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Registro Completo |
Biblioteca(s): |
Embrapa Instrumentação. |
Data corrente: |
28/09/2022 |
Data da última atualização: |
29/11/2024 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Autoria: |
ALVARENGA, A. D.; ANDRE, R. S.; TEODORO, K. B. R.; SCHNEIDER, R.; MERCANTE, L. A.; CORREA, D. S. |
Afiliação: |
AUGUSTO D. ALVARENGA, FEDERAL UNIVERSITY OF SAO CARLOS (UFSCAR); RAFAELA DA S. ANDRE, UNIVERSIDADE FEDERAL DE SÃO CARLOS; KELCIANE B.R TEODORO, UNIVERSIDADE DE GRENOBLE; RODRIGO SCHNEIDER, FEDERAL UNIVERSITY OF SAO CARLOS (UFSCAR); LUIZA A. MERCANTE, FEDERAL UNIVERSITY OF BAHIA (UFBA); DANIEL SOUZA CORREA, CNPDIA. |
Título: |
Nanofibrous filtering membranes modified with sucrose-derived carbonaceous materials for adsorption in batch and fixed bed. |
Ano de publicação: |
2023 |
Fonte/Imprenta: |
Chemical Engineering Journal, v. 451, e138557, 2023. |
Páginas: |
1 - 15 |
ISSN: |
1385-8947 |
DOI: |
https://doi.org/10.1016/j.cej.2022.138557 |
Idioma: |
Inglês |
Conteúdo: |
Membrane technologies have been considered as an efficient and economical alternative to help providing clean water for the population on a large scale. In this regard, the development of low-cost adsorbent membranes, with scalable production and high efficiency is indeed necessary and urgently required. In this work, we investigated the methylene blue removal performance of solution blow spun (SBS) polyamide 6 (PA6) nanofibrous membranes (NFMs) coated with different types of carbonaceous materials. Sucrose was employed as carbon source and two distinct approaches, namely hydrothermal and caramelization routes, were investigated to produce it. The NFMs were functionalized by dip-coating and then chemically activated using NaOH to further enhance the adsorption efficiency. The carbonaceous materials-modified NFMs were characterized by scanning electron microscopy (SEM), contact angle, Zeta potential, Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA). Batch and fixed bed experiments revealed that the NFMs modified by dip coating with the carbonaceous materials present competitive adsorption capacity in addition to be a simple, low cost and scalable strategy. The experimental and maximum adsorption capacities of batch adsorption were 371.69 mg/g and 471.58 mg/g for the NFMs modified with hydrothermal carbon, and 260.52 mg/g and 651.04 mg/g for the NFMs coated with black caramel, respectively. The NFMs modified with hydrothermal carbon and caramel carbon showed applicability in scalable systems based on fixed bed adsorption experiments. Our results suggest that nanofibrous membranes coated with carbonaceous materials from sucrose are a suitable tool to develop adsorptive membranes for pollutants removal and open the venue to also explore other carbon-rich sources, including bio- and food residues for adsorptive applications. MenosMembrane technologies have been considered as an efficient and economical alternative to help providing clean water for the population on a large scale. In this regard, the development of low-cost adsorbent membranes, with scalable production and high efficiency is indeed necessary and urgently required. In this work, we investigated the methylene blue removal performance of solution blow spun (SBS) polyamide 6 (PA6) nanofibrous membranes (NFMs) coated with different types of carbonaceous materials. Sucrose was employed as carbon source and two distinct approaches, namely hydrothermal and caramelization routes, were investigated to produce it. The NFMs were functionalized by dip-coating and then chemically activated using NaOH to further enhance the adsorption efficiency. The carbonaceous materials-modified NFMs were characterized by scanning electron microscopy (SEM), contact angle, Zeta potential, Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA). Batch and fixed bed experiments revealed that the NFMs modified by dip coating with the carbonaceous materials present competitive adsorption capacity in addition to be a simple, low cost and scalable strategy. The experimental and maximum adsorption capacities of batch adsorption were 371.69 mg/g and 471.58 mg/g for the NFMs modified with hydrothermal carbon, and 260.52 mg/g and 651.04 mg/g for the NFMs coated with black ... Mostrar Tudo |
Palavras-Chave: |
Carbonaceous materials; Fixed bed; Solution blow spinning; Sustainable materials. |
Categoria do assunto: |
-- |
Marc: |
LEADER 02795naa a2200265 a 4500 001 2146960 005 2024-11-29 008 2023 bl uuuu u00u1 u #d 022 $a1385-8947 024 7 $ahttps://doi.org/10.1016/j.cej.2022.138557$2DOI 100 1 $aALVARENGA, A. D. 245 $aNanofibrous filtering membranes modified with sucrose-derived carbonaceous materials for adsorption in batch and fixed bed.$h[electronic resource] 260 $c2023 300 $a1 - 15 520 $aMembrane technologies have been considered as an efficient and economical alternative to help providing clean water for the population on a large scale. In this regard, the development of low-cost adsorbent membranes, with scalable production and high efficiency is indeed necessary and urgently required. In this work, we investigated the methylene blue removal performance of solution blow spun (SBS) polyamide 6 (PA6) nanofibrous membranes (NFMs) coated with different types of carbonaceous materials. Sucrose was employed as carbon source and two distinct approaches, namely hydrothermal and caramelization routes, were investigated to produce it. The NFMs were functionalized by dip-coating and then chemically activated using NaOH to further enhance the adsorption efficiency. The carbonaceous materials-modified NFMs were characterized by scanning electron microscopy (SEM), contact angle, Zeta potential, Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA). Batch and fixed bed experiments revealed that the NFMs modified by dip coating with the carbonaceous materials present competitive adsorption capacity in addition to be a simple, low cost and scalable strategy. The experimental and maximum adsorption capacities of batch adsorption were 371.69 mg/g and 471.58 mg/g for the NFMs modified with hydrothermal carbon, and 260.52 mg/g and 651.04 mg/g for the NFMs coated with black caramel, respectively. The NFMs modified with hydrothermal carbon and caramel carbon showed applicability in scalable systems based on fixed bed adsorption experiments. Our results suggest that nanofibrous membranes coated with carbonaceous materials from sucrose are a suitable tool to develop adsorptive membranes for pollutants removal and open the venue to also explore other carbon-rich sources, including bio- and food residues for adsorptive applications. 653 $aCarbonaceous materials 653 $aFixed bed 653 $aSolution blow spinning 653 $aSustainable materials 700 1 $aANDRE, R. S. 700 1 $aTEODORO, K. B. R. 700 1 $aSCHNEIDER, R. 700 1 $aMERCANTE, L. A. 700 1 $aCORREA, D. S. 773 $tChemical Engineering Journal$gv. 451, e138557, 2023.
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1. |  | FRANCHINI, J. C.; DEBIASI, H.; WRUCK, F. J.; SKORUPA, L. A.; WINK, N. N.; GUISOLPHI, I. J.; CAUMO, A. L.; HATORI, T. Integração lavoura-pecuária: alternativa para diversificação e redução do impacto ambiental do sistema produtivo no Vale do Rio Xingu. Londrina: Embrapa Soja, 2010. 20 p. il. (Embrapa Soja. Circular Técnica, 77).Biblioteca(s): Embrapa Arroz e Feijão; Embrapa Meio Ambiente; Embrapa Soja; Embrapa Solos. |
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2. |  | FRANCHINI, J. C.; DEBIASI, H.; WRUCK, F. J.; SKORUPA, L. A.; WINK, N. N.; GUISOLPHI, I. J.; CAUMO, A. L.; HATORI, T. Matéria orgânica do solo em sistemas produtivos integrados no Mato Grosso associada ao plantio direto e ao uso de forrageiras tropicais. In: REUNIÃO DE PESQUISA DE SOJA DA REGIÃO CENTRAL DO BRASIL, 31., 2010, Brasília, DF. Resumos... Londrina: Embrapa Soja, 2010. p. 410-412. Editores técnicos: Adilson de Oliveira Junior, Odilon Ferreira Saraiva, Regina Maria Villas Bôas de Campo Leite, César de Castro, Jussara Flores de Oliveira Arbues, Wellington Cavalcanti.Tipo: Artigo em Anais de Congresso |
Biblioteca(s): Embrapa Soja. |
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3. |  | FRANCHINI, J. C.; DEBIASI, H.; WRUCK, F. J.; SKORUPA, L. A.; WINK, N. N.; GUISOLPHI, I. J.; CAUMO, A. L.; HATORI, T. Matéria orgânica do solo em sistemas produtivos integrados no Mato Grosso associada ao plantio direto e ao uso de forrageiras tropicais. In: REUNIÃO DE PESQUISA DE SOJA DA REGIÃO CENTRAL DO BRASIL, 31., 2010, Brasília, DF. Resumos... Londrina: Embrapa Soja, 2010. p. 410-412. Editores técnicos: Adilson de Oliveira Junior, Odilon Ferreira Saraiva, Regina Maria Villas Bôas de Campo Leite, Cesar de Castro, Jussara Flores de Oliveira Arbues, Wellington Cavalcanti.Biblioteca(s): Embrapa Arroz e Feijão. |
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