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Biblioteca(s): |
Embrapa Meio Ambiente. |
Data corrente: |
22/01/2020 |
Data da última atualização: |
05/03/2024 |
Tipo da produção científica: |
Nota Técnica/Nota Científica |
Autoria: |
ASSALIN, M. R.; SANTOS, L. D. L. dos; SOUZA, D. R. C. de; ROSA, M. A.; DUARTE, R. C. R. M.; CASTANHA, R. F.; DONAIRE, P. P. R.; DURAN, N. |
Afiliação: |
MARCIA REGINA ASSALIN, CNPMA; LUCAS D. L. DOS DANTOS, CNPMA; DEBORA RENATA CASSOLI DE S DUTRA, CNPMA; MARIA APARECIDA ROSA, CNPMA; RAFAELA C. R. M. DUARTE, CNPMA; RODRIGO FERNANDES CASTANHA, CNPMA; PATRICIA PULCINI ROSVALD DONAIRE, UNIVERSIDAD FEDERAL DO ABC/SP; NELSON DURA´N, UNICAMP/SP. |
Título: |
Nanoformulation as a tool for improvement of thiamethoxam encapsulation and evaluation of ecotoxicological impacts. |
Ano de publicação: |
2019 |
Fonte/Imprenta: |
Energy, Ecology and Environment, v. 4, n. 6. p. 310-317, 2019. |
DOI: |
https://doi.org/10.1007/s40974-019-00138-1 |
Idioma: |
Inglês |
Conteúdo: |
Abstract: Huanglonbing, or citrus greening, is the most serious disease of citrus which cause large economic losses. One of the strategies to avoid the spread of the disease is the control of Diaphorina citri psyllid, its insect vector, by the application of insecticides. Development of nanoinsecticides, which are less harmful to the environment and more efficient (in terms of cost and performance) than the existing formulations, is a current challenge. In this work, nanocarriers composed of chitosan–tripolyphosphate (by ionic gelification approach) and poly-ε-caprolactone (PCL)–chitosan (by double-emulsion–solvent evaporation method) for thiametoxam insecticide were developed and characterized. Toxicological assessments using Raphidocelis subcapta, Artemia salina and Caernohabditis elegans were performed comparing PCL–chitosan nanoparticle and PCL–chitosan loaded thiamethoxam in comparison to commercial pesticide. The nanoparticles obtained from optimized conditions resulted in positive charged nanoparticles, with medium dispersity. The double-emulsion method resulted in smaller nanoparticles (313.5 ± 7 nm) and increased encapsulation efficiency (36.6 ± 0.2%) in comparison to chitosan–tripolyphosphate nanoparticles. The lower encapsulation efficiency was observed in chitosan–tripolyphosphate, impairing agricultural applications. The EC50 values (mg L⁻¹) of Raphidocelis subcapitata and C. elegans obtained for poly-ε-caprolactone with thiamethoxam were 56.15 (18.91–131.21) and 66.07 (1.20–274.14), respectively, and poly-ε-caprolactone without thiamethoxam 94.26 (22.42–166.10) and 214.63 (139.08–494.3), respectively. No toxicity was found in Artemia salina. Our results indicate that nanoparticles (with and without thiamethoxam) were more toxic to soil organisms (C. elegan) than commercial formulations. MenosAbstract: Huanglonbing, or citrus greening, is the most serious disease of citrus which cause large economic losses. One of the strategies to avoid the spread of the disease is the control of Diaphorina citri psyllid, its insect vector, by the application of insecticides. Development of nanoinsecticides, which are less harmful to the environment and more efficient (in terms of cost and performance) than the existing formulations, is a current challenge. In this work, nanocarriers composed of chitosan–tripolyphosphate (by ionic gelification approach) and poly-ε-caprolactone (PCL)–chitosan (by double-emulsion–solvent evaporation method) for thiametoxam insecticide were developed and characterized. Toxicological assessments using Raphidocelis subcapta, Artemia salina and Caernohabditis elegans were performed comparing PCL–chitosan nanoparticle and PCL–chitosan loaded thiamethoxam in comparison to commercial pesticide. The nanoparticles obtained from optimized conditions resulted in positive charged nanoparticles, with medium dispersity. The double-emulsion method resulted in smaller nanoparticles (313.5 ± 7 nm) and increased encapsulation efficiency (36.6 ± 0.2%) in comparison to chitosan–tripolyphosphate nanoparticles. The lower encapsulation efficiency was observed in chitosan–tripolyphosphate, impairing agricultural applications. The EC50 values (mg L⁻¹) of Raphidocelis subcapitata and C. elegans obtained for poly-ε-caprolactone with thiamethoxam were 56.15 (18.91–131.21) an... Mostrar Tudo |
Palavras-Chave: |
Caernohabditis elegans; Ecotoxicity; Pesticide; Polymeric nanoparticles. |
Thesagro: |
Greening; Impacto Ambiental; Inseticida. |
Thesaurus Nal: |
Ecotoxicology; Encapsulation; Environmental impact; Insecticides; thiamethoxam. |
Categoria do assunto: |
-- |
Marc: |
LEADER 02952naa a2200361 a 4500 001 2119220 005 2024-03-05 008 2019 bl uuuu u00u1 u #d 024 7 $ahttps://doi.org/10.1007/s40974-019-00138-1$2DOI 100 1 $aASSALIN, M. R. 245 $aNanoformulation as a tool for improvement of thiamethoxam encapsulation and evaluation of ecotoxicological impacts.$h[electronic resource] 260 $c2019 520 $aAbstract: Huanglonbing, or citrus greening, is the most serious disease of citrus which cause large economic losses. One of the strategies to avoid the spread of the disease is the control of Diaphorina citri psyllid, its insect vector, by the application of insecticides. Development of nanoinsecticides, which are less harmful to the environment and more efficient (in terms of cost and performance) than the existing formulations, is a current challenge. In this work, nanocarriers composed of chitosan–tripolyphosphate (by ionic gelification approach) and poly-ε-caprolactone (PCL)–chitosan (by double-emulsion–solvent evaporation method) for thiametoxam insecticide were developed and characterized. Toxicological assessments using Raphidocelis subcapta, Artemia salina and Caernohabditis elegans were performed comparing PCL–chitosan nanoparticle and PCL–chitosan loaded thiamethoxam in comparison to commercial pesticide. The nanoparticles obtained from optimized conditions resulted in positive charged nanoparticles, with medium dispersity. The double-emulsion method resulted in smaller nanoparticles (313.5 ± 7 nm) and increased encapsulation efficiency (36.6 ± 0.2%) in comparison to chitosan–tripolyphosphate nanoparticles. The lower encapsulation efficiency was observed in chitosan–tripolyphosphate, impairing agricultural applications. The EC50 values (mg L⁻¹) of Raphidocelis subcapitata and C. elegans obtained for poly-ε-caprolactone with thiamethoxam were 56.15 (18.91–131.21) and 66.07 (1.20–274.14), respectively, and poly-ε-caprolactone without thiamethoxam 94.26 (22.42–166.10) and 214.63 (139.08–494.3), respectively. No toxicity was found in Artemia salina. Our results indicate that nanoparticles (with and without thiamethoxam) were more toxic to soil organisms (C. elegan) than commercial formulations. 650 $aEcotoxicology 650 $aEncapsulation 650 $aEnvironmental impact 650 $aInsecticides 650 $athiamethoxam 650 $aGreening 650 $aImpacto Ambiental 650 $aInseticida 653 $aCaernohabditis elegans 653 $aEcotoxicity 653 $aPesticide 653 $aPolymeric nanoparticles 700 1 $aSANTOS, L. D. L. dos 700 1 $aSOUZA, D. R. C. de 700 1 $aROSA, M. A. 700 1 $aDUARTE, R. C. R. M. 700 1 $aCASTANHA, R. F. 700 1 $aDONAIRE, P. P. R. 700 1 $aDURAN, N. 773 $tEnergy, Ecology and Environment$gv. 4, n. 6. p. 310-317, 2019.
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3. | | MORASI, I. M.; AMARO, A. R. F. V. B. de L.; DUARTE, R. C. R. M.; VILELA, V. A. A.; PACKER, A. P. Avaliação do manejo de nitrogênio no cafeeiro utilizando clorofilômetro. In: CONGRESSO BRASILEIRO DE PESQUISAS CAFEEIRAS, 41, 2015, Poços de Caldas. Com mais tecnologia, mas café se aprecia: trabalhos apresentados. Poços de Caldas: Fundação Procafé, 2015. 301-302Tipo: Resumo em Anais de Congresso |
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4. | | ASSALIN, M. R.; SANTOS, L. D. L. dos; SOUZA, D. R. C. de; ROSA, M. A.; DUARTE, R. C. R. M.; CASTANHA, R. F.; DONAIRE, P. P. R.; DURAN, N. Nanoformulation as a tool for improvement of thiamethoxam encapsulation and evaluation of ecotoxicological impacts. Energy, Ecology and Environment, v. 4, n. 6. p. 310-317, 2019.Tipo: Nota Técnica/Nota Científica |
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