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 | Acesso ao texto completo restrito à biblioteca da Embrapa Solos. Para informações adicionais entre em contato com cnps.biblioteca@embrapa.br. |
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Registro Completo |
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Biblioteca(s): |
Embrapa Solos. |
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Data corrente: |
29/09/2021 |
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Data da última atualização: |
13/10/2021 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
BISPO, F. H. A.; MENEZES, M. D. de; FONTANA, A.; SARKIS, J. E. de S.; GONÇALVES, C. M.; CARVALHO, T. S. de; CURI, N.; GUILHERME, L. R. G. |
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Afiliação: |
FÁBIO HENRIQUE ALVES BISPO, UFLA; MICHELE DUARTE DE MENEZES, UFLA; ADEMIR FONTANA, CNPS; JORGE EDUARDO DE SOUZA SARKIS, IPEN; CRISTIANO MOREIRA GONÇALVES, UFLA; TEOTÔNIO SOARES DE CARVALHO, UFLA; NILTON CURI, UFLA; LUIZ ROBERTO GUIMARÃES GUILHERME, UFLA. |
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Título: |
Rare earth elements (REEs): geochemical patterns and contamination aspects in Brazilian benchmark soils. |
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Ano de publicação: |
2021 |
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Fonte/Imprenta: |
Environmental Pollution, v. 289, 117972, Nov. 2021. |
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DOI: |
https://doi.org/10.1016/j.envpol.2021.117972 |
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Idioma: |
Inglês |
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Conteúdo: |
Rare earth elements have been increasingly used in modern societies and soils are likely to be the final destination of several REE-containing (by)products. This study reports REE contents for topsoils (0-20 cm) of 175 locations in reference (n = 68) and cultivated (n = 107) areas in Brazil. Benchmark soil samples were selected accomplishing a variety of environmental conditions, aiming to: i) establishing natural background and anthropogenic concentrations for REE in soils; ii) assessing potential contamination of soils - via application of phosphate fertilizers - with REE; and, iii) predicting soil-REE contents using biomes, soil type, parent material, land use, sand content, and biomes-land use interaction as forecaster variables through generalized least squares multiple regression. Our hypotheses were that the variability of soil-REE contents is influenced by parent material, pedogenic processes, land use, and biomes, as well as that cultivated soils may have been potentially contaminated with REE via input of phosphate fertilizers. The semi-total concentrations of REE were assessed by inductively coupled plasma mass spectrometry (ICP-MS) succeeding a microwave-assisted aqua regia digestion. Analytical procedures followed a rigorous QA/QC protocol. Soil physicochemical composition and total oxides were also determined. Natural background and anthropogenic concentrations for REE were established statistically from the dataset by the median plus two median absolute deviations method. Contamination aspects were assessed by REE-normalized patterns, REE fractionation indices, and Ce and Eu anomalies ratios, as well as enrichment factors. The results indicate that differences in the amounts of REE in cultivated soils can be attributed to land use and agricultural sources (e.g., phosphate-fertilizer inputs), while those in reference soils can be attributed to parent materials, biomes, and pedogenic processes. The biomes, land use, and sand content helped to predict concentrations of light REE in Brazilian soils, with parent material being also of special relevance to predict heavy REE contents in particular. MenosRare earth elements have been increasingly used in modern societies and soils are likely to be the final destination of several REE-containing (by)products. This study reports REE contents for topsoils (0-20 cm) of 175 locations in reference (n = 68) and cultivated (n = 107) areas in Brazil. Benchmark soil samples were selected accomplishing a variety of environmental conditions, aiming to: i) establishing natural background and anthropogenic concentrations for REE in soils; ii) assessing potential contamination of soils - via application of phosphate fertilizers - with REE; and, iii) predicting soil-REE contents using biomes, soil type, parent material, land use, sand content, and biomes-land use interaction as forecaster variables through generalized least squares multiple regression. Our hypotheses were that the variability of soil-REE contents is influenced by parent material, pedogenic processes, land use, and biomes, as well as that cultivated soils may have been potentially contaminated with REE via input of phosphate fertilizers. The semi-total concentrations of REE were assessed by inductively coupled plasma mass spectrometry (ICP-MS) succeeding a microwave-assisted aqua regia digestion. Analytical procedures followed a rigorous QA/QC protocol. Soil physicochemical composition and total oxides were also determined. Natural background and anthropogenic concentrations for REE were established statistically from the dataset by the median plus two median absolute deviat... Mostrar Tudo |
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Palavras-Chave: |
Anthropogenic sources; Emerging contaminants; Environmental geochemistry; Geochemical signatures; Lanthanides. |
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Thesagro: |
Geoquímica; Solo Tropical. |
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Thesaurus Nal: |
Tropical soils. |
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Categoria do assunto: |
P Recursos Naturais, Ciências Ambientais e da Terra |
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Marc: |
LEADER 03116naa a2200313 a 4500
001 2134832
005 2021-10-13
008 2021 bl uuuu u00u1 u #d
024 7 $ahttps://doi.org/10.1016/j.envpol.2021.117972$2DOI
100 1 $aBISPO, F. H. A.
245 $aRare earth elements (REEs)$bgeochemical patterns and contamination aspects in Brazilian benchmark soils.$h[electronic resource]
260 $c2021
520 $aRare earth elements have been increasingly used in modern societies and soils are likely to be the final destination of several REE-containing (by)products. This study reports REE contents for topsoils (0-20 cm) of 175 locations in reference (n = 68) and cultivated (n = 107) areas in Brazil. Benchmark soil samples were selected accomplishing a variety of environmental conditions, aiming to: i) establishing natural background and anthropogenic concentrations for REE in soils; ii) assessing potential contamination of soils - via application of phosphate fertilizers - with REE; and, iii) predicting soil-REE contents using biomes, soil type, parent material, land use, sand content, and biomes-land use interaction as forecaster variables through generalized least squares multiple regression. Our hypotheses were that the variability of soil-REE contents is influenced by parent material, pedogenic processes, land use, and biomes, as well as that cultivated soils may have been potentially contaminated with REE via input of phosphate fertilizers. The semi-total concentrations of REE were assessed by inductively coupled plasma mass spectrometry (ICP-MS) succeeding a microwave-assisted aqua regia digestion. Analytical procedures followed a rigorous QA/QC protocol. Soil physicochemical composition and total oxides were also determined. Natural background and anthropogenic concentrations for REE were established statistically from the dataset by the median plus two median absolute deviations method. Contamination aspects were assessed by REE-normalized patterns, REE fractionation indices, and Ce and Eu anomalies ratios, as well as enrichment factors. The results indicate that differences in the amounts of REE in cultivated soils can be attributed to land use and agricultural sources (e.g., phosphate-fertilizer inputs), while those in reference soils can be attributed to parent materials, biomes, and pedogenic processes. The biomes, land use, and sand content helped to predict concentrations of light REE in Brazilian soils, with parent material being also of special relevance to predict heavy REE contents in particular.
650 $aTropical soils
650 $aGeoquímica
650 $aSolo Tropical
653 $aAnthropogenic sources
653 $aEmerging contaminants
653 $aEnvironmental geochemistry
653 $aGeochemical signatures
653 $aLanthanides
700 1 $aMENEZES, M. D. de
700 1 $aFONTANA, A.
700 1 $aSARKIS, J. E. de S.
700 1 $aGONÇALVES, C. M.
700 1 $aCARVALHO, T. S. de
700 1 $aCURI, N.
700 1 $aGUILHERME, L. R. G.
773 $tEnvironmental Pollution$gv. 289, 117972, Nov. 2021.
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Registro original: |
Embrapa Solos (CNPS) |
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Biblioteca |
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Tipo/Formato |
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Registro |
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| Registros recuperados : 68 | |
| 5. |  | MARCHI, G. M.; GUILHERME, L. R. G.; CHANG, A. C. Recuperação e especiação de elementos-traço em um solo tratado com lodo de esgoto. In: REUNIÃO BRASILEIRA DE FERTILIDADE DO SOLO E NUTRIÇÃO DE PLANTAS, 28.; REUNIÃO BRASILEIRA SOBRE MICORRIZAS, 12.; SIMPÓSIO BRASILEIRO DE MICROBIOLOGIA DO SOLO, 10.; REUNIÃO BRASILEIRA DE BIOLOGIA DO SOLO, 7., 2008, Londrina. FertBio 2008: desafios para o uso do solo com eficiência e qualidade ambiental: anais. Londrina: SBCS: Embrapa Soja: IAPAR: UEL, 2008. 1 CD-ROM.| Tipo: Artigo em Anais de Congresso / Nota Técnica |
| Biblioteca(s): Embrapa Cerrados. |
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| 7. | | RANGEL, O. J. P.; SILVA, C. A.; BETTIOL, W.; GUILHERME, L. R. G.; DYNIA, J. F. Acúmulo de Cu, Mn, Ni, Pb e Zn em latossolo vermelho adubado com fontes de lodo de esgoto e cultivado com milho. Ciência e Agrotecnologia, Lavras, v. 28, n. 1, p.15-23, jan./fev., 2004.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: Nacional - A |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 8. | | SILVA, D. R. G.; MARCHI, G.; SPEHAR, C. R.; GUILHERME, L. R. G.; FAQUIN, V. Agronomic efficiency of potassium fertilization in lettuce fertilized with alternative nutrient sources. Revista Ciência Agronômica, v. 44, n. 2, p. 267-277, abr-jun, 2013.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 1 |
| Biblioteca(s): Embrapa Cerrados. |
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| 9. | | MARTINS, V.; GONÇALVES, A. S. F.; MARCHI, G.; GUILHERME, L. R. G.; MARTINS, E. de S. Solubilização de potássio em misturas de verdete e calcário tratadas termoquimicamente. Pesquisa Agropecuária Tropical, Goiânia, v. 45, n. 1, p. 66-72, jan./mar. 2015.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 1 |
| Biblioteca(s): Embrapa Cerrados. |
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| 12. | | MARCHI, G. M.; GUILHERME, L. R. G.; CHANG, A. C.; NASCIMENTO, C. W. A. Extractabilidade de metais de um solo com carga variável tratado com lodo de esgoto. In: REUNIÃO BRASILEIRA DE FERTILIDADE DO SOLO E NUTRIÇÃO DE PLANTAS, 28.; REUNIÃO BRASILEIRA SOBRE MICORRIZAS, 12.; SIMPÓSIO BRASILEIRO DE MICROBIOLOGIA DO SOLO, 10.; REUNIÃO BRASILEIRA DE BIOLOGIA DO SOLO, 7., 2008, Londrina. FertBio 2008: desafios para o uso do solo com eficiência e qualidade ambiental: anais. Londrina: SBCS: Embrapa Soja: IAPAR: UEL, 2008. 1 CD-ROM.| Tipo: Artigo em Anais de Congresso / Nota Técnica |
| Biblioteca(s): Embrapa Cerrados. |
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| 13. | | GONÇALVES, A. S. F.; VANESSA MARTINS; MARCHI, G.; GUILHERME, L. R. G.; MARTINS, E. de S. Estudo da solubilidade de uma fonte não convencional de potássio para fins agrícolas. In: REUNIÃO BRASILEIRA DE FERTILIDADE DO SOLO E NUTRIÇÃO DE PLANTAS, 30.; REUNIÃO BRASILEIRA SOBRE MICORRIZAS, 14.; SIMPÓSIO BRASILEIRO DE MICROBIOLOGIA DO SOLO, 12.; REUNIÃO BRASILEIRA DE BIOLOGIA DO SOLO, 9.; SIMPÓSIO SOBRE SELÊNIO NO BRASIL, 1., 2012, Maceió. A responsabilidade socioambiental da pesquisa agrícola: anais. Viçosa, MG: Sociedade Brasileira de Ciência do Solo, 2012.| Tipo: Artigo em Anais de Congresso |
| Biblioteca(s): Embrapa Cerrados. |
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| 15. | | SILVA, A. B. da; MARCHI, G.; SILVA, O. D. D. da; GUILHERME, L. R. G. Etrace express: programa para análise de risco de elementos-traço em fertilizantes inorgânicos. In: ENCONTRO DE JOVENS TALENTOS DA EMBRAPA CERRADOS, 4., 2009, Planaltina, DF. Resumos apresentados... Planaltina, DF: Embrapa Cerrados, 2009. p. 31-32 (Embrapa Cerrados. Documentos, 243).| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Cerrados. |
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| 16. | | MARCHI, G.; GUILHERME, L. R. G.; SILVA, A. B. DA; SILVA, O. D. D. da. Etrace Express: software for risk analysis of trace elements in inorganic fertilizers post application. In: WORLD CONGRESS OF SOIL SCIENCE, 19., 2010, Brisbane. Soil solutions for a changing world. Brisbane: International Union of Soil Science: ASSSI, 2010. 1 CD-ROM. GIKES, R. J.; PRAKONGKEP, N. (Ed.).| Tipo: Artigo em Anais de Congresso |
| Biblioteca(s): Embrapa Cerrados. |
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| Registros recuperados : 68 | |
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| Nenhum registro encontrado para a expressão de busca informada. |
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