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 | Acesso ao texto completo restrito à biblioteca da Embrapa Florestas. Para informações adicionais entre em contato com cnpf.biblioteca@embrapa.br. |
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Registro Completo |
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Biblioteca(s): |
Embrapa Florestas. |
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Data corrente: |
17/09/2018 |
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Data da última atualização: |
10/12/2018 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
MATOS, M. de; MATTOS, B. D.; TARDY, B. L.; ROJAS, O. J.; MAGALHAES, W. L. E. |
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Afiliação: |
Mailson de Matos, Integrated Program in Engineering & Materials Science, UFPR; Bruno D. Mattos, School of Chemical Engineering; Blaise L. Tardy, School of Chemical Engineering; Orlando J. Rojas, School of Chemical Engineering; WASHINGTON LUIZ ESTEVES MAGALHAES, CNPF. |
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Título: |
Use of biogenic silica in porous alginate matrices for sustainable fertilization with tailored nutrient delivery. |
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Ano de publicação: |
2018 |
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Fonte/Imprenta: |
ACS Sustainable Chemistry & Engineering, v. 6, n. 2, p. 2716-2723, 2018. |
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DOI: |
10.1021/acssuschemeng.7b04331 |
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Idioma: |
Inglês |
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Conteúdo: |
Population growth coupled with significant pressure for clean agricultural practices puts a heavy burden on conventional crop treatments that target high yields with minimal cropland expansion. Optimization of fertilization systems is required as part of the solutions to current megatrends. Herein, we present a sustainable strategy to achieve controlled release formulations for nitrogen fertilization. Specifically, we used interfacial engineering to design alginate-based matrices that incorporated biogenic silica particles to achieve increased interfacial area for dynamic entrapment and release of ammonium nitrate. The incorporation of biogenic silica in the alginate matrix provided a porous architecture spanning length scales from the micro- (within particles) to the macrosize (within the polymeric matrix) levels, leading to tunable patterns of nitrogen release. Alginate? biogenic silica granules approached the European requirements of ?slow-release? compositions. At optimized silica content, 15% of the nitrogen was released within 24 h and 56% over 28 days. The complete nitrogen dissolution was achieved after 60 days. The experimental results and kinetic models provided insights on the mechanisms driving the nitrogen release from the alginate? silica matrix as a function of the pore?polymer hybrid architectures. |
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Palavras-Chave: |
Biogenic silica; Cellulose nanofibrils; Liberação lenta; Nanofibrila de celulose; Sílica biogênica; Slow release. |
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Thesaurus Nal: |
Nitrogen; Sodium alginate. |
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Categoria do assunto: |
X Pesquisa, Tecnologia e Engenharia |
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Marc: |
LEADER 02206naa a2200277 a 4500
001 2095805
005 2018-12-10
008 2018 bl uuuu u00u1 u #d
024 7 $a10.1021/acssuschemeng.7b04331$2DOI
100 1 $aMATOS, M. de
245 $aUse of biogenic silica in porous alginate matrices for sustainable fertilization with tailored nutrient delivery.$h[electronic resource]
260 $c2018
520 $aPopulation growth coupled with significant pressure for clean agricultural practices puts a heavy burden on conventional crop treatments that target high yields with minimal cropland expansion. Optimization of fertilization systems is required as part of the solutions to current megatrends. Herein, we present a sustainable strategy to achieve controlled release formulations for nitrogen fertilization. Specifically, we used interfacial engineering to design alginate-based matrices that incorporated biogenic silica particles to achieve increased interfacial area for dynamic entrapment and release of ammonium nitrate. The incorporation of biogenic silica in the alginate matrix provided a porous architecture spanning length scales from the micro- (within particles) to the macrosize (within the polymeric matrix) levels, leading to tunable patterns of nitrogen release. Alginate? biogenic silica granules approached the European requirements of ?slow-release? compositions. At optimized silica content, 15% of the nitrogen was released within 24 h and 56% over 28 days. The complete nitrogen dissolution was achieved after 60 days. The experimental results and kinetic models provided insights on the mechanisms driving the nitrogen release from the alginate? silica matrix as a function of the pore?polymer hybrid architectures.
650 $aNitrogen
650 $aSodium alginate
653 $aBiogenic silica
653 $aCellulose nanofibrils
653 $aLiberação lenta
653 $aNanofibrila de celulose
653 $aSílica biogênica
653 $aSlow release
700 1 $aMATTOS, B. D.
700 1 $aTARDY, B. L.
700 1 $aROJAS, O. J.
700 1 $aMAGALHAES, W. L. E.
773 $tACS Sustainable Chemistry & Engineering$gv. 6, n. 2, p. 2716-2723, 2018.
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Registro original: |
Embrapa Florestas (CNPF) |
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| Registros recuperados : 45 | |
| 28. |  | MATTOS, B. D.; MISSIO, A. L.; CADEMARTORI, P. H. G. de; GATTO, D. A.; MAGALHAES, W. L. E. Color changes of wood from Pinus taeda and Schizolobium parahybum treated by in situ polymerization of methyl methacrylate using cross-linkers. Maderas. Ciencia y tecnología, Concepción, v. 18, n. 1, p. 113-124, ene. 2016.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 1 |
| Biblioteca(s): Embrapa Florestas. |
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| 30. | | MATTOS, B. D.; MISSIO, A. L.; CADEMARTORI, P. H. G.; LOURENÇON, T. V.; GATTO, D. A.; MAGALHAES, W. L. E. Pinewood composite prepared by in situ graft polymerization of epoxy monomer. Polymer Composites, v. 38, n. 3, p. 597-603, Mar. 2017.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Florestas. |
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| 32. | | MATTOS, B. D.; SILVA, L. R. da; SOUZA, I. R. de; MAGALHAES, W. L. E.; LEME, D. M. Slow delivery of biocide from nanostructured, microscaled, particles reduces its phytoxicity: a model investigation. Journal of Hazardous Materials, v. 367, p. 513-519, Apr. 2019. 7 p.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Florestas. |
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| 37. | | MATTOS, B. D.; TARDY, B. L.; PEZHMAN, M.; KÄMÄRÄINEN, T.; LINDER, M.; SCHREINER, W. H.; MAGALHAES, W. L. E.; ROJAS, O. J. Controlled biocide release from hierarchically-structured biogenic silica: surface chemistry to tune release rate and responsiveness. Scientific Reports, v. 8, Article 5555, Apr. 2018. 11 p.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Florestas. |
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| 38. | | MISSIO, A. L.; MATTOS, B. D.; CADEMARTORI, P. H. G. de; MAGALHAES, W. L. E.; BERGER, C.; HASELEIN, C. R.; GATTO, D. A.; PETUTSCHNIGG, A.; TONDI, G. Impact of tannin as sustainable compatibilizer for wood-polypropylene composites. Polymer Composites, v. 39, n. 2, p. 4275-4284, Dec. 2018.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Florestas. |
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| 39. | | MATOS, M.; MATTOS, B. D.; CADEMARTORI, P. H. G. de; LOURENÇON, T. V.; HANSEL, F. A.; ZANONI, P. R. S.; YAMAMOTO, C. I.; MAGALHAES, W. L. E. Pilot-scaled fast-pyrolysis conversion of eucalyptus wood fines into products: discussion toward possible applications in biofuels, materials, and precursors. BioEnergy Research, v. 13, p. 411-422, 2020.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Florestas. |
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| 40. | | MATTOS, B. D.; TARDY, B. L.; GRECA, L. G.; KÄMÄRÄINEN, T.; XIANG, W.; CUSOLA, O.; MAGALHAES, W. L. E.; ROJAS, O. J. Nanofibrillar networks enable universal assembly of superstructured particle constructs. Science Advances, v. 6, n. 19, eaaz7328, May 2020.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 2 |
| Biblioteca(s): Embrapa Florestas. |
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| Registros recuperados : 45 | |
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| Nenhum registro encontrado para a expressão de busca informada. |
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