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Registro Completo |
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Biblioteca(s): |
Embrapa Pecuária Sudeste. |
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Data corrente: |
10/11/2010 |
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Data da última atualização: |
19/07/2011 |
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Tipo da produção científica: |
Resumo em Anais de Congresso |
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Autoria: |
CARAPELLI, R.; GUERRA, M. B. B.; MIRANDA, K. dos A. de; PEREIRA FILHO, E. R.; NOGUEIRA, A. R. de A. |
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Afiliação: |
RODOLFO CARAPELLI, UFSCar/SÃO CARLOS, SP; MARCELO BRAGA BUENO GUERRA, UFSCar/SÃO CARLOS, SP; KELBER DOS ANJOS DE MIRANDA, UFSCar/SÃO CARLOS, SP; EDENIR RODRIGUES PEREIRA FILHO, UFSCar/SÃO CARLOS, SP; ANA RITA DE ARAUJO NOGUEIRA, CPPSE. |
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Título: |
Potentialities of hydride generation atomic absorption spectrometry (HGAAS) in the fast sequential determination of AS, BI and SB. |
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Ano de publicação: |
2010 |
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Fonte/Imprenta: |
In: RIO SYMPOSIUM ON ATOMIC SPECTROMETRY, 11., 2010, Mar del Prata: Horiba, 2010. |
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Páginas: |
p. 169 |
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Idioma: |
Português |
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Conteúdo: |
In this study, a sensitive hydride generation method was combined with fast sequential flame atomic absorption spectrometry (FS-FAAS) for the sequential determination of As, Bi and Sb in water samples. A Doehlert design was performed to identify a compromise condition to determine sequentially the three elements. The best condition was reached using NaBH40.8 % mv-1as the reducing agent. Another four variables were also tested: HCI concentration as the carrier solution (2 to 10 mol L-1), KI concentration as the pre-reductor solution (1 to 7 % mv-1), employment of ascorbic acid (0 to 6 % mv-1) as auxiliary pre-reductor, and integration time (3 replicates of 0.5 to 2 s). All these evaluated conditions were not significant at the investigated levels. Therefore, the optimized parameters were: HCI 6 mol L-1 in order to avoid interferences from the matrix, KI 1 % mv-1 without ascorbic acid to reduce reagent consumption and waste generation, finally, because of the lower delay time (20s) of the measurements, integration time of 1 s with 5 replicates was employed to precision improvement. That delay time was chosen as the minimum time to signal stabilization after the entire signal profile examination. The linear ranges were from 0.5 to 1 0 ~g L-1 of As, Bi and Sb. The accuracy of the proposed method was checked using two Certified Reference Materials (CRM) related with trace metals in water, HPS-TMDW and NIST 1643e. The results obtained for both CRM were in agreement with the certified value, with the following recoveries: As (average of 76%), Bi (average of 104%), Sb (average of 89 %).The proposed method has several advantages for routine analysis of As, Bi and Sb in water such as: good sensitivity (LaD: 0.132mg L- 1for As, 0.088mg L-1for Bi and 0.110mg L-1for Sb; n=10), high analytical throughput (270 determinations per hour), and low reagent consumption when compared with single elements determinations. MenosIn this study, a sensitive hydride generation method was combined with fast sequential flame atomic absorption spectrometry (FS-FAAS) for the sequential determination of As, Bi and Sb in water samples. A Doehlert design was performed to identify a compromise condition to determine sequentially the three elements. The best condition was reached using NaBH40.8 % mv-1as the reducing agent. Another four variables were also tested: HCI concentration as the carrier solution (2 to 10 mol L-1), KI concentration as the pre-reductor solution (1 to 7 % mv-1), employment of ascorbic acid (0 to 6 % mv-1) as auxiliary pre-reductor, and integration time (3 replicates of 0.5 to 2 s). All these evaluated conditions were not significant at the investigated levels. Therefore, the optimized parameters were: HCI 6 mol L-1 in order to avoid interferences from the matrix, KI 1 % mv-1 without ascorbic acid to reduce reagent consumption and waste generation, finally, because of the lower delay time (20s) of the measurements, integration time of 1 s with 5 replicates was employed to precision improvement. That delay time was chosen as the minimum time to signal stabilization after the entire signal profile examination. The linear ranges were from 0.5 to 1 0 ~g L-1 of As, Bi and Sb. The accuracy of the proposed method was checked using two Certified Reference Materials (CRM) related with trace metals in water, HPS-TMDW and NIST 1643e. The results obtained for both CRM were in agreement with the certif... Mostrar Tudo |
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Palavras-Chave: |
Atomic absorption; BS, BI, SB; Spectrometry (HAAGS). |
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Categoria do assunto: |
W Química e Física |
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URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/item/37794/1/PROCI-2010.00197.pdf
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Marc: |
LEADER 02611nam a2200205 a 4500
001 1866644
005 2011-07-19
008 2010 bl uuuu u00u1 u #d
100 1 $aCARAPELLI, R.
245 $aPotentialities of hydride generation atomic absorption spectrometry (HGAAS) in the fast sequential determination of AS, BI and SB.
260 $aIn: RIO SYMPOSIUM ON ATOMIC SPECTROMETRY, 11., 2010, Mar del Prata: Horiba$c2010
300 $ap. 169
520 $aIn this study, a sensitive hydride generation method was combined with fast sequential flame atomic absorption spectrometry (FS-FAAS) for the sequential determination of As, Bi and Sb in water samples. A Doehlert design was performed to identify a compromise condition to determine sequentially the three elements. The best condition was reached using NaBH40.8 % mv-1as the reducing agent. Another four variables were also tested: HCI concentration as the carrier solution (2 to 10 mol L-1), KI concentration as the pre-reductor solution (1 to 7 % mv-1), employment of ascorbic acid (0 to 6 % mv-1) as auxiliary pre-reductor, and integration time (3 replicates of 0.5 to 2 s). All these evaluated conditions were not significant at the investigated levels. Therefore, the optimized parameters were: HCI 6 mol L-1 in order to avoid interferences from the matrix, KI 1 % mv-1 without ascorbic acid to reduce reagent consumption and waste generation, finally, because of the lower delay time (20s) of the measurements, integration time of 1 s with 5 replicates was employed to precision improvement. That delay time was chosen as the minimum time to signal stabilization after the entire signal profile examination. The linear ranges were from 0.5 to 1 0 ~g L-1 of As, Bi and Sb. The accuracy of the proposed method was checked using two Certified Reference Materials (CRM) related with trace metals in water, HPS-TMDW and NIST 1643e. The results obtained for both CRM were in agreement with the certified value, with the following recoveries: As (average of 76%), Bi (average of 104%), Sb (average of 89 %).The proposed method has several advantages for routine analysis of As, Bi and Sb in water such as: good sensitivity (LaD: 0.132mg L- 1for As, 0.088mg L-1for Bi and 0.110mg L-1for Sb; n=10), high analytical throughput (270 determinations per hour), and low reagent consumption when compared with single elements determinations.
653 $aAtomic absorption
653 $aBS, BI, SB
653 $aSpectrometry (HAAGS)
700 1 $aGUERRA, M. B. B.
700 1 $aMIRANDA, K. dos A. de
700 1 $aPEREIRA FILHO, E. R.
700 1 $aNOGUEIRA, A. R. de A.
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Registro original: |
Embrapa Pecuária Sudeste (CPPSE) |
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| Registros recuperados : 34 | |
| 4. |  | SILVA, A. B. S. da; PEREIRA FILHO, E. R.; NOGUEIRA, A. R. de A. Direct determination of TiO2 as Ti used as digestibility marker in bovine faeces by Laser-Induced Breakdown Spectroscopy (LIBS). In: COLLOQUIUM SPECTROSCOPICUM INTERNATIONALE, 40., EURO-MEDITERRANEAN SYMPOSIUM ON LIBS, 9., 2017, Pisa, Italy. Proceedings... Pisa, Italy: IUPAC, 2017. p. 52.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Pecuária Sudeste. |
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| 13. | | DIB, S. R.; TULLIO, R. R.; NASSU, R. T.; PEREIRA FILHO, E. R.; NOGUEIRA, A. R. de A. Determinação de metais por técnicas espectroanalíticas em amostras de carne e sangue de bovinos submetidos à dieta com adição de erva-mate (Ilex paraguariensis, St. Hilaire). In: ENCONTRO NACIONAL DE QUÍMICA ANALÍTICA, 18., 2016, Florianópolis. Anais... Florianópolis: SBQ, 2016.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Pecuária Sudeste. |
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| 16. | | COUTINHO, H. L. C.; LIGO, M. A. V.; . NOVELLI, A. F.; BETTANIN, V. C.; PEREIRA FILHO, E. R. Monitoramento da população de microrganismos amonificadores e nitrificadores e de taxas de amonificação e nitrificação em solos sob cultivo de cana-de-açúcar na região de Ribeirão Preto, SP. In: CONGRESSO LATINO-AMERICANO DE CIENCIA DO SOLO, 13., 1996, Aguas de Lindoia. Resumos. Piracicaba: ESALQ / SBCS, 1996. CD-ROM.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 17. | | GONZALEZ, M. H.; OLIVEIRA, R. V.; PEREIRA FILHO, E. R.; NÓBREGA, J. A.; NOGUEIRA, A. R. de A. Otimização da separação de isômeros de ácidos nitrobenzóicos resultantes da digestão ácida de materiais biológicos. In: ENCONTRO NACIONAL DE QUÍMICA ANALÍTICA, 14., 2007, João Pessoa, PB. Anais... João Pessoa: SBQA, 2007. 1 CD-ROM.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Pecuária Sudeste. |
|  |
| 18. | | GONZALES, M. H.; OLIVEIRA, R. V.; PEREIRA FILHO, E. R.; NÓBREGA, J. A; NOGUEIRA, A. R. de A. Quantificação de NBA's provenientes da digestão ácida de materiais biológicos assistida por radiação micro-ondas. In: ENCONTRO NACIONAL DE QUÍMICA ANALÍTICA, 15.; CONGRESSO IBEROAMERICANO DE QUÍMICA ANALÍTICA, 3., 2009, Salvador, BA. Anais... Salvador: SBQ: UFBA, 2009.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Pecuária Sudeste. |
| |
| 20. | | CARAPELLI, R.; GUERRA, M. B. B.; MIRANDA, K. dos A. de; PEREIRA FILHO, E. R.; NOGUEIRA, A. R. de A. Potentialities of hydride generation atomic absorption spectrometry (HGAAS) in the fast sequential determination of AS, BI and SB. In: RIO SYMPOSIUM ON ATOMIC SPECTROMETRY, 11., 2010, Mar del Prata: Horiba, 2010. p. 169| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Pecuária Sudeste. |
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| Registros recuperados : 34 | |
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| Nenhum registro encontrado para a expressão de busca informada. |
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