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Registro Completo |
Biblioteca(s): |
Embrapa Instrumentação. |
Data corrente: |
28/03/2005 |
Data da última atualização: |
28/03/2005 |
Autoria: |
SAAB, S. C.; MARTIN-NETO, L. |
Título: |
Use of the EPR technique to determine thermal stability of some humified organic substances found in soil organic-mineral fractions. |
Ano de publicação: |
2003 |
Fonte/Imprenta: |
Química Nova, v. 26, n. 4. p. 497-498, 2003. |
Idioma: |
Inglês |
Conteúdo: |
In this work, using the EPR spectroscopy, we analysed the thermal stability of some organic-mineral compounds found in a Gleysoil from Rio Janeiro. It was observed a complete disappearance of the EPR signal around 600 °C for the < 2 µm fraction and a residual EPR signal of semiquinone free radical for the 2-20 µm and 20-53 µm fractions at the same temperature. Also, the experiments showed that the 2-20 µm fraction had a larger concentration of semiquinone free radical per g of carbon and a smaller line width indicated a larger humification of this fraction. This is an evidence that the soil organic matter of this fraction (2-20 µm) is more stable than the other ones.
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Palavras-Chave: |
Estabilização; Matéria orgânica do solo; Radicais livres. |
Categoria do assunto: |
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Marc: |
LEADER 01221naa a2200169 a 4500 001 1028885 005 2005-03-28 008 2003 bl --- 0-- u #d 100 1 $aSAAB, S. C. 245 $aUse of the EPR technique to determine thermal stability of some humified organic substances found in soil organic-mineral fractions. 260 $c2003 520 $aIn this work, using the EPR spectroscopy, we analysed the thermal stability of some organic-mineral compounds found in a Gleysoil from Rio Janeiro. It was observed a complete disappearance of the EPR signal around 600 °C for the < 2 µm fraction and a residual EPR signal of semiquinone free radical for the 2-20 µm and 20-53 µm fractions at the same temperature. Also, the experiments showed that the 2-20 µm fraction had a larger concentration of semiquinone free radical per g of carbon and a smaller line width indicated a larger humification of this fraction. This is an evidence that the soil organic matter of this fraction (2-20 µm) is more stable than the other ones. 653 $aEstabilização 653 $aMatéria orgânica do solo 653 $aRadicais livres 700 1 $aMARTIN-NETO, L. 773 $tQuímica Nova$gv. 26, n. 4. p. 497-498, 2003.
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Embrapa Instrumentação (CNPDIA) |
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