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 | Acesso ao texto completo restrito à biblioteca da Embrapa Agroenergia. Para informações adicionais entre em contato com cnpae.biblioteca@embrapa.br. |
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Registro Completo |
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Biblioteca(s): |
Embrapa Agroenergia. |
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Data corrente: |
11/11/2013 |
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Data da última atualização: |
21/09/2017 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
ABDELNUR, P. V.; VAZ, B. G.; ROCHA, J. D.; ALMEIDA, M. B. B. de; TEIXEIRA, M. A. G.; PEREIRA, R. C. L. |
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Afiliação: |
PATRICIA VERARDI ABDELNUR, CNPAE; Boniek G. Vaz, Universidade Federal do Goiás; JOSE DILCIO ROCHA, CNPAE; Marlon B. B. de Almeida, Petrobrás; Marco Antonio G. Teixeira, Petrobrás; Rosana C. L. Pereira, Petrobras. |
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Título: |
Characterization of bio-oils from different pyrolysis process steps and biomass using high-resolution mass spectrometry. |
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Ano de publicação: |
2013 |
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Fonte/Imprenta: |
Energy & Fuels, v. 27, n. 11, p. 6646-6654, 2013. |
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DOI: |
10.1021/ef400788v |
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Idioma: |
Inglês |
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Conteúdo: |
Next-generation biofuels have been widely investigated because they have particular advantages compared to first-generation biofuels. Pyrolysis is an example of a thermochemical route extensively used in oil and coal industries worldwide to produce these biofuels. Strategies for low-cost upgrading are among the biggest challenges facing the adoption of bio-oils in the development of commercial biofuels. Specific biomass sources could be the best option for generating bio-oil with the required properties. For this, it is necessary to understand the composition of these biomasses and their bio-oils. Here, we analyzed bio-oil samples from the fast pyrolysis of different biomasses collected during two different steps of the process by direct-infusion high-resolution mass spectrometry. First, a comparative study of two common high-resolution mass spectrometers, quadrupole time-of-flight mass spectrometry (Q-TOF MS) and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS), was performed to validate the methodology and to investigate the differences in mass discrimination and resolution. FT-ICR MS showed the best performance because of its unsurpassed resolution and accuracy. We apply the common petroleomics tools to interpret the mass spectra obtained. The FT-ICR MS analysis reveals that bio-oils are dominated by Ox species. The class profile of bio-oils was strongly affected by the biomass and steps of the pyrolysis process. |
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Palavras-Chave: |
Bio-oils. |
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Thesaurus Nal: |
biofuels; biomass. |
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Categoria do assunto: |
-- |
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Marc: |
LEADER 02155naa a2200229 a 4500
001 1970901
005 2017-09-21
008 2013 bl uuuu u00u1 u #d
024 7 $a10.1021/ef400788v$2DOI
100 1 $aABDELNUR, P. V.
245 $aCharacterization of bio-oils from different pyrolysis process steps and biomass using high-resolution mass spectrometry.$h[electronic resource]
260 $c2013
520 $aNext-generation biofuels have been widely investigated because they have particular advantages compared to first-generation biofuels. Pyrolysis is an example of a thermochemical route extensively used in oil and coal industries worldwide to produce these biofuels. Strategies for low-cost upgrading are among the biggest challenges facing the adoption of bio-oils in the development of commercial biofuels. Specific biomass sources could be the best option for generating bio-oil with the required properties. For this, it is necessary to understand the composition of these biomasses and their bio-oils. Here, we analyzed bio-oil samples from the fast pyrolysis of different biomasses collected during two different steps of the process by direct-infusion high-resolution mass spectrometry. First, a comparative study of two common high-resolution mass spectrometers, quadrupole time-of-flight mass spectrometry (Q-TOF MS) and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS), was performed to validate the methodology and to investigate the differences in mass discrimination and resolution. FT-ICR MS showed the best performance because of its unsurpassed resolution and accuracy. We apply the common petroleomics tools to interpret the mass spectra obtained. The FT-ICR MS analysis reveals that bio-oils are dominated by Ox species. The class profile of bio-oils was strongly affected by the biomass and steps of the pyrolysis process.
650 $abiofuels
650 $abiomass
653 $aBio-oils
700 1 $aVAZ, B. G.
700 1 $aROCHA, J. D.
700 1 $aALMEIDA, M. B. B. de
700 1 $aTEIXEIRA, M. A. G.
700 1 $aPEREIRA, R. C. L.
773 $tEnergy & Fuels$gv. 27, n. 11, p. 6646-6654, 2013.
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Registro original: |
Embrapa Agroenergia (CNPAE) |
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Registro Completo
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Biblioteca(s): |
Embrapa Clima Temperado. |
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Data corrente: |
23/05/2014 |
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Data da última atualização: |
23/05/2014 |
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Tipo da produção científica: |
Resumo em Anais de Congresso |
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Autoria: |
SIVA, M. L. E.; PICOLOTTO, L.; PEREIRA, I. dos S.; HÖHN, D.; ANTUNES, L. E. C. |
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Afiliação: |
Matheus Lemons e Silva, UFPEL; Luciano Picolotto, Bolsista PNPD/Capes da Embrapa Clima Temperado Pelotas; Ivan Dos Santos Pereira, Bolsista PNPD/Capes da Embrapa Clima Temperado; Daniela Höhn, UFPEL; LUIS EDUARDO CORREA ANTUNES, CPACT. |
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Título: |
Efeito da aplicação de diferentes doses de cianamida hidrogenada sobre brotação de mirtileiro. |
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Ano de publicação: |
2014 |
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Fonte/Imprenta: |
In: ENCONTRO SOBRE PEQUENAS FRUTAS E FRUTAS NATIVAS DO MERCOSUL, 6., 2014, Pelotas. Palestras e resumos... Pelotas: Embrapa Clima Temperado, 2014. 189 p. |
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Idioma: |
Português |
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Thesagro: |
Mirtilo. |
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Categoria do assunto: |
-- |
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URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/item/102561/1/8.pdf
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Marc: |
LEADER 00616nam a2200157 a 4500
001 1986951
005 2014-05-23
008 2014 bl uuuu u00u1 u #d
100 1 $aSIVA, M. L. E.
245 $aEfeito da aplicação de diferentes doses de cianamida hidrogenada sobre brotação de mirtileiro.$h[electronic resource]
260 $aIn: ENCONTRO SOBRE PEQUENAS FRUTAS E FRUTAS NATIVAS DO MERCOSUL, 6., 2014, Pelotas. Palestras e resumos... Pelotas: Embrapa Clima Temperado, 2014. 189 p.$c2014
650 $aMirtilo
700 1 $aPICOLOTTO, L.
700 1 $aPEREIRA, I. dos S.
700 1 $aHÖHN, D.
700 1 $aANTUNES, L. E. C.
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Embrapa Clima Temperado (CPACT) |
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