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Registro Completo |
Biblioteca(s): |
Embrapa Milho e Sorgo; Embrapa Soja; Embrapa Trigo. |
Data corrente: |
22/10/2015 |
Data da última atualização: |
17/08/2021 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Autoria: |
KARAM, D.; GAZZIERO, D. L. P.; VARGAS, L. |
Afiliação: |
DECIO KARAM, CNPMS; DIONISIO LUIZ PISA GAZZIERO, CNPSO; LEANDRO VARGAS, CNPT. |
Título: |
A nova era biotecnológica na agricultura: situação dos novos eventos. |
Ano de publicação: |
2015 |
Fonte/Imprenta: |
Revista Plantio Direto, Passo Fundo, v. 25, n. 145/146, p. 9-15, set. 2015. |
ISSN: |
1677-8081 |
Idioma: |
Português |
Conteúdo: |
x |
Palavras-Chave: |
Planta daninha; Planta tiguera; Plantas geneticamente modificadas. |
Thesagro: |
Biossegurança; Biotecnologia; Glycine max; Herbicida; Milho; Planta transgênica; Soja; Zea mays. |
Thesaurus Nal: |
Biosecurity; Biotechnology; Herbicides; Transgenic plants. |
Categoria do assunto: |
-- H Saúde e Patologia |
URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/item/133602/1/ID-43388-2015v25n145p9plantiodireto.pdf
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Marc: |
LEADER 00929naa a2200337 a 4500 001 2029191 005 2021-08-17 008 2015 bl uuuu u00u1 u #d 022 $a1677-8081 100 1 $aKARAM, D. 245 $aA nova era biotecnológica na agricultura$bsituação dos novos eventos.$h[electronic resource] 260 $c2015 520 $ax 650 $aBiosecurity 650 $aBiotechnology 650 $aHerbicides 650 $aTransgenic plants 650 $aBiossegurança 650 $aBiotecnologia 650 $aGlycine max 650 $aHerbicida 650 $aMilho 650 $aPlanta transgênica 650 $aSoja 650 $aZea mays 653 $aPlanta daninha 653 $aPlanta tiguera 653 $aPlantas geneticamente modificadas 700 1 $aGAZZIERO, D. L. P. 700 1 $aVARGAS, L. 773 $tRevista Plantio Direto, Passo Fundo$gv. 25, n. 145/146, p. 9-15, set. 2015.
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Embrapa Trigo (CNPT) |
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| Acesso ao texto completo restrito à biblioteca da Embrapa Instrumentação. Para informações adicionais entre em contato com cnpdia.biblioteca@embrapa.br. |
Registro Completo
Biblioteca(s): |
Embrapa Instrumentação. |
Data corrente: |
02/10/2023 |
Data da última atualização: |
02/10/2023 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Circulação/Nível: |
A - 1 |
Autoria: |
SILVA, R. M. e; SOUZA, F. L.; DIAS, E.; SILVA, G. T. S. T. da; DÚRAN, F. E.; REGO, A.; HIGGINS, D.; RIBEIRO, C. |
Afiliação: |
Department of Chemical Engineering, McMaster University, Hamilton, Ontario, Canada; Department of Chemistry and Molecular Physics, Institute of Chemistry of Sao Carlos, University of Sao Paulo, Brazil; Department of Chemistry and Molecular Physics, Institute of Chemistry of Sao Carlos, University of Sao Paulo, Brazil; Interdisciplinary Laboratory of Electrochemistry and Ceramics, Department of Chemistry, Federal University of Sao Carlos; Department of Fuel and Hydrogen Cells, Nuclear and Energy Research Institute; Department of Chemical Engineering, McMaster University, Hamilton, Ontario, Canada; Department of Chemical Engineering, McMaster University, Hamilton, Ontario, Canada; CAUE RIBEIRO DE OLIVEIRA, CNPDIA. |
Título: |
The role of TiO2:SnO2 heterojunction for partial oxidation of methane by photoelectrocatalytic process at room temperature. |
Ano de publicação: |
2023 |
Fonte/Imprenta: |
Journal of Alloys and Compounds, v. 968, 172090, 2023. |
Páginas: |
7 p. |
ISSN: |
0925-8388 |
DOI: |
https://doi.org/10.1016/j.jallcom.2023.172090 |
Idioma: |
Inglês |
Conteúdo: |
hane into hydrocarbons using photoelectrochemical routes is attractive from a sustainability point of view owing to the possibility of using renewable energy (i.e., solar illumination) to activate this stable molecule. However, the process demands the development of novel catalysts that can promote methane activation and oxidation in a controlled manner to increase energy conversion efficiency. Herein, we demonstrated that semiconductor heterostructures improved charge separation compared to the individual materials alone. A more effortless transfer between bands favors the separation of the electron-hole (e− /h+) pairs generated by the photoelectrocatalytic system and prevents them from recombining. This process produces reactive oxygens, essential to driving methane oxidation conversion of the C?H bond cleavage. TiO2:SnO2 semiconductor heterojunction catalysts in film shape were investigated for methane oxidation via a photoelectrocatalytic process. The methane oxidation reactions were carried out in an inflow and sealed electrochemical system for 1 h. Liquid-state nuclear magnetic resonance revealed methanol and acetic acid as the main liquid products, where the TiO2:SnO2 heterojunction exhibited better performance with values of 30 and 8 µmol. cm− 2 .h− 1 , respectively. Compared to their materials alone, the superior performance of the TiO2:SnO2 heterojunction is attributed to the formation of heterostructure type II that enables a more effortless transfer between bands, facilitating the separation of the generated e− /h+ pairs under UV-Vis irradiation. The outcomes achieved here will motivate further studies for developing semiconductor heterojunction structure catalysts in photoelectrocatalysis to partially oxidize methane into valuable chemicals. Menoshane into hydrocarbons using photoelectrochemical routes is attractive from a sustainability point of view owing to the possibility of using renewable energy (i.e., solar illumination) to activate this stable molecule. However, the process demands the development of novel catalysts that can promote methane activation and oxidation in a controlled manner to increase energy conversion efficiency. Herein, we demonstrated that semiconductor heterostructures improved charge separation compared to the individual materials alone. A more effortless transfer between bands favors the separation of the electron-hole (e− /h+) pairs generated by the photoelectrocatalytic system and prevents them from recombining. This process produces reactive oxygens, essential to driving methane oxidation conversion of the C?H bond cleavage. TiO2:SnO2 semiconductor heterojunction catalysts in film shape were investigated for methane oxidation via a photoelectrocatalytic process. The methane oxidation reactions were carried out in an inflow and sealed electrochemical system for 1 h. Liquid-state nuclear magnetic resonance revealed methanol and acetic acid as the main liquid products, where the TiO2:SnO2 heterojunction exhibited better performance with values of 30 and 8 µmol. cm− 2 .h− 1 , respectively. Compared to their materials alone, the superior performance of the TiO2:SnO2 heterojunction is attributed to the formation of heterostructure type II that enables a more effortless tran... Mostrar Tudo |
Palavras-Chave: |
CH4 oxidation; Methane oxidation; Photoelectrocatalysis; TiO2 SnO2 heterojunction. |
Categoria do assunto: |
-- |
Marc: |
LEADER 02695naa a2200289 a 4500 001 2157017 005 2023-10-02 008 2023 bl uuuu u00u1 u #d 022 $a0925-8388 024 7 $ahttps://doi.org/10.1016/j.jallcom.2023.172090$2DOI 100 1 $aSILVA, R. M. e 245 $aThe role of TiO2$bSnO2 heterojunction for partial oxidation of methane by photoelectrocatalytic process at room temperature.$h[electronic resource] 260 $c2023 300 $a7 p. 520 $ahane into hydrocarbons using photoelectrochemical routes is attractive from a sustainability point of view owing to the possibility of using renewable energy (i.e., solar illumination) to activate this stable molecule. However, the process demands the development of novel catalysts that can promote methane activation and oxidation in a controlled manner to increase energy conversion efficiency. Herein, we demonstrated that semiconductor heterostructures improved charge separation compared to the individual materials alone. A more effortless transfer between bands favors the separation of the electron-hole (e− /h+) pairs generated by the photoelectrocatalytic system and prevents them from recombining. This process produces reactive oxygens, essential to driving methane oxidation conversion of the C?H bond cleavage. TiO2:SnO2 semiconductor heterojunction catalysts in film shape were investigated for methane oxidation via a photoelectrocatalytic process. The methane oxidation reactions were carried out in an inflow and sealed electrochemical system for 1 h. Liquid-state nuclear magnetic resonance revealed methanol and acetic acid as the main liquid products, where the TiO2:SnO2 heterojunction exhibited better performance with values of 30 and 8 µmol. cm− 2 .h− 1 , respectively. Compared to their materials alone, the superior performance of the TiO2:SnO2 heterojunction is attributed to the formation of heterostructure type II that enables a more effortless transfer between bands, facilitating the separation of the generated e− /h+ pairs under UV-Vis irradiation. The outcomes achieved here will motivate further studies for developing semiconductor heterojunction structure catalysts in photoelectrocatalysis to partially oxidize methane into valuable chemicals. 653 $aCH4 oxidation 653 $aMethane oxidation 653 $aPhotoelectrocatalysis 653 $aTiO2 SnO2 heterojunction 700 1 $aSOUZA, F. L. 700 1 $aDIAS, E. 700 1 $aSILVA, G. T. S. T. da 700 1 $aDÚRAN, F. E. 700 1 $aREGO, A. 700 1 $aHIGGINS, D. 700 1 $aRIBEIRO, C. 773 $tJournal of Alloys and Compounds$gv. 968, 172090, 2023.
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