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Registro Completo |
Biblioteca(s): |
Embrapa Instrumentação. |
Data corrente: |
20/09/2021 |
Data da última atualização: |
10/06/2022 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Autoria: |
MORAIS, C. P. de; NICOLODELLI, G.; FOSCHINI, M. M.; SILVA, K. S. G. da; MAUAD, F. F.; MOUNIER, S.; MILORI, D. M. B. P. |
Afiliação: |
MILENE CORSO MITSUYUKI, CNPDIA; DEBORA MARCONDES BASTOS PEREIRA, CNPDIA. |
Título: |
Total phosphorus determination in eutrophic tropical river sediments by laser-induced breakdown spectroscopy techniques. |
Ano de publicação: |
2021 |
Fonte/Imprenta: |
Analytical Methods, v. 13, 2021. |
Páginas: |
77 - 83 |
ISSN: |
1759-9660 |
DOI: |
10.1039/d0ay02008g |
Idioma: |
Inglês |
Conteúdo: |
Total phosphorus (TP) in sediments is an important chemical variable in the study of the extent of eutrophication in water bodies. Two methods, based on single pulse (SP) and double pulse (DP) laserinduced breakdown spectroscopy (LIBS), were developed for determining TP in the sediment cores of Brazilian rivers upstream from the Barra Bonita reservoir. TP concentration in the sediments was determined by inductively coupled plasma optical emission spectrometry (ICP OES) on digested samples. Besides, a LIBS system operating in SP and DP modes was used to develop methods for TP quantification in sediment pellets. In LIBS, the most appropriate wavelength to measure P was 214.91 nm. The calibration curves showed correlation coefficients of 0.93 and 0.92 and limits of detection of 709 mg kg#1;1 and 349 mg kg#1;1 for SP and DP LIBS, respectively. The two proposed methods were validated and the average percentage errors were 14% and 10% for SP and DP LIBS, respectively. The ICP OES and SP and DP LIBS data showed that the most superficial layers of the Piracicaba River, all the sedimentary layers of the Tiete River, and the con ˆ fluence region present a high concentration of TP, according to the Brazilian sediment quality criterion. In conclusion, SP and DP LIBS were confirmed as promising alternative tools to traditional analytical methods for monitoring the TP content in the sediments that come from different hydrographic units. The proposed method using DP LIBS proved more sensitive than SP LIBS, but the SP LIBS method demonstrated enough precision for determining TP in eutrophic river sediments. MenosTotal phosphorus (TP) in sediments is an important chemical variable in the study of the extent of eutrophication in water bodies. Two methods, based on single pulse (SP) and double pulse (DP) laserinduced breakdown spectroscopy (LIBS), were developed for determining TP in the sediment cores of Brazilian rivers upstream from the Barra Bonita reservoir. TP concentration in the sediments was determined by inductively coupled plasma optical emission spectrometry (ICP OES) on digested samples. Besides, a LIBS system operating in SP and DP modes was used to develop methods for TP quantification in sediment pellets. In LIBS, the most appropriate wavelength to measure P was 214.91 nm. The calibration curves showed correlation coefficients of 0.93 and 0.92 and limits of detection of 709 mg kg#1;1 and 349 mg kg#1;1 for SP and DP LIBS, respectively. The two proposed methods were validated and the average percentage errors were 14% and 10% for SP and DP LIBS, respectively. The ICP OES and SP and DP LIBS data showed that the most superficial layers of the Piracicaba River, all the sedimentary layers of the Tiete River, and the con ˆ fluence region present a high concentration of TP, according to the Brazilian sediment quality criterion. In conclusion, SP and DP LIBS were confirmed as promising alternative tools to traditional analytical methods for monitoring the TP content in the sediments that come from different hydrographic units. The proposed method using DP LIBS proved more sensit... Mostrar Tudo |
Palavras-Chave: |
Chemical variable; Piracicaba River; SP and DP LIBS. |
Categoria do assunto: |
-- |
Marc: |
LEADER 02401naa a2200265 a 4500 001 2134588 005 2022-06-10 008 2021 bl uuuu u00u1 u #d 022 $a1759-9660 024 7 $a10.1039/d0ay02008g$2DOI 100 1 $aMORAIS, C. P. de 245 $aTotal phosphorus determination in eutrophic tropical river sediments by laser-induced breakdown spectroscopy techniques.$h[electronic resource] 260 $c2021 300 $a77 - 83 520 $aTotal phosphorus (TP) in sediments is an important chemical variable in the study of the extent of eutrophication in water bodies. Two methods, based on single pulse (SP) and double pulse (DP) laserinduced breakdown spectroscopy (LIBS), were developed for determining TP in the sediment cores of Brazilian rivers upstream from the Barra Bonita reservoir. TP concentration in the sediments was determined by inductively coupled plasma optical emission spectrometry (ICP OES) on digested samples. Besides, a LIBS system operating in SP and DP modes was used to develop methods for TP quantification in sediment pellets. In LIBS, the most appropriate wavelength to measure P was 214.91 nm. The calibration curves showed correlation coefficients of 0.93 and 0.92 and limits of detection of 709 mg kg#1;1 and 349 mg kg#1;1 for SP and DP LIBS, respectively. The two proposed methods were validated and the average percentage errors were 14% and 10% for SP and DP LIBS, respectively. The ICP OES and SP and DP LIBS data showed that the most superficial layers of the Piracicaba River, all the sedimentary layers of the Tiete River, and the con ˆ fluence region present a high concentration of TP, according to the Brazilian sediment quality criterion. In conclusion, SP and DP LIBS were confirmed as promising alternative tools to traditional analytical methods for monitoring the TP content in the sediments that come from different hydrographic units. The proposed method using DP LIBS proved more sensitive than SP LIBS, but the SP LIBS method demonstrated enough precision for determining TP in eutrophic river sediments. 653 $aChemical variable 653 $aPiracicaba River 653 $aSP and DP LIBS 700 1 $aNICOLODELLI, G. 700 1 $aFOSCHINI, M. M. 700 1 $aSILVA, K. S. G. da 700 1 $aMAUAD, F. F. 700 1 $aMOUNIER, S. 700 1 $aMILORI, D. M. B. P. 773 $tAnalytical Methods$gv. 13, 2021.
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Embrapa Instrumentação (CNPDIA) |
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Registros recuperados : 35 | |
21. | | OLIVEIRA, T. C. de; BENEDUCCI, W. P.; BONFIM, P. F.; FOSCHINI, M. M.; FRUETT, F.; RODRIGUEZ, J. C. C.; FERREIRA, M. D. Embedded system for monitoring impact magnitude during orange transport. Chemical engineering transactions, [S. l.], v. 44, 2015. 6 p.Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 2 |
Biblioteca(s): Embrapa Instrumentação. |
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22. | | GUIMARÃES, G. G. F.; PEREIRA, E. I.; NOGUEIRA, A. R. A.; CRUZ, C. C. T.; FOSCHINI, M. M.; BERNARDI, A. C. C.; OLIVEIRA, C. R. de. Liberação controlada de ureia proveniente de nanocompósitos reduz a volatização de amônia e aumenta a eficiência do uso de nitrogênio pela planta. In: WORKSHOP DA REDE DE NANOTECNOLOGIA APLICADA AO AGRONEGÓCIO, 9., 2017, São Carlos. Anais ... São Carlos: Embrapa Instrumentação, 2017. p.471-474. Editores: Caue Ribeiro de Oliveira, Elaine Cristina Paris, Luiz Henrique Capparelli Mattoso, Marcelo Porto Bemquerer, Maria Alice Martins, Odílio Benedito Garrido de Assis.Tipo: Artigo em Anais de Congresso |
Biblioteca(s): Embrapa Instrumentação. |
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23. | | SAPELLI, K. S.; BORBA, K. R.; MIRANDA, M.; SPRICIGO, P. C.; BRESOLIN, J. D.; FOSCHINI, M. M.; CORREA, D. S.; FERREIRA, M. D. Postharvest quality of papaya fruit wrapped with polyvinyl chloride film added with silver. ISHS Acta Horticulturae, v. 1325, p. 265-272, 2021. V International Symposium on Postharvest Pathology: From Consumer to Laboratory-Sustainable Approaches to Managing Postharvest Pathogens.Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 1 |
Biblioteca(s): Embrapa Instrumentação. |
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25. | | DE MORAES, C. P.; BABOS, D. V.; COSTA, V. C.; NERIS, J. B.; NICOLODELLI, G.; FOSCHINI, M. M.; MAUAD, F. F.; MOUNIER, S.; MILORI, D. M. B. P. Direct determination of Cu, Cr, and Ni in river sediments using double pulse laser-induced breakdown spectroscopy: Ecological risk and pollution level assessment. Science of the Total Environment, v. 837, 155699, 2022. 9 p.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
Biblioteca(s): Embrapa Instrumentação. |
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26. | | SPRICIGO, P. C.; PILON, L.; TRENTO, J. P.; MOURA, M. R. de; BONFIM, K. S.; FOSCHINI, M. M.; MATTOSO, L. H. C.; FERREIRA, M. D. Nano-chitosan as an antimicrobial agent in preservative solutions for cut flowers. Journal of Chemical Technology and Biotechnology, v. 96, n. 8, p. 2168-2175, Aug. 2021. 8 p. Na publicação: Milene C Mitsuyuki.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
Biblioteca(s): Embrapa Hortaliças; Embrapa Instrumentação. |
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29. | | PARIZE, D. D. da S.; FOSCHINI, M. M.; OLIVEIRA, J. E. de; KLAMCZYNSKI, A. P.; GLENN, G. M.; MARCONCINI, J. M.; MATTOSO, L. H. C. Solution blow spinning: parameters optimization and effects on the properties of nanofibers from poly(lactic acid)/dimethyl carbonate solutions. Journal of materials science, [S. l.], v. 51, n. 9, p. 4627-4638, 2016.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
Biblioteca(s): Embrapa Instrumentação. |
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30. | | PEREIRA, E. I.; NOGUEIRA, A. R. de A.; CRUZ, C. C. T. da; GUIMARAES, G. G. F.; FOSCHINI, M. M.; BERNARDI, A. C. de C.; OLIVEIRA, C. R. de. Controlled urea release employing nanocomposites increases the efficiency of nitrogen use by forage. ACS Sustainable Chemistry & Engineering, v. 5, n. 11, p. 9993-10001, 2017.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
Biblioteca(s): Embrapa Instrumentação; Embrapa Pecuária Sudeste. |
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31. | | ZUCCHINI, N. M.; FLORENCIO, C.; MIRANDA, M.; OLDONI, F. C. A.; BONFIM, N. S.; RODRIGUES, K. A.; OLIVEIRA, R. M. D. DE; FOSCHINI, M. M.; HUBINGER, S. Z.; BRESOLIN, J. D.; FERREIRA, M. D. Effect of carnauba wax nanoemulsion coating on postharvest papaya quality. ISHS Acta Horticulturae, v. 1325, p. 199-206, 2021. V International Symposium on Postharvest Pathology: From Consumer to Laboratory-Sustainable Approaches to Managing Postharvest Pathogens.Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 1 |
Biblioteca(s): Embrapa Instrumentação. |
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32. | | PESTANA, G. C.; SANTOS, K. A. F. DOS; MIRANDA, M.; SPRICIGO, P. C.; FOSCHINI, M. M.; BRESOLIN, J. D.; HUBINGER, S. Z.; ASSIS, O. B. G. de; FERREIRA, M. D. Effects of carnauba wax and chitosan bilayer edible coating on shelf life of fresh-cut apple. ISHS Acta Horticulturae, v. 1325, p. 215-224, 2021. V International Symposium on Postharvest Pathology: From Consumer to Laboratory-Sustainable Approaches to Managing Postharvest Pathogens.Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 1 |
Biblioteca(s): Embrapa Instrumentação. |
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33. | | GUIMARAES, G. G. F.; PEREIRA, E. I.; NOGUEIRA, A. R. de A.; CRUZ, C. C. T. da; FOSCHINI, M. M.; BERNARDI, A. C. de C.; OLIVEIRA, C. R. de. Liberação controlada de ureia proveniente de nanocompósitos reduz a volatilização de amônia e aumenta a eficiência do uso de nitrogênio pela planta. In: WORKSHOP DE NANOTECNOLOGIA APLICADA AO AGRONEGÓCIO, 9., 2017, São Carlos, SP. Anais... São Carlos, SP: Embrapa Instrumentação, 2017. cap. 7. p. 471-474.Tipo: Artigo em Anais de Congresso |
Biblioteca(s): Embrapa Pecuária Sudeste. |
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34. | | SANTOS, J. V. dos; BENTO, L. R.; BRESOLIN, J. D.; FOSCHINI, M. M.; OLIVEIRA, P. P. A.; PEZZOPANE, J. R. M.; BERNARDI, A. C. de C.; MENDES, I. C.; MARTIN NETO, L. The long-term effects of intensive grazing and silvopastoral systems on soil physicochemical properties, enzymatic activity, and microbial biomass. Catena, v. 219, a106619, 2022. 1 - 11Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
Biblioteca(s): Embrapa Cerrados; Embrapa Instrumentação; Embrapa Pecuária Sudeste. |
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35. | | PINTO, D. M.; OLIVEIRA, P. de; MINITTI, A. F.; MENDES, A. M.; VILELA, G. F.; CASTRO, G. S. A.; ROCHA, J. D.; BOGIANI, J. C.; NOGUEIRA JUNIOR, L. R.; COSTA, C. C. da; NOVAES, R. M. L.; JESUS, I. R. D. de; FAE, V. A.; EDUARDO, M. de P.; FOSCHINI, M. M.; ALENCAR, J. R. DE; CRUZ, M. C. D.; GARCIA, E. P. DE. A.; JARDINE, J. G.; RODRIGUES, G. S. Ambitec-TICs: avaliação de impactos de tecnologias de informação e comunicação aplicadas à agropecuária. Campinas: Embrapa Territorial, 2020. 31 p. (Embrapa Territorial. Documentos, 131)Biblioteca(s): Embrapa Agricultura Digital; Embrapa Instrumentação; Embrapa Meio Ambiente; Embrapa Recursos Genéticos e Biotecnologia; Embrapa Solos; Embrapa Territorial. |
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Registros recuperados : 35 | |
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Nenhum registro encontrado para a expressão de busca informada. |
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