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 | Acesso ao texto completo restrito à biblioteca da Embrapa Pecuária Sudeste. Para informações adicionais entre em contato com cppse.biblioteca@embrapa.br. |
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Registro Completo |
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Biblioteca(s): |
Embrapa Pecuária Sudeste. |
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Data corrente: |
04/09/2017 |
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Data da última atualização: |
05/01/2018 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
MACHADO, R. C.; AMARAL, C. D. B. do; SCHIAVO, D.; NOBREGA, J. de A.; NOGUEIRA, A. R. de A. |
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Afiliação: |
Raquel Cardoso Machado, UFSCar; Clarice Dias Britto do Amaral, UFSCar; Daniela Schiavo, Agilent Technologies; Joaquim de Araújo Nobrega, UFSCar; ANA RITA DE ARAUJO NOGUEIRA, CPPSE. |
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Título: |
Complex samples and spectral interferences in ICP-MS: evaluation of tandem mass spectrometry for interference-free determination of cadmium, tin and platinum group elements. |
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Ano de publicação: |
2017 |
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Fonte/Imprenta: |
Microchemical Journal, v. 130, p. 271-275, 2017. |
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DOI: |
https://doi.org/10.1016/j.microc.2016.09.011 |
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Idioma: |
Inglês |
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Conteúdo: |
An analytical method was developed for determination of Cd, Sn, Pd, Pt and Rh in sediments, fertilizer and sludge samples by inductively coupled plasma tandem mass spectrometry (ICP-MS/MS). The performance of ICP-MS/MS using oxygen into the octopole reaction system (ORS3) and MS/MS mode, on mass and shift mass, was evaluated to overcome spectral interferences. Addition and recovery experiments in sediments, fertilizer and sludge samples at three concentration levels, 0.5, 1.0 and 5.0 μg L− 1, were carried out to evaluate the accuracy of the developed procedure. Quantitative recoveries, from 80 to 113% for 112Cd+, 120Sn+ and 106Pd+ were reached using MS/MS in on mass operation mode. For Pt and Rh, recoveries ranged from 81 to 117% by monitoring 195Pt16O+ and 103Rh16O+ in MS/MS (shift mass mode) with 0.3 mL min− 1 oxygen gas flow rate pressurized into the ORS3. Limits of detection of the developed method were 15, 2.5, 1.8, 9.0 and 9.9 μg kg− 1 for 195Pt16O+, 103Rh16O+, 112Cd+, 120Sn+, and 106Pd+, respectively. All analytes were simultaneously interference-free determined by ICP-MS/MS, which demonstrates the potential of this instrumental analytical strategy for Cd, Sn, Pd, Pt, and Rh determination in complex samples. |
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Palavras-Chave: |
Mass shift mode; Spectral interferences. |
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Thesaurus Nal: |
tandem mass spectrometry. |
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Categoria do assunto: |
W Química e Física |
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Marc: |
LEADER 02045naa a2200217 a 4500
001 2074928
005 2018-01-05
008 2017 bl uuuu u00u1 u #d
024 7 $ahttps://doi.org/10.1016/j.microc.2016.09.011$2DOI
100 1 $aMACHADO, R. C.
245 $aComplex samples and spectral interferences in ICP-MS$bevaluation of tandem mass spectrometry for interference-free determination of cadmium, tin and platinum group elements.$h[electronic resource]
260 $c2017
520 $aAn analytical method was developed for determination of Cd, Sn, Pd, Pt and Rh in sediments, fertilizer and sludge samples by inductively coupled plasma tandem mass spectrometry (ICP-MS/MS). The performance of ICP-MS/MS using oxygen into the octopole reaction system (ORS3) and MS/MS mode, on mass and shift mass, was evaluated to overcome spectral interferences. Addition and recovery experiments in sediments, fertilizer and sludge samples at three concentration levels, 0.5, 1.0 and 5.0 μg L− 1, were carried out to evaluate the accuracy of the developed procedure. Quantitative recoveries, from 80 to 113% for 112Cd+, 120Sn+ and 106Pd+ were reached using MS/MS in on mass operation mode. For Pt and Rh, recoveries ranged from 81 to 117% by monitoring 195Pt16O+ and 103Rh16O+ in MS/MS (shift mass mode) with 0.3 mL min− 1 oxygen gas flow rate pressurized into the ORS3. Limits of detection of the developed method were 15, 2.5, 1.8, 9.0 and 9.9 μg kg− 1 for 195Pt16O+, 103Rh16O+, 112Cd+, 120Sn+, and 106Pd+, respectively. All analytes were simultaneously interference-free determined by ICP-MS/MS, which demonstrates the potential of this instrumental analytical strategy for Cd, Sn, Pd, Pt, and Rh determination in complex samples.
650 $atandem mass spectrometry
653 $aMass shift mode
653 $aSpectral interferences
700 1 $aAMARAL, C. D. B. do
700 1 $aSCHIAVO, D.
700 1 $aNOBREGA, J. de A.
700 1 $aNOGUEIRA, A. R. de A.
773 $tMicrochemical Journal$gv. 130, p. 271-275, 2017.
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| 2. |  | PEREIRA, A. da S. A evolução da cultura da batata no Brasil. Horticultura Brasileira, Brasília, DF, v. 29, n. 2, jul. 2011. p. S5701-S5710 Suplemento. Trabalho apresentado no 51 Congresso Brasileiro de Olericultura, 51., 2011, Viçosa, MG.| Tipo: Artigo em Anais de Congresso |
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