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 | Acesso ao texto completo restrito à biblioteca da Embrapa Instrumentação. Para informações adicionais entre em contato com cnpdia.biblioteca@embrapa.br. |
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Registro Completo |
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
15/10/2020 |
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Data da última atualização: |
11/12/2024 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
TADINI, A. M.; MOUNIER, S.; MILORI, D. M. B. P. |
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Afiliação: |
DEBORA MARCONDES BASTOS PEREIRA, CNPDIA. |
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Título: |
Modeling the quenching of fluorescence from organic matter in Amazonian soils. |
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Ano de publicação: |
2020 |
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Fonte/Imprenta: |
Science of the Total Environment, v. 698, 134067, 2020. |
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ISSN: |
0048-9697 |
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DOI: |
https://doi.org/10.1016/j.scitotenv.2019.134067 |
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Idioma: |
Inglês |
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Conteúdo: |
Knowledge of the interactions of soil organic matter (SOM) with metal species is important in order to obtain information concerning the fates of the metals in environment, whose reactive functional groups present in SOM can provide high complexation capacity. The aim of this study was to evaluate the interactions involving humic acids (HA) and fulvic acids (FA), extracted from Amazonian soils, with Cu(II) andAl(III) ions, using fluorescence quenching spectroscopy. The obtained results showed that the data for the humic fractions of the Amazonian Spodosols could be fitted with one to one complexation model, which provided the best representation of the changes in fluorescence quenching after addition of Cu(II) or Al (III) ions. It was found that the HA presented fewer complexation sites and lower stability constants, compared to the FA samples. Furthermore, the FA showed selective interaction with the metals, while the HA fraction was less selective and could be associated its homogeneous structure. The results showed that the humic acids required 10 times more carbon in their structures than fulvic acids for complexing a metal atom. This behavior can be associated to the fact that the Fulvic Acid fraction has higher mobility and greater interaction during the profile when compare humic acids. Hence, given the diversity of metals to which the HA has affinity, this soil fraction appears to be mainly responsible for soil fertility, while the FA fraction has higher mobility and greater interaction with water MenosKnowledge of the interactions of soil organic matter (SOM) with metal species is important in order to obtain information concerning the fates of the metals in environment, whose reactive functional groups present in SOM can provide high complexation capacity. The aim of this study was to evaluate the interactions involving humic acids (HA) and fulvic acids (FA), extracted from Amazonian soils, with Cu(II) andAl(III) ions, using fluorescence quenching spectroscopy. The obtained results showed that the data for the humic fractions of the Amazonian Spodosols could be fitted with one to one complexation model, which provided the best representation of the changes in fluorescence quenching after addition of Cu(II) or Al (III) ions. It was found that the HA presented fewer complexation sites and lower stability constants, compared to the FA samples. Furthermore, the FA showed selective interaction with the metals, while the HA fraction was less selective and could be associated its homogeneous structure. The results showed that the humic acids required 10 times more carbon in their structures than fulvic acids for complexing a metal atom. This behavior can be associated to the fact that the Fulvic Acid fraction has higher mobility and greater interaction during the profile when compare humic acids. Hence, given the diversity of metals to which the HA has affinity, this soil fraction appears to be mainly responsible for soil fertility, while the FA fraction has higher mobility and... Mostrar Tudo |
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Palavras-Chave: |
Amazonian Spodosol; Complexation; Humic fractions; Mobility. |
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Categoria do assunto: |
-- |
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Marc: |
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001 2125518
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008 2020 bl uuuu u00u1 u #d
022 $a0048-9697
024 7 $ahttps://doi.org/10.1016/j.scitotenv.2019.134067$2DOI
100 1 $aTADINI, A. M.
245 $aModeling the quenching of fluorescence from organic matter in Amazonian soils.$h[electronic resource]
260 $c2020
520 $aKnowledge of the interactions of soil organic matter (SOM) with metal species is important in order to obtain information concerning the fates of the metals in environment, whose reactive functional groups present in SOM can provide high complexation capacity. The aim of this study was to evaluate the interactions involving humic acids (HA) and fulvic acids (FA), extracted from Amazonian soils, with Cu(II) andAl(III) ions, using fluorescence quenching spectroscopy. The obtained results showed that the data for the humic fractions of the Amazonian Spodosols could be fitted with one to one complexation model, which provided the best representation of the changes in fluorescence quenching after addition of Cu(II) or Al (III) ions. It was found that the HA presented fewer complexation sites and lower stability constants, compared to the FA samples. Furthermore, the FA showed selective interaction with the metals, while the HA fraction was less selective and could be associated its homogeneous structure. The results showed that the humic acids required 10 times more carbon in their structures than fulvic acids for complexing a metal atom. This behavior can be associated to the fact that the Fulvic Acid fraction has higher mobility and greater interaction during the profile when compare humic acids. Hence, given the diversity of metals to which the HA has affinity, this soil fraction appears to be mainly responsible for soil fertility, while the FA fraction has higher mobility and greater interaction with water
653 $aAmazonian Spodosol
653 $aComplexation
653 $aHumic fractions
653 $aMobility
700 1 $aMOUNIER, S.
700 1 $aMILORI, D. M. B. P.
773 $tScience of the Total Environment$gv. 698, 134067, 2020.
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| 1. |  | CUADRA, S. V.; COSTA, M. H.; KUCHARIK, C. J.; ROCHA, H. R. da; TATSCH, J. D.; INMAN-BAMBER, G.; ROCHA, R. P. da; LEITE, C. C.; CABRAL, O. M. R. A biophysical model of Sugarcane growth. Global Change Biology. Bioenergy, v. 4, n. 1, p. 36-48, 2012.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 2 |
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