBREGA, J. A.
773 $tJournal of Braziliand Chemical Society$gv.15, n.5, p.676-681, 2004.
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Embrapa Pecuária Sudeste (CPPSE) |
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| 1. |  | ASCHERI, J. L. R.; NASCIMENTO, R. E.; LOUVAIN, T. S.; OUCHI, K.; PEREIRA, A. P. L. Utilizacao de penduculos de caju desidratados na elaboracao de pellets e farinha pre-gelatinizada por extrusao. In: SIMPOSIO LATINO AMERICANO DE CIENCIA DE ALIMENTOS, 3., 1999, Campinas, SP. Livro de resumos... Campinas, 1999. p. 215.| Biblioteca(s): Embrapa Agroindústria de Alimentos. |
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