Registro Completo |
Biblioteca(s): |
Embrapa Instrumentação. |
Data corrente: |
11/12/2024 |
Data da última atualização: |
11/12/2024 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Autoria: |
FLORENCIO, C.; BRONDI, M. G.; SILVA, M. J.; BONDANCIA, T. J.; MARTINS, M. A.; FARINAS, C. S.; OLIVEIRA, C. R. de; MATTOSO, L. H. C. |
Afiliação: |
FEDERAL UNIVERSITY OF SAO CARLOS; FEDERAL UNIVERSITY OF SAO CARLOS; MARIA ALICE MARTINS, CNPDIA; CRISTIANE SANCHEZ FARINAS, CNPDIA; CAUE RIBEIRO DE OLIVEIRA, CNPDIA; LUIZ HENRIQUE CAPPARELLI MATTOSO, CNPDIA. |
Título: |
Carboxymethylcellulose production from sugarcane bagasse: A new approach in biorefinery concept. |
Ano de publicação: |
2024 |
Fonte/Imprenta: |
International Journal of Biological Macromolecules, v. 282, 136998, 2024. |
Páginas: |
1 - 12 |
ISSN: |
0141-8130 |
DOI: |
https://doi.org/10.1016/j.ijbiomac.2024.136998 |
Idioma: |
Inglês |
Conteúdo: |
Although the production of carboxymethylcellulose from different raw materials is commercial, its preparation from agro-industrial residues has still been poorly explored in terms of performance, cost-effectiveness, and sustainability. Here, sugarcane bagasse was used as raw material for the carboxymethylcellulose (CMCb) syn thesis within the biorefinery context. Sequential treatments were used for the removal of hemicellulose and lignin and the isolation of cellulose, whose conversion into CMCb was carried out through treatments with NaOH and monochloroacetic acid (MCA). The chemical modifications led to a CMCb with a substitution degree of 0.44, purity of 71.3 %, and 32 % crystallinity. Our residue-based CMCb was adequate for microorganism encapsula tion, a high-value application, promoting viable conidia after 5 months of storage in equivalent conditions of high-purity, commercial CMC. Our findings show a route for the preparation of valuable polysaccharides from waste in future biorefineries, which, depending on their characteristics, can be applied in different processes. Here we use them for the encapsulation of a bioagent, although they can easily be used in other applications such as packaging and coating |
Palavras-Chave: |
Agro-industrial residue; Biorefinery; Carboxymethyl cellulose; Natural polymers. |
Categoria do assunto: |
-- |
Marc: |
LEADER 02129naa a2200289 a 4500 001 2170446 005 2024-12-11 008 2024 bl uuuu u00u1 u #d 022 $a0141-8130 024 7 $ahttps://doi.org/10.1016/j.ijbiomac.2024.136998$2DOI 100 1 $aFLORENCIO, C. 245 $aCarboxymethylcellulose production from sugarcane bagasse$bA new approach in biorefinery concept.$h[electronic resource] 260 $c2024 300 $a1 - 12 520 $aAlthough the production of carboxymethylcellulose from different raw materials is commercial, its preparation from agro-industrial residues has still been poorly explored in terms of performance, cost-effectiveness, and sustainability. Here, sugarcane bagasse was used as raw material for the carboxymethylcellulose (CMCb) syn thesis within the biorefinery context. Sequential treatments were used for the removal of hemicellulose and lignin and the isolation of cellulose, whose conversion into CMCb was carried out through treatments with NaOH and monochloroacetic acid (MCA). The chemical modifications led to a CMCb with a substitution degree of 0.44, purity of 71.3 %, and 32 % crystallinity. Our residue-based CMCb was adequate for microorganism encapsula tion, a high-value application, promoting viable conidia after 5 months of storage in equivalent conditions of high-purity, commercial CMC. Our findings show a route for the preparation of valuable polysaccharides from waste in future biorefineries, which, depending on their characteristics, can be applied in different processes. Here we use them for the encapsulation of a bioagent, although they can easily be used in other applications such as packaging and coating 653 $aAgro-industrial residue 653 $aBiorefinery 653 $aCarboxymethyl cellulose 653 $aNatural polymers 700 1 $aBRONDI, M. G. 700 1 $aSILVA, M. J. 700 1 $aBONDANCIA, T. J. 700 1 $aMARTINS, M. A. 700 1 $aFARINAS, C. S. 700 1 $aOLIVEIRA, C. R. de 700 1 $aMATTOSO, L. H. C. 773 $tInternational Journal of Biological Macromolecules$gv. 282, 136998, 2024.
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Registro original: |
Embrapa Instrumentação (CNPDIA) |
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