| |
|
|
 | Acesso ao texto completo restrito à biblioteca da Embrapa Florestas. Para informações adicionais entre em contato com cnpf.biblioteca@embrapa.br. |
|
Registro Completo |
|
Biblioteca(s): |
Embrapa Florestas. |
|
Data corrente: |
28/09/2022 |
|
Data da última atualização: |
28/09/2022 |
|
Tipo da produção científica: |
Artigo em Periódico Indexado |
|
Autoria: |
BARBIERI, S. F.; LIMA, L. T. F. de; BAUM, J. C. S.; MISCHIATTI, K. L.; GODOY, R. C. B. de; SILVEIRA, J. L. M. |
|
Afiliação: |
SHAYLA FERNANDA BARBIERI, FEDERAL UNIVERSITY OF PARANÁ; LUCAS TREVISAN FRANÇA DE LIMA, FEDERAL UNIVERSITY OF PARANÁ; JÉSSICA CAROLINE SCHOLZE BAUM, FEDERAL UNIVERSITY OF PARANÁ; KEYLLA LENÇONE MISCHIATTI, FEDERAL UNIVERSITY OF PARANÁ; ROSSANA CATIE BUENO DE GODOY, CNPF; JOANA LÉA MEIRA SILVEIRA, FEDERAL UNIVERSITY OF PARANÁ. |
|
Título: |
Polysaccharides from pinhão seeds of Araucaria angustifolia: extraction, isolation and structural characterization. |
|
Ano de publicação: |
2022 |
|
Fonte/Imprenta: |
Journal of Food Composition and Analysis, v. 115, 104888, p. 1-9, 2023. |
|
DOI: |
https://doi.org/10.1016/j.jfca.2022.104888 |
|
Idioma: |
Português |
|
Conteúdo: |
Araucaria angustifolia is one of the main conifer species with great economic importance. Its seeds, known as pinhão, play a fundamental role in ecosystem conservation and have promising potential for application in the food/nutraceutical industry. This study aimed to elucidate the fine chemical structure of polysaccharides, showing for the first time the composition of non-starch polysaccharides present in the pinh ?ao seeds. For this, the seeds were submitted to sequential extractions giving rise to the water polysaccharide (PW), and alkaline polysaccharides (PA2M), and (PA4M) fractions, obtained after aqueous, 2 mol L-1 and 4 mol L-1 NaOH extraction, respectively. The polysaccharides isolated showed the presence of glucose (between 96.8% and 76.3%) indicating starch as the main component of all fractions. Moreover, after enzymatic treatment, the PA4M-A fraction was obtained showing mostly arabinose in its monosaccharide composition. In this way, the chemical structure of PA4M-A was investigated by 1D 1H, 13C NMR and 2D 1H?13C HSQC, 1H?1H COSY and 1H?13C HMBC NMR spectroscopy, which demonstrated the presence of arabinans composed with a backbone of (1?5)-linked-?-L- arabinofuranosyl units substituted in O-2 and/or O-3 position by ?-L-Araf-(1? or ?-L-Araf-(1?3)-?-L-Araf-(1?side chains. The structural elucidation of the arabinans presents in the pinh ?ao cell wall contributes to the knowledge of the molecular structure of the A.angustifolia seeds. |
|
Palavras-Chave: |
Arabinan; Araucaria forest; Gymnosperm tree; NMR analysis. |
|
Thesagro: |
Araucária Angustifólia. |
|
Thesaurus Nal: |
Chemical structure; Starch. |
|
Categoria do assunto: |
K Ciência Florestal e Produtos de Origem Vegetal |
|
Marc: |
LEADER 02359naa a2200277 a 4500
001 2146924
005 2022-09-28
008 2022 bl uuuu u00u1 u #d
024 7 $ahttps://doi.org/10.1016/j.jfca.2022.104888$2DOI
100 1 $aBARBIERI, S. F.
245 $aPolysaccharides from pinhão seeds of Araucaria angustifolia$bextraction, isolation and structural characterization.$h[electronic resource]
260 $c2022
520 $aAraucaria angustifolia is one of the main conifer species with great economic importance. Its seeds, known as pinhão, play a fundamental role in ecosystem conservation and have promising potential for application in the food/nutraceutical industry. This study aimed to elucidate the fine chemical structure of polysaccharides, showing for the first time the composition of non-starch polysaccharides present in the pinh ?ao seeds. For this, the seeds were submitted to sequential extractions giving rise to the water polysaccharide (PW), and alkaline polysaccharides (PA2M), and (PA4M) fractions, obtained after aqueous, 2 mol L-1 and 4 mol L-1 NaOH extraction, respectively. The polysaccharides isolated showed the presence of glucose (between 96.8% and 76.3%) indicating starch as the main component of all fractions. Moreover, after enzymatic treatment, the PA4M-A fraction was obtained showing mostly arabinose in its monosaccharide composition. In this way, the chemical structure of PA4M-A was investigated by 1D 1H, 13C NMR and 2D 1H?13C HSQC, 1H?1H COSY and 1H?13C HMBC NMR spectroscopy, which demonstrated the presence of arabinans composed with a backbone of (1?5)-linked-?-L- arabinofuranosyl units substituted in O-2 and/or O-3 position by ?-L-Araf-(1? or ?-L-Araf-(1?3)-?-L-Araf-(1?side chains. The structural elucidation of the arabinans presents in the pinh ?ao cell wall contributes to the knowledge of the molecular structure of the A.angustifolia seeds.
650 $aChemical structure
650 $aStarch
650 $aAraucária Angustifólia
653 $aArabinan
653 $aAraucaria forest
653 $aGymnosperm tree
653 $aNMR analysis
700 1 $aLIMA, L. T. F. de
700 1 $aBAUM, J. C. S.
700 1 $aMISCHIATTI, K. L.
700 1 $aGODOY, R. C. B. de
700 1 $aSILVEIRA, J. L. M.
773 $tJournal of Food Composition and Analysis$gv. 115, 104888, p. 1-9, 2023.
Download
Esconder MarcMostrar Marc Completo |
|
Registro original: |
Embrapa Florestas (CNPF) |
|
|
Biblioteca |
ID |
Origem |
Tipo/Formato |
Classificação |
Cutter |
Registro |
Volume |
Status |
URL |
Voltar
|
|
|
| Registros recuperados : 305 | |
| 2. |  | PAIVA, E. Diagnóstico e prognóstico do milho transgênico. In: CONGRESSO NACIONAL DE MILHO E SORGO, 25.; SIMPOSIO BRASILEIRO SOBRE A LAGARTA-DO-CARTUCHO, SPODOPTERA FRUGIPERDA, 1., 2004, Cuiabá, MT. Da agricultura familiar ao agronegócio: tecnologia, competitividade e sustentabilidade: [palestras]. Sete Lagoas: ABMS: Embrapa Milho e Sorgo; Cuiabá: Empaer, 2004. 1 CD-ROM.| Tipo: Artigo em Anais de Congresso |
| Biblioteca(s): Embrapa Milho e Sorgo. |
|    |
| 4. | | PAIVA, E. Genética e bioquímica da tolerância ao alumínio. In: REUNIAO BRASILEIRA DE FERTILIDADE DO SOLO E NUTRICAO DE PLANTAS, 23.; REUNIAO BRASILEIRA SOBRE MICORRIZAS, 7.; SIMPOSIO BRASILEIRO DE MICROBIOLOGIA DO SOLO, 5.; REUNIAO BRASILEIRA DE BIOLOGIA DO SOLO, 2., 1998. Caxambu, MG. Fertibio 98: resumos. Lavras: UFLA: SBCS: SBM, 1998. p. 15.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Milho e Sorgo. |
| |
| 5. | | PAIVA, E. Genética e bioquímica da tolerância ao alumínio. Revista Brasileira de Fisiologia Vegetal, Brasilia, v. 11, p. 2-3, 1999. Suplemento. Edição de resumos do 7º Congresso Brasileiro de Fisiologia Vegetal, Brasília, 1999.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Milho e Sorgo. |
| |
| 6. | | PAIVA, E. Organismos geneticamente modificados no Brasil. In: CONGRESSO NACIONAL DE MILHO E SORGO, 27.; SIMPOSIO BRASILEIRO SOBRE A LAGARTA-DO-CARTUCHO , SPODOPTERA FRUGIPERDA, 3.; WORKSHOP SOBRE MANEJO E ETIOLOGIA DA MANCHA BRANCA DO MILHO, 2008, Londrina. Agroenergia, producao de alimentos e mudanças climáticas: desafios para milho e sorgo: trabalhos e palestras. [Londrina]: IAPAR; [Sete Lagoas]: Embrapa Milho e Sorgo, 2008. 1 CD-ROM.| Tipo: Artigo em Anais de Congresso / Nota Técnica |
| Biblioteca(s): Embrapa Milho e Sorgo. |
| |
| 12. | | PAIVA, E.; CARNEIRO, N. P. Avanços biotecnológicos na agricultura mundial. In: CONGRESSO NACIONAL DE MILHO E SORGO, 23., 2000, Uberlândia, MG. A inovação tecnológica e a competividade no contexto dos mercados globalizados: resumos expandidos. Sete Lagoas: ABMS: Embrapa Milho e Sorgo; Uberlândia: Universidade Federal de Uberlandia, 2000. 1 CD-ROM.| Tipo: Artigo em Anais de Congresso |
| Biblioteca(s): Embrapa Milho e Sorgo. |
| |
| Registros recuperados : 305 | |
|
| Expressão de busca inválida. Verifique!!! |
|
|
