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Biblioteca(s): |
Embrapa Solos. |
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Data corrente: |
12/02/2014 |
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Data da última atualização: |
10/11/2021 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
AGUIAR, N. O.; NOVOTNY, E. H.; OLIVEIRA, A. L.; RUMJANEK, V. M.; OLIVARES, F. L.; CANELLAS, L. P. |
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Afiliação: |
Núcleo de Desenvolvimento de Insumos Biológicos para a Agricultura (Nudiba), Universidade Estadual do Norte Fluminense Darcy Ribeiro (UENF); ETELVINO HENRIQUE NOVOTNY, CNPS; Laboratório de Química do Núcleo de Criminalística da Superintendência da Polícia Federal no Estado do Rio de Janeiro; Laboratório de Química do Núcleo de Criminalística da Superintendência da Polícia Federal no Estado do Rio de Janeiro; Núcleo de Desenvolvimento de Insumos Biológicos para a Agricultura (Nudiba), Universidade Estadual do Norte Fluminense Darcy Ribeiro (UENF); L.P. Canellas, Núcleo de Desenvolvimento de Insumos Biológicos para a Agricultura (Nudiba), Universidade Estadual do Norte Fluminense Darcy Ribeiro (UENF). |
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Título: |
Prediction of humic acids bioactivity using spectroscopy and multivariate analysis. |
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Ano de publicação: |
2013 |
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Fonte/Imprenta: |
Journal of Geochemical Exploration, v. 129, p. 95-102, Jun. 2013. |
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DOI: |
https://doi.org/10.1016/j.gexplo.2012.10.005 |
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Idioma: |
Inglês |
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Conteúdo: |
Humic substances (HS) represent the organic material most widespread in nature and have positive effects on plant physiology influencing nutrient uptake and root architecture. Understanding the structure-activity relationship has been considered an essential step to drive technological approaches to produce HS with enhanced plant growth promotion performance. In this studywe used solid state nuclear magnetic resonance (CP-MAS 13C NMR) and infrared spectroscopy with diffuse reflectance (DRIFT), a collection of data from humic acid-like substances (HA) obtained from vermicompost produced with different sources of raw material and maturation stage. The bioactivity was evaluated using the ability of HA to induce lateral root emergence sites as well acidification of the liquidmediumby treated-maize root seedlings. The structure-activity relationshipwas done using multivariate analysis including principal component analysis (PCA), principal component regression (PCR) and Spearman correlation joined with NMR and DRIFT results. The main variables (higher loadings) correlated with HA bioactivity were for NMR positive loadings for lignin (56 ppm, 124 ppm, 148 and 153 ppm) and COOH groups (174 ppm) and negative loadings for carbohydrates (64, 75 and 102 ppm). For DRIFT the main positive loadings were aryl stretching and bending (1560, 1480, 860 and 780 cm-1) probably from lignins; for 2926 cm-1 and 2852 cm-1 due to C-H asymmetric and symmetric stretching, respectively, probably from long chain fat acids due to the presence of rocking absorption band of (CH2)n with n>4 at 720 cm-1 and negative loadings due to carbohydrate moieties (around 1100 cm-1, C-O stretching) and carboxylic acids (1724 cm-1, C-O stretching and 1220 cm-1, C-OH stretching and CO-H bending). The use of spectroscopy data to attempt to relate structure to bioactivity may be of practical interest in developing plant growth promoters using renewed source of humic materials. MenosHumic substances (HS) represent the organic material most widespread in nature and have positive effects on plant physiology influencing nutrient uptake and root architecture. Understanding the structure-activity relationship has been considered an essential step to drive technological approaches to produce HS with enhanced plant growth promotion performance. In this studywe used solid state nuclear magnetic resonance (CP-MAS 13C NMR) and infrared spectroscopy with diffuse reflectance (DRIFT), a collection of data from humic acid-like substances (HA) obtained from vermicompost produced with different sources of raw material and maturation stage. The bioactivity was evaluated using the ability of HA to induce lateral root emergence sites as well acidification of the liquidmediumby treated-maize root seedlings. The structure-activity relationshipwas done using multivariate analysis including principal component analysis (PCA), principal component regression (PCR) and Spearman correlation joined with NMR and DRIFT results. The main variables (higher loadings) correlated with HA bioactivity were for NMR positive loadings for lignin (56 ppm, 124 ppm, 148 and 153 ppm) and COOH groups (174 ppm) and negative loadings for carbohydrates (64, 75 and 102 ppm). For DRIFT the main positive loadings were aryl stretching and bending (1560, 1480, 860 and 780 cm-1) probably from lignins; for 2926 cm-1 and 2852 cm-1 due to C-H asymmetric and symmetric stretching, respectively, probably from lo... Mostrar Tudo |
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Palavras-Chave: |
Análise multivariada; Efeitos fisiológicos; Espectroscopia RMN; Relação bioatividade estrutural; Tração. |
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Categoria do assunto: |
P Recursos Naturais, Ciências Ambientais e da Terra |
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Marc: |
LEADER 02769naa a2200253 a 4500
001 1979549
005 2021-11-10
008 2013 bl uuuu u00u1 u #d
024 7 $ahttps://doi.org/10.1016/j.gexplo.2012.10.005$2DOI
100 1 $aAGUIAR, N. O.
245 $aPrediction of humic acids bioactivity using spectroscopy and multivariate analysis.$h[electronic resource]
260 $c2013
520 $aHumic substances (HS) represent the organic material most widespread in nature and have positive effects on plant physiology influencing nutrient uptake and root architecture. Understanding the structure-activity relationship has been considered an essential step to drive technological approaches to produce HS with enhanced plant growth promotion performance. In this studywe used solid state nuclear magnetic resonance (CP-MAS 13C NMR) and infrared spectroscopy with diffuse reflectance (DRIFT), a collection of data from humic acid-like substances (HA) obtained from vermicompost produced with different sources of raw material and maturation stage. The bioactivity was evaluated using the ability of HA to induce lateral root emergence sites as well acidification of the liquidmediumby treated-maize root seedlings. The structure-activity relationshipwas done using multivariate analysis including principal component analysis (PCA), principal component regression (PCR) and Spearman correlation joined with NMR and DRIFT results. The main variables (higher loadings) correlated with HA bioactivity were for NMR positive loadings for lignin (56 ppm, 124 ppm, 148 and 153 ppm) and COOH groups (174 ppm) and negative loadings for carbohydrates (64, 75 and 102 ppm). For DRIFT the main positive loadings were aryl stretching and bending (1560, 1480, 860 and 780 cm-1) probably from lignins; for 2926 cm-1 and 2852 cm-1 due to C-H asymmetric and symmetric stretching, respectively, probably from long chain fat acids due to the presence of rocking absorption band of (CH2)n with n>4 at 720 cm-1 and negative loadings due to carbohydrate moieties (around 1100 cm-1, C-O stretching) and carboxylic acids (1724 cm-1, C-O stretching and 1220 cm-1, C-OH stretching and CO-H bending). The use of spectroscopy data to attempt to relate structure to bioactivity may be of practical interest in developing plant growth promoters using renewed source of humic materials.
653 $aAnálise multivariada
653 $aEfeitos fisiológicos
653 $aEspectroscopia RMN
653 $aRelação bioatividade estrutural
653 $aTração
700 1 $aNOVOTNY, E. H.
700 1 $aOLIVEIRA, A. L.
700 1 $aRUMJANEK, V. M.
700 1 $aOLIVARES, F. L.
700 1 $aCANELLAS, L. P.
773 $tJournal of Geochemical Exploration$gv. 129, p. 95-102, Jun. 2013.
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Embrapa Solos (CNPS) |
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| Registros recuperados : 640 | |
| 62. |  | MILORI, D. M. B. P.; BAYER, C.; BAGNATO, V. S.; MILNICZUK, J.; MARTIN-NETO, L. Fluorescence spectroscopy as alternative approach to study humidification degree in soil humic acids. In: INTERNATIONAL MEETING OF THE INTERNATIONAL HUMIC SUBSTANCES SOCIETY-IHSS, 10., 2000, Toulouse, France. Entering the third millenium with a common approach to humic substances and organic matter in water, soil and sediments: proceedings... [S.l.]: IHSS, 2000. v.1, p. 97-100.| Biblioteca(s): Embrapa Instrumentação. |
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| 65. | | BARRIQUELLO, M. F.; MARTIN-NETO, L.; MILORI, D. M. B. P.; NEVES, E. F. DE A. Fluorescence spectroscopy comparision of soil humic acids and model humic acid-type polymers In: INTERNATIONAL MEETING OF INTERNATIONAL HUMIC SUBSTANCES SOCIETY. -- IHSS, 12, São Pedro, SP, 2004. Humic substances and soil and water environment. Abstracts...[São Carlos], SP: Embrapa Instrumentação Agropecuária, 2004. p.43| Biblioteca(s): Embrapa Instrumentação. |
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| 67. | | NEVES, E. A.; BARRIQUELLO, M. F.; MILORI, D. M. B. P.; MARTIN NETO, L. Fluorescence spectroscopy of a humic acid-like polymer. In: FRIMMEL, F. H.; ABBT-BRAUN, G. (Ed.). MEETING OF THE INTERNATIONAL HUMIC SUBSTANCES SOCIETY, 13TH ., 2006, Karlsruhe. Humic substances - Linking structure to functions. Proceedings... [S. l.]: IHSS, 2006. p. 249-252.| Biblioteca(s): Embrapa Instrumentação. |
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| 68. | | MOUNIER, S.; REDON, R.; NICOLODELLI, G.; GOBATO, M.; MILORI, D. M. B. P. Fluorescência 3D de sólidos: efeito da concentração e reabsorção. In: SIMPÓSIO NACIONAL DE INSTRUMENTAÇÃO AGROPECUÁRIA, 2014, São Carlos, SP Anais do SIAGRO: ciência, inovação e mercado 2014. São Carlos, SP: Embrapa Instrumentação, 2014. p. 145-148. Editores: Carlos Manoel Pedro Vaz, Débora Marcondes Bastos Pereira Milori, Silvio Crestana.| Tipo: Artigo em Anais de Congresso |
| Biblioteca(s): Embrapa Instrumentação. |
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| Registros recuperados : 640 | |
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