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 | Acesso ao texto completo restrito à biblioteca da Embrapa Pecuária Sudeste. Para informações adicionais entre em contato com cppse.biblioteca@embrapa.br. |
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Registro Completo |
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Biblioteca(s): |
Embrapa Pecuária Sudeste. |
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Data corrente: |
17/12/2019 |
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Data da última atualização: |
17/12/2019 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
NEIVA, A. M.; SPERANÇA, M. A.; COSTA, V. C.; JACINTO, M. A. C.; PEREIRA-FILHO, E. R. |
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Afiliação: |
Ariane Maciel Neiva, UFSCar; Marco Aurélio Sperança, UFSCar; Vinicius Câmara Costa, UFSCar; MANUEL ANTONIO CHAGAS JACINTO, CPPSE; Edenir Rodrigues Pereira-Filho, UFSCar. |
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Título: |
Determination of toxic metals in leather by wavelength dispersive X-ray fluorescence (WDXRF) and inductively coupled plasma optical emission spectrometry (ICP OES) with emphasis on chromium. |
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Ano de publicação: |
2018 |
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Fonte/Imprenta: |
Environmental Monitoring and Assessment, v.190, n.168, p.1-15, 2018. |
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DOI: |
https://doi.org/10.1007/s10661-018-6990-y |
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Idioma: |
Inglês |
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Conteúdo: |
The tanning industry is one of the largest environmental polluters due to high generation waste in all production processes, but the tanning is particularly worrisome due to the use of significant amounts of chromium. Cr is an element potentially toxic to both health and the environment, depending on the concentration and the oxidation state. Cr(VI) can come in contact with human skin when using leather goods, which can cause allergies and dermatitis, besides being carcinogenic. Considering that approximately 90% of the world production of leather is performed with Cr salts, the determination of this element in leather is necessary to avoid exposure to the risks that the element can provide. The main goal of this study was the development of an alternative analytical method for the determination of Cr in leathers (ovine and bovine leather tanned with Cr and vegetable tannin) using wavelength dispersive X-ray fluorescence (WDXRF) for direct solid analysis. Besides performing analysis of the chemical composition and determination of Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Ni, Pb, Sb, Sr, Ti, and Zn in leather by inductively coupled plasma optical emission spectrometry (ICP OES). Principal component analysis (PCA) was also used in the evaluation of the WDXRF and ICP OES data sets. WDXRF calibration models for Cr presented satisfactory figures of merit and the analysis of the leathers revealed an alarming concentration of total Cr in the samples reaching 21,353 mg kg?1. |
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Palavras-Chave: |
Cr; Direct solid analysis; Inductively coupled plasma atomic emission spectrometry (ICP OES); Laser-induced breakdown spectroscopy (LIBS); Wavelength dispersive X-ray fluorescence (WDXRF). |
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Thesaurus Nal: |
Leather. |
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Categoria do assunto: |
X Pesquisa, Tecnologia e Engenharia |
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Marc: |
LEADER 02474naa a2200253 a 4500
001 2117090
005 2019-12-17
008 2018 bl uuuu u00u1 u #d
024 7 $ahttps://doi.org/10.1007/s10661-018-6990-y$2DOI
100 1 $aNEIVA, A. M.
245 $aDetermination of toxic metals in leather by wavelength dispersive X-ray fluorescence (WDXRF) and inductively coupled plasma optical emission spectrometry (ICP OES) with emphasis on chromium.$h[electronic resource]
260 $c2018
520 $aThe tanning industry is one of the largest environmental polluters due to high generation waste in all production processes, but the tanning is particularly worrisome due to the use of significant amounts of chromium. Cr is an element potentially toxic to both health and the environment, depending on the concentration and the oxidation state. Cr(VI) can come in contact with human skin when using leather goods, which can cause allergies and dermatitis, besides being carcinogenic. Considering that approximately 90% of the world production of leather is performed with Cr salts, the determination of this element in leather is necessary to avoid exposure to the risks that the element can provide. The main goal of this study was the development of an alternative analytical method for the determination of Cr in leathers (ovine and bovine leather tanned with Cr and vegetable tannin) using wavelength dispersive X-ray fluorescence (WDXRF) for direct solid analysis. Besides performing analysis of the chemical composition and determination of Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Ni, Pb, Sb, Sr, Ti, and Zn in leather by inductively coupled plasma optical emission spectrometry (ICP OES). Principal component analysis (PCA) was also used in the evaluation of the WDXRF and ICP OES data sets. WDXRF calibration models for Cr presented satisfactory figures of merit and the analysis of the leathers revealed an alarming concentration of total Cr in the samples reaching 21,353 mg kg?1.
650 $aLeather
653 $aCr
653 $aDirect solid analysis
653 $aInductively coupled plasma atomic emission spectrometry (ICP OES)
653 $aLaser-induced breakdown spectroscopy (LIBS)
653 $aWavelength dispersive X-ray fluorescence (WDXRF)
700 1 $aSPERANÇA, M. A.
700 1 $aCOSTA, V. C.
700 1 $aJACINTO, M. A. C.
700 1 $aPEREIRA-FILHO, E. R.
773 $tEnvironmental Monitoring and Assessment$gv.190, n.168, p.1-15, 2018.
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Registro original: |
Embrapa Pecuária Sudeste (CPPSE) |
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Registro Completo
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Biblioteca(s): |
Embrapa Amazônia Oriental. |
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Data corrente: |
07/12/2010 |
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Data da última atualização: |
05/04/2011 |
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Tipo da produção científica: |
Resumo em Anais de Congresso |
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Autoria: |
OLIVEIRA, R. R. S. de; WATRIN, O. dos S.; SAMPAIO, S. M. N.; PIMENTEL, G. M. |
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Afiliação: |
RODRIGO RAFAEL SOUZA DE OLIVEIRA, BOLSISTA EMBRAPA/UFPA; ORLANDO DOS SANTOS WATRIN, CPATU; SANDRA MARIA NEIVA SAMPAIO, CPATU; GUSTAVO MARTINEZ PIMENTEL, BOLSISTA EMBRAPA/UFPA. |
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Título: |
Análise espaço-temporal do uso da terra em duas mesobacias no Nordeste paraense. |
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Ano de publicação: |
2010 |
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Fonte/Imprenta: |
In: SEMINÁRIO GESTABACIAS, 1., 2010, Belém, PA. Resultados de pesquisas em mesobacias do Nordeste paraense e sua aplicação no desenvolvimento rural. Belém, PA: Embrapa Amazônia Oriental: Projeto Gestabacias, 2010. |
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Descrição Física: |
1 CD-ROM. |
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Idioma: |
Português |
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Palavras-Chave: |
Análise multitemporal da paisagem. |
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Thesagro: |
Bacia Hidrográfica; Sensoriamento Remoto. |
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Categoria do assunto: |
-- |
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URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/item/29957/1/RODRIGO-OLIVEIRA.pdf
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Marc: |
LEADER 00744nam a2200181 a 4500
001 1868948
005 2011-04-05
008 2010 bl uuuu u00u1 u #d
100 1 $aOLIVEIRA, R. R. S. de
245 $aAnálise espaço-temporal do uso da terra em duas mesobacias no Nordeste paraense.
260 $aIn: SEMINÁRIO GESTABACIAS, 1., 2010, Belém, PA. Resultados de pesquisas em mesobacias do Nordeste paraense e sua aplicação no desenvolvimento rural. Belém, PA: Embrapa Amazônia Oriental: Projeto Gestabacias$c2010
300 $c1 CD-ROM.
650 $aBacia Hidrográfica
650 $aSensoriamento Remoto
653 $aAnálise multitemporal da paisagem
700 1 $aWATRIN, O. dos S.
700 1 $aSAMPAIO, S. M. N.
700 1 $aPIMENTEL, G. M.
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