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Registro Completo |
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
25/09/2023 |
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Data da última atualização: |
25/09/2023 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
ALVARENGA, A. D.; FACURE, M. H. M.; MONTES-SÁNCHEZ, I.; OLIVEIRA, G. O. S.; LANZA, M. R. V.; MERCANTE, L. A.; CORREA, D. S. |
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Afiliação: |
PPG-Biotec, Center for Exact Sciences and Technology, Federal University of Sao Carlos (UFSCar); Department of Chemistry, Center for Exact Sciences and Technology, Federal University of Sao Carlos (UFSCar); Institute of Chemistry of Sao Carlos (IQSC), University of Sao Paulo (USP); Institute of Chemistry of Sao Carlos (IQSC), University of Sao Paulo (USP); Institute of Chemistry of Sao Carlos (IQSC), University of Sao Paulo (USP); Institute of Chemistry, Federal University of Bahia (UFBA); DANIEL SOUZA CORREA, CNPDIA. |
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Título: |
Multifunctional and sustainable soot-modified nanofibrous membrane for adsorption, sensing and hydrogen peroxide electrogeneration. |
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Ano de publicação: |
2023 |
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Fonte/Imprenta: |
Journal of Cleaner Production, n. 422, 138697, 2023. |
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ISSN: |
0959-6526 |
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DOI: |
https://doi.org/10.1016/j.jclepro.2023.138697 |
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Idioma: |
Inglês |
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Conteúdo: |
The incineration of plastics and biomass is an efficient alternative to reduce the amount of solid waste and is also beneficial for energy production. Soot is one of the main byproducts generated during solid waste incineration, and so far, it has been treated as a pollutant. However, soot is an interesting nanostructured material displaying high specific surface area and chemical reactivity. In this work, soot produced by incomplete burning of plastic materials was combined with polymer nanofibers resulting in a multifunctional membrane explored for pollutant adsorption, sensing of organic pollutants, and in the electrogeneration of hydrogen peroxide. Specifically, soot was immobilized onto polyamide 6 nanofibrous membranes (NFM) produced by solution blow spinning following two different approaches: pre-synthesis and post-synthesis modification, and then the effect of soot chemical activation with NaOH was investigated. The adsorption tests showed that the chemical activation was essential to increase efficiency by improving its hydrophilicity and generation of adsorption sites. The experimental and calculated batch adsorption efficiency towards methylene blue was 94.33 mg/g and 37.71 mg/g, respectively. The adsorption efficiency in the fixed bed was 8.00 mg/g. The functional NFMs maintained their efficiency for at least ten adsorption cycles, increasing their economic viability. Furthermore, the NFMs were applied as flexible and free-standing electrodes for detecting methylene blue with a limit of detection of 2.4 nmol/L. The average per-electrode cost was estimated to be US$0.04. Finally, the NFM also demonstrated the ability to generate H2O2 in situ. Altogether, these results suggest that the immobilization of soot onto nanofibrous membranes is an efficient strategy for developing multifunctional and sustainable materials towards environmental applications. MenosThe incineration of plastics and biomass is an efficient alternative to reduce the amount of solid waste and is also beneficial for energy production. Soot is one of the main byproducts generated during solid waste incineration, and so far, it has been treated as a pollutant. However, soot is an interesting nanostructured material displaying high specific surface area and chemical reactivity. In this work, soot produced by incomplete burning of plastic materials was combined with polymer nanofibers resulting in a multifunctional membrane explored for pollutant adsorption, sensing of organic pollutants, and in the electrogeneration of hydrogen peroxide. Specifically, soot was immobilized onto polyamide 6 nanofibrous membranes (NFM) produced by solution blow spinning following two different approaches: pre-synthesis and post-synthesis modification, and then the effect of soot chemical activation with NaOH was investigated. The adsorption tests showed that the chemical activation was essential to increase efficiency by improving its hydrophilicity and generation of adsorption sites. The experimental and calculated batch adsorption efficiency towards methylene blue was 94.33 mg/g and 37.71 mg/g, respectively. The adsorption efficiency in the fixed bed was 8.00 mg/g. The functional NFMs maintained their efficiency for at least ten adsorption cycles, increasing their economic viability. Furthermore, the NFMs were applied as flexible and free-standing electrodes for detecting methy... Mostrar Tudo |
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Palavras-Chave: |
Hydrogen peroxide generation; Sensor; Sustainability. |
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Categoria do assunto: |
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Marc: |
LEADER 02716naa a2200253 a 4500
001 2156876
005 2023-09-25
008 2023 bl uuuu u00u1 u #d
022 $a0959-6526
024 7 $ahttps://doi.org/10.1016/j.jclepro.2023.138697$2DOI
100 1 $aALVARENGA, A. D.
245 $aMultifunctional and sustainable soot-modified nanofibrous membrane for adsorption, sensing and hydrogen peroxide electrogeneration.$h[electronic resource]
260 $c2023
520 $aThe incineration of plastics and biomass is an efficient alternative to reduce the amount of solid waste and is also beneficial for energy production. Soot is one of the main byproducts generated during solid waste incineration, and so far, it has been treated as a pollutant. However, soot is an interesting nanostructured material displaying high specific surface area and chemical reactivity. In this work, soot produced by incomplete burning of plastic materials was combined with polymer nanofibers resulting in a multifunctional membrane explored for pollutant adsorption, sensing of organic pollutants, and in the electrogeneration of hydrogen peroxide. Specifically, soot was immobilized onto polyamide 6 nanofibrous membranes (NFM) produced by solution blow spinning following two different approaches: pre-synthesis and post-synthesis modification, and then the effect of soot chemical activation with NaOH was investigated. The adsorption tests showed that the chemical activation was essential to increase efficiency by improving its hydrophilicity and generation of adsorption sites. The experimental and calculated batch adsorption efficiency towards methylene blue was 94.33 mg/g and 37.71 mg/g, respectively. The adsorption efficiency in the fixed bed was 8.00 mg/g. The functional NFMs maintained their efficiency for at least ten adsorption cycles, increasing their economic viability. Furthermore, the NFMs were applied as flexible and free-standing electrodes for detecting methylene blue with a limit of detection of 2.4 nmol/L. The average per-electrode cost was estimated to be US$0.04. Finally, the NFM also demonstrated the ability to generate H2O2 in situ. Altogether, these results suggest that the immobilization of soot onto nanofibrous membranes is an efficient strategy for developing multifunctional and sustainable materials towards environmental applications.
653 $aHydrogen peroxide generation
653 $aSensor
653 $aSustainability
700 1 $aFACURE, M. H. M.
700 1 $aMONTES-SÁNCHEZ, I.
700 1 $aOLIVEIRA, G. O. S.
700 1 $aLANZA, M. R. V.
700 1 $aMERCANTE, L. A.
700 1 $aCORREA, D. S.
773 $tJournal of Cleaner Production$gn. 422, 138697, 2023.
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Registro original: |
Embrapa Instrumentação (CNPDIA) |
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| Registros recuperados : 57 | |
| 41. |  | MERCANTE, L. A.; FACURE, M. H. M.; LOCILENTO, D.; MIGLIORINI, F. L.; SANFELICE, R. C.; MATTOSO, L. H. C.; CORREA, D. S. Composite membranes based on polymeric nanofibers/graphene oxide with dye sorption capability. In: BRAZIL MRS MEETING - SBPMAT, 15, 2016, Rio de Janeiro. Proceedings... Rio de Janeiro: SBPMat, 2016. p. 388.| Tipo: Artigo em Anais de Congresso |
| Biblioteca(s): Embrapa Instrumentação. |
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| 42. | | MERCANTE, L. A.; SCHNEIDER, R.; FACURE, M. H. M.; ANDRE. R. S.; TEODORO, K.; MARTINS, D.; MIGLIORINI, F.; CORREA, D. S. ELETROFIAÇÃO: PARÂMETRO E CONFIGURAÇÕES DE SISTEMA, TIPOS DE FIBRAS E MÉTODOS DE MODIFICAÇÃO. In: MERCANTE, L. A.; CORRÊA, D. S. (org.). Eletrofiação e nanofibras: fundamentos e aplicações. Ponta Grossa, PR: Atena Editora, 2023. cap. 2. 13-51| Tipo: Capítulo em Livro Técnico-Científico |
| Biblioteca(s): Embrapa Instrumentação. |
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| 43. | | PAULA, K. T.; SANTOS, S. N. C.; FACURE, M. H. M.; ARAUJO, F. L.; ANDRADE, M. B.; CORREA, D. S.; MENDONÇA, C. R. Fabrication of interdigitated electrodes of graphene oxide/silica by femtosecond laser-induced forward transfer for sensing applications. Journal Applied Physics, v. 133, 053103, 2023. 1 - 11| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Instrumentação. |
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| 44. | | PAULA, K. T.; GAÁL, G.; ALMEIDA, G. F. B.; ANDRADE, M. B.; FACURE, M. H. M.; CORREA, D. S.; RIUL JUNIOR, A.; RODRIGUES, V.; MENDONÇA, C. R. Femtosecond laser micromachining of polylactic acid/graphene composites for designing interdigitated microelectrodes for sensor applications. Optics and Laser Technology, v. 101, p. 74-79, 2018.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Instrumentação. |
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| 46. | | PAULA, K. T.; SANTOS, M. V.; FACURE, M. H. M.; ANDRADE, M. B.; ARAÚJO, F. L.; CORREA, D. S.; RIBEIRO, S. J. L.; MENDONÇA, K. R. Laser patterning and induced reduction of graphene oxide functionalized silk fibroin. Optical Materials, n. 99, a. 109540, 2020. 1 - 6| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Instrumentação. |
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| 47. | | GUEDES, M. D. V.; MARQUES, M. S.; BERLITZ, S. J.; FACURE, M. H. M.; CORREA, D. S.; STEFFENS, C.; CONTRI, R. V.; KÜLKAMP-GUERRREIRO, I. C. Lamivudine and Zidovudine-Loaded Nanostructures: Green Chemistry Preparation for Pediatric Oral Administration. Nanomaterials, v. 13, 770, 2023. 1 - 18| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 3 |
| Biblioteca(s): Embrapa Instrumentação. |
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| 48. | | CARDOSO, R. M.; PEREIRA, T. S.; FACURE, M. H. M.; SANTOS, D. M.; MERCANTE, L. A.; MATTOSO, L. H. C.; CORREA, D. S. Current progress in plant pathogen detection enabled by nanomaterials-based (bio)sensors. Sensors and Actuators Reports, v. 4, 100068, 2022. 18 p.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 1 |
| Biblioteca(s): Embrapa Instrumentação. |
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| 49. | | FUKUSHIMA, K. L.; SCAGION, V. P.; FACURE, M. H. M.; PINHEIRO, A. C. M.; CORREA, D. S.; NUMES, C. A.; OLIVEIRA, J. E. Development of an electronic tongue based on a nanocomposite for discriminating flavor enhancers and commercial salts. IEEE Sensors Journal, v. 21, n. 2, 2021. 1250-1256| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Instrumentação. |
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| 51. | | ALVARENGA, A. D.; FACURE, M. H. M.; MONTES-SÁNCHEZ, I.; OLIVEIRA, G. O. S.; LANZA, M. R. V.; MERCANTE, L. A.; CORREA, D. S. Multifunctional and sustainable soot-modified nanofibrous membrane for adsorption, sensing and hydrogen peroxide electrogeneration. Journal of Cleaner Production, n. 422, 138697, 2023.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Instrumentação. |
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| 52. | | SOUSA, L. P. O.; FUKUSHIMA, K. L.; SCAGION, V. P.; FACURE, M. H. M.; CORREA, D. S.; OLIVEIRA, J. E.; FERREIRA, D. D. A principal curves-based method for electronic tongue data analysis. IEEE Sensors Journal, v. 21, n. 4, 2021.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Instrumentação. |
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| 53. | | ANDRÉ, R. S.; SANTOS, D. M.; MERCANTE, L. A.; FACURE, M. H. M.; CAMPANA-FILHO, S. P.; MATTOSO, L. H. C.; CORREA, D. S. Nanochitin-based composite films as a disposable ethanol sensor. Journal of Environmental Chemical Engineering, v. 8, 104163, 2020.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Instrumentação. |
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| 54. | | ANDRE, R. S.; FACURE, M. H. M.; SCHNEIDER, R.; MIGLIORINI, F. L.; SANTOS, D. M. dos; MERCANTE, L. A.; CORREA, D. S. Sensing Materials: Nanofibers Produced by Electrospinning and Solution Blow Spinning. In: Narayan, R. (Ed.), Encyclopedia of Sensors and Biosensors, v. 2, 2023. 521-541| Tipo: Capítulo em Livro Técnico-Científico |
| Biblioteca(s): Embrapa Instrumentação. |
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| 56. | | PAVINATTO, A.; MERCANTE, L. A.; FACURE, M. H. M.; PENA, R. B.; SANFELICE, R. C.; MATTOSO, L. H. C.; CORREA, D. S. Ultrasensitive biosensor based on polyvinylpyrrolidone/chitosan/reduced graphene oxide electrospun nanofibers for 17alfa - Ethinylestradiol electrochemical detection. Applied Surface Science, v. 458, p. 431-437, 2018.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Instrumentação. |
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| 57. | | CHRISTINELLI, W. A.; SHIMIZU, F. M.; FACURE, M. H. M.; CERRI, R.; OLIVEIRA JUNIOR, O. N.; CORREA, D. S.; MATTOSO, L. H. C. Two-dimensional MoS2-based impedimetric electronic tongue for the discrimination of endocrine disrupting chemicals using machine learning. Sensors and Actuators: B. Chemical, v. 336, 129696, 2021. 1 - 11| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Instrumentação. |
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| Registros recuperados : 57 | |
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| Nenhum registro encontrado para a expressão de busca informada. |
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