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Registro Completo |
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
21/08/2023 |
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Data da última atualização: |
21/08/2023 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
PERES, L. G. S.; MALAFATTI, J. O. D.; BERNARDI, B.; MATTOSO, L. H. C.; PARIS, E. C. |
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Afiliação: |
UNIVERSIDADE FEDERAL DE SÃO CARLOS; National Nanotechnology Laboratory for Agriculture; UNIVERSIDADE FEDERAL DE SÃO CARLOS; LUIZ HENRIQUE CAPPARELLI MATTOSO, CNPDIA; ELAINE CRISTINA PARIS, CNPDIA. |
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Título: |
Biodegradable Starch Sachets Reinforced with Montmorillonite for Packing ZnO Nanoparticles: Solubility and Zn2+ Ions Release. |
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Ano de publicação: |
2023 |
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Fonte/Imprenta: |
Journal of Polymers and the Environment, v. 31, 2023. |
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Páginas: |
2388 - 2398 |
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DOI: |
https://doi.org/10.1007/s10924-023-02769-2 |
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Idioma: |
Inglês |
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Conteúdo: |
Agriculture?s importance in human lives and the economy has directed studies to improve crop production. An essential challenge for improving fertilizer efficacy is reducing losses due to leaching and increasing nutrient supplies. In this context, biodegradable sachets stand out as internal packaging instead of direct insertion into the polymer matrix, facilitating the system processing and making it easier to adapt the soil?s nutritional quantity. Thus, the present work aimed to increase the zinc oxide (ZnO) solubility by obtaining nanoparticles using top-down and bottom-up approaches and packaging them in montmorillonite (MMT) reinforced starch sachets. The different diameters and forms of the ZnO nanoparticles were evaluated to understand the solubility dependence on these parameters. In this way, the top-down process for the attritor milling method allowed the nanoparticles with about 71 nm average diameter and greater homogeneity than the commercial one (approximately 174 nm). The milled ZnO nanoparticles presented better solubility than those synthesized bottom-up processes and the commercial ones, reaching a 90 to 100% solubility plateau in 48 h. Concerning starch sachets, the 1% MMT (w w−1 ) insertion in the polymeric matrix promoted increased water vapor barrier and mechanical properties, improving tensile strength. In the solubility test for nanoparticulate ZnO packed in sachets, similar behaviors improved properties from the MMT reinforcement insertion showed as an alternative source of Zn2+ ions to minimize losses during application. MenosAgriculture?s importance in human lives and the economy has directed studies to improve crop production. An essential challenge for improving fertilizer efficacy is reducing losses due to leaching and increasing nutrient supplies. In this context, biodegradable sachets stand out as internal packaging instead of direct insertion into the polymer matrix, facilitating the system processing and making it easier to adapt the soil?s nutritional quantity. Thus, the present work aimed to increase the zinc oxide (ZnO) solubility by obtaining nanoparticles using top-down and bottom-up approaches and packaging them in montmorillonite (MMT) reinforced starch sachets. The different diameters and forms of the ZnO nanoparticles were evaluated to understand the solubility dependence on these parameters. In this way, the top-down process for the attritor milling method allowed the nanoparticles with about 71 nm average diameter and greater homogeneity than the commercial one (approximately 174 nm). The milled ZnO nanoparticles presented better solubility than those synthesized bottom-up processes and the commercial ones, reaching a 90 to 100% solubility plateau in 48 h. Concerning starch sachets, the 1% MMT (w w−1 ) insertion in the polymeric matrix promoted increased water vapor barrier and mechanical properties, improving tensile strength. In the solubility test for nanoparticulate ZnO packed in sachets, similar behaviors improved properties from the MMT reinforcement insertion showe... Mostrar Tudo |
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Palavras-Chave: |
Composite; Fertilizer; Sachets. |
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Categoria do assunto: |
-- |
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Marc: |
LEADER 02301naa a2200229 a 4500
001 2156029
005 2023-08-21
008 2023 bl uuuu u00u1 u #d
024 7 $ahttps://doi.org/10.1007/s10924-023-02769-2$2DOI
100 1 $aPERES, L. G. S.
245 $aBiodegradable Starch Sachets Reinforced with Montmorillonite for Packing ZnO Nanoparticles$bSolubility and Zn2+ Ions Release.$h[electronic resource]
260 $c2023
300 $a2388 - 2398
520 $aAgriculture?s importance in human lives and the economy has directed studies to improve crop production. An essential challenge for improving fertilizer efficacy is reducing losses due to leaching and increasing nutrient supplies. In this context, biodegradable sachets stand out as internal packaging instead of direct insertion into the polymer matrix, facilitating the system processing and making it easier to adapt the soil?s nutritional quantity. Thus, the present work aimed to increase the zinc oxide (ZnO) solubility by obtaining nanoparticles using top-down and bottom-up approaches and packaging them in montmorillonite (MMT) reinforced starch sachets. The different diameters and forms of the ZnO nanoparticles were evaluated to understand the solubility dependence on these parameters. In this way, the top-down process for the attritor milling method allowed the nanoparticles with about 71 nm average diameter and greater homogeneity than the commercial one (approximately 174 nm). The milled ZnO nanoparticles presented better solubility than those synthesized bottom-up processes and the commercial ones, reaching a 90 to 100% solubility plateau in 48 h. Concerning starch sachets, the 1% MMT (w w−1 ) insertion in the polymeric matrix promoted increased water vapor barrier and mechanical properties, improving tensile strength. In the solubility test for nanoparticulate ZnO packed in sachets, similar behaviors improved properties from the MMT reinforcement insertion showed as an alternative source of Zn2+ ions to minimize losses during application.
653 $aComposite
653 $aFertilizer
653 $aSachets
700 1 $aMALAFATTI, J. O. D.
700 1 $aBERNARDI, B.
700 1 $aMATTOSO, L. H. C.
700 1 $aPARIS, E. C.
773 $tJournal of Polymers and the Environment$gv. 31, 2023.
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| 4. |  | FILIMBERTI, E. L.; SOUZA, M. M. de; SILVA, C. da S.; TIESEN, C. M. A.; TARDIN, F. D.; SILVA, A. F. da. Comportamento produtivo de sorgo sacarino em função do arranjo de plantas In: JORNADA CIENTÍFICA DA EMBRAPA AGROSSILVIPASTORIL, 2.,2013, Sinop. Anais... Sinop, MT: Embrapa Agrossilvipastoril, 2013. 1 CD.| Tipo: Resumo em Anais de Congresso |
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