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Biblioteca(s): |
Embrapa Agricultura Digital. |
Data corrente: |
09/10/2018 |
Data da última atualização: |
07/01/2020 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Autoria: |
ASENSIO, V.; ABREU-JUNIOR, C. H.; SILVA, F. C. da; CHITOLINA, J. C. |
Afiliação: |
VERONICA ASENSIO, Cena/USP; CÁSSIO HAMILTON ABREU-JUNIOR, Cena/USP; FABIO CESAR DA SILVA, CNPTIA; JOSÉ CARLOS CHITOLINA, Fundação Municipal de Ensino de Piracicaba. |
Título: |
Evaluation of chemical extractants to assess metals phytoavailability in Brazilian municipal solid waste composts. |
Ano de publicação: |
2018 |
Fonte/Imprenta: |
Environmental Pollution, v. 243, Part B, p. 1235-1241, Dec. 2018. |
DOI: |
https://doi.org/10.1016/j.envpol.2018.09.100 |
Idioma: |
Inglês |
Conteúdo: |
Municipal solid wastes (MSW) can be composted to become an organic fertilizer. However, besides plant nutrients, it can also contain high concentration of some toxic metals than can pollute agricultural soils, contaminate food, animals and human being. A greenhouse experiment was carried out for two purposes: i) to evaluate the concentrations of cadmium, copper, chromium, nickel, lead and zinc in four Brazilian MSW composts, and, ii) to know which is the best solution for extracting those metals in phytoavailable form from the composts. In order to evaluate the phytoavailability of metals, they were extracted with six chemical extractants: i) water, ii) 0.05 mol L-1 Ca(NO3)2, iii) 0.1 mol L-1 HCl, iv) 0.005 mol L-1 DTPA at pH 7.3, v) 0.05 mol L-1 CaCl2 and vi) Mehlich 3 solution. In addition, lettuces were cultivated as a test plant in pots containing 1.8 kg of MSW compost as substrate. Fifty-six days later, lettuce plants were harvested. New lettuces were then planted for a second cycle, and then harvested after fifty-six days. Semi-total concentration of metals in composts and total in plants was also determined through an extraction with nitric-perchloric acid. Semi-total concentration of Cd and Pb exceeded the intervention limits from Brazil in the four studied composts, and lettuce plants were polluted by those two elements. Therefore, compost made of MSW must be characterized before being used for agricultural soils. Copper and nickel in phytoavailable were effectively extracted with the strongest chelating agents used, HCl and Mehlich 3, probably because most metal is bound to organic matter in the compost. Cadmium, chromium, lead and zinc were no efficiently extracted with any of the tested extractants. MenosMunicipal solid wastes (MSW) can be composted to become an organic fertilizer. However, besides plant nutrients, it can also contain high concentration of some toxic metals than can pollute agricultural soils, contaminate food, animals and human being. A greenhouse experiment was carried out for two purposes: i) to evaluate the concentrations of cadmium, copper, chromium, nickel, lead and zinc in four Brazilian MSW composts, and, ii) to know which is the best solution for extracting those metals in phytoavailable form from the composts. In order to evaluate the phytoavailability of metals, they were extracted with six chemical extractants: i) water, ii) 0.05 mol L-1 Ca(NO3)2, iii) 0.1 mol L-1 HCl, iv) 0.005 mol L-1 DTPA at pH 7.3, v) 0.05 mol L-1 CaCl2 and vi) Mehlich 3 solution. In addition, lettuces were cultivated as a test plant in pots containing 1.8 kg of MSW compost as substrate. Fifty-six days later, lettuce plants were harvested. New lettuces were then planted for a second cycle, and then harvested after fifty-six days. Semi-total concentration of metals in composts and total in plants was also determined through an extraction with nitric-perchloric acid. Semi-total concentration of Cd and Pb exceeded the intervention limits from Brazil in the four studied composts, and lettuce plants were polluted by those two elements. Therefore, compost made of MSW must be characterized before being used for agricultural soils. Copper and nickel in phytoavailable were effectively... Mostrar Tudo |
Palavras-Chave: |
Chemical extractants; Metal phytoavailability; Municipal solid waste compost. |
Thesagro: |
Alface; Cobre; Resíduo Solido. |
Thesaurus Nal: |
Copper; Lettuce; Municipal solid waste. |
Categoria do assunto: |
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Registro original: |
Embrapa Agricultura Digital (CNPTIA) |
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1. |  | KULCHESKI, F. R.; OLIVEIRA, L. F. V.; MOLINA, L. G.; ALMERAO, M. P.; RODRIGUES, F. A.; MARCOLINO, J.; BARBOSA, J. F.; STOLF-MOREIRA, R.; NEPOMUCENO, A. L.; MARCELINO-GUIMARÃES, F. C.; ABDELNOOR, R. V.; NASCIMENTO, L. C.; CARAZZOLLE, M. F.; PEREIRA, G. A. G.; MARGIS, R. Identification of novel soybean microRNAs involved in abiotic and biotic stresses. BMC Genomics, v. 12, article 307, jun. 2011. 17 p.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
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