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Registro Completo |
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Biblioteca(s): |
Embrapa Agroindústria de Alimentos. |
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Data corrente: |
01/08/2024 |
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Data da última atualização: |
24/09/2024 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
CUCINOTTA, L.; ROTONDO, A.; COPPOLINO, C.; IRRERA, E.; DUARTE, L. A.; CIPRIANO, R. R.; AMARAL, W. do; LOUREIRO, W.; DESCHAMPS, C.; BIZZO, H. R.; DONATO, P.; SCIARRONE, D.; MONDELLO, L.; SALERNO, T. M. G. |
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Afiliação: |
LORENZO CUCINOTTA, UNIVERSITÀ DEGLI STUDI DI MESSINA; ARCHIMEDE ROTONDO, UNIVERSITÀ DI MESSINA; CARMELO COPPOLINO, UNIVERSITÀ DEGLI STUDI DI MESSINA; ELISA IRRERA; LAURA A. DUARTE, UNIVERSIDADE FEDERAL DO PARANÁ; ROGER R. CIPRIANO, UNIVERSIDADE FEDERAL DO PARANÁ; WANDERLEI DO AMARAL, UNIVERSIDADE FEDERAL DO PARANÁ; WILSON LOUREIRO, UNIVERSIDADE FEDERAL DO PARANÁ; CICERO DESCHAMPS; HUMBERTO RIBEIRO BIZZO, CTAA; PAOLA DONATO, UNIVERSITÀ DEGLI STUDI DI MESSINA; DANILO SCIARRONE, UNIVERSITÀ DEGLI STUDI DI MESSINA; LUIGI MONDELLO, UNIVERSITÀ DEGLI STUDI DI MESSINA; TANIA MARIA GRAZIA SALERNO, UNIVERSITÀ DEGLI STUDI DI MESSINA. |
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Título: |
Gas chromatographic techniques and spectroscopic approaches for a deep characterization of Piper gaudichaudianum Kunth essential oil from Brazil. |
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Ano de publicação: |
2024 |
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Fonte/Imprenta: |
Journal of Chromatography A, v. 1732, 465208, 2024. |
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DOI: |
https://doi.org/10.1016/j.chroma.2024.465208 |
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Idioma: |
Inglês |
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Conteúdo: |
Piper gaudichaudianum Kunth essential oil (EO) is a natural source of bioactive components, having multiple therapeutic applications. Its chemical composition is highly variable, and strictly depends on abiotic factors, resulting in various biological activities. The present study details the utilization of multiple gas chromatographic techniques alongside nuclear magnetic resonance (NMR) spectroscopy to characterize the essential oil of Piper gaudichaudianum Kunth from Brazil. Seventy-six components were identified using GC–MS analysis, while enantio‐selective multidimensional gas chromatography elucidated the enantiomeric distribution of eight chiral components, for the first time in the literature. Following GC–MS analysis, an unidentified component, constituting approximately 27 % of the total oil, prompted an isolation step through preparative gas chromatography. Through the combined use of nuclear magnetic resonance, GC-Fourier transform infrared spectroscopy (FTIR), and mass spectrometry (MS), the unknown molecule was structurally identified as 4-[(3E)‐dec-3-en-1-yl]phenol. Remarkably, it was identified as a known molecule, gibbilimbol B, and not previously listed in any MS database. Subsequently, the spectrum was included in a commercial library, specifically the FFNSC 4.0 MS database, for the first time. |
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Palavras-Chave: |
Componentes quirais; Cromatografia gasosa multidimensional; Enantiomeric separation; Espectometria de massa (MS); Espectroscopia de ressonância magnética nuclear; GC-FTIR; GC-MS; NMR; Piper gaudichaudianum Kunth do Brasil; Preparative gas chromatography; Uso combinado de ressonância magnética nuclear espectroscopia de infravermelho com transformada GC-Fourier (FTIR). |
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Thesagro: |
Cromatografia Gasosa; Óleo Essencial. |
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Thesaurus Nal: |
Essential oils; Gas chromatography. |
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Categoria do assunto: |
W Química e Física |
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Marc: |
LEADER 02910naa a2200469 a 4500
001 2166152
005 2024-09-24
008 2024 bl uuuu u00u1 u #d
024 7 $ahttps://doi.org/10.1016/j.chroma.2024.465208$2DOI
100 1 $aCUCINOTTA, L.
245 $aGas chromatographic techniques and spectroscopic approaches for a deep characterization of Piper gaudichaudianum Kunth essential oil from Brazil.$h[electronic resource]
260 $c2024
520 $aPiper gaudichaudianum Kunth essential oil (EO) is a natural source of bioactive components, having multiple therapeutic applications. Its chemical composition is highly variable, and strictly depends on abiotic factors, resulting in various biological activities. The present study details the utilization of multiple gas chromatographic techniques alongside nuclear magnetic resonance (NMR) spectroscopy to characterize the essential oil of Piper gaudichaudianum Kunth from Brazil. Seventy-six components were identified using GC–MS analysis, while enantio‐selective multidimensional gas chromatography elucidated the enantiomeric distribution of eight chiral components, for the first time in the literature. Following GC–MS analysis, an unidentified component, constituting approximately 27 % of the total oil, prompted an isolation step through preparative gas chromatography. Through the combined use of nuclear magnetic resonance, GC-Fourier transform infrared spectroscopy (FTIR), and mass spectrometry (MS), the unknown molecule was structurally identified as 4-[(3E)‐dec-3-en-1-yl]phenol. Remarkably, it was identified as a known molecule, gibbilimbol B, and not previously listed in any MS database. Subsequently, the spectrum was included in a commercial library, specifically the FFNSC 4.0 MS database, for the first time.
650 $aEssential oils
650 $aGas chromatography
650 $aCromatografia Gasosa
650 $aÓleo Essencial
653 $aComponentes quirais
653 $aCromatografia gasosa multidimensional
653 $aEnantiomeric separation
653 $aEspectometria de massa (MS)
653 $aEspectroscopia de ressonância magnética nuclear
653 $aGC-FTIR
653 $aGC-MS
653 $aNMR
653 $aPiper gaudichaudianum Kunth do Brasil
653 $aPreparative gas chromatography
653 $aUso combinado de ressonância magnética nuclear espectroscopia de infravermelho com transformada GC-Fourier (FTIR)
700 1 $aROTONDO, A.
700 1 $aCOPPOLINO, C.
700 1 $aIRRERA, E.
700 1 $aDUARTE, L. A.
700 1 $aCIPRIANO, R. R.
700 1 $aAMARAL, W. do
700 1 $aLOUREIRO, W.
700 1 $aDESCHAMPS, C.
700 1 $aBIZZO, H. R.
700 1 $aDONATO, P.
700 1 $aSCIARRONE, D.
700 1 $aMONDELLO, L.
700 1 $aSALERNO, T. M. G.
773 $tJournal of Chromatography A$gv. 1732, 465208, 2024.
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Registro original: |
Embrapa Agroindústria de Alimentos (CTAA) |
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