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5. | | TORRES, J. A.; NOGUEIRA, A. E.; SILVA, G. T. S. T.; OLIVEIRA, C. R. de. Redução fotocatalítica de CO2: influência do caráter básico do MgO. In: WORKSHOP DA REDE DE NANOTECNOLOGIA APLICADA AO AGRONEGÓCIO, 9., 2017, São Carlos. Anais ... São Carlos: Embrapa Instrumentação, 2017. p.414-417. Editores: Caue Ribeiro de Oliveira, Elaine Cristina Paris, Luiz Henrique Capparelli Mattoso, Marcelo Porto Bemquerer, Maria Alice Martins, Odílio Benedito Garrido de Assis. Biblioteca(s): Embrapa Instrumentação. |
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7. | | S. JUNIOR, R. C.; NOGUEIRA, A. E.; GIROTO, A. S.; TORRES, J. A.; RIBEIRO, C.; SIQUEIRA, K. P. F. Microwave-assisted synthesis of Ca1-xMnxMoO4 (x = 0, 0.2, 0.7, and 1) and its application in artificial photosynthesis. Ceramics International, v. 7, 2021. 5388-5398 Biblioteca(s): Embrapa Instrumentação. |
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10. | | NOGUEIRA, A. E.; SILVA, G. T. S. T.; OLIVEIRA, J. A.; TORRES, J. A.; SILVA, M.; CARMO, M.; RIBEIRO, C. Unveiling copper oxide role in CO2 photoreduction process - catalyst or reactant? In: SPRING MEETING OF THE EUROPEAN MATERIALS RESEARCH SOCIETY, 37. 2019, Nice, França, 2019. Biblioteca(s): Embrapa Instrumentação. |
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11. | | NASCIMENTO, V. R. S.; TORRES, J. A.; IGA, G. D.; SANTOS, A. L. dos; EGUES, S. M.; FILHO, J. B. G.; FERREIRA, L. F. R.; RIBEIRO, C. CO2 Photoreduction Product Selectivity with TiO2__Cu Nanocatalysts under Different Reaction Media. ChemCatChem, e202301612, 2024. 1 - 12 Biblioteca(s): Embrapa Instrumentação. |
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12. | | SILVA, G. T. S. T.; NOGUEIRA, A. E.; OLIVEIRA, J. A.; JODAR, L. V.; TORRES, J. A.; OLIVEIRA, C. R. de. Influência da acidez superficial da niobia para o processo de fotorredução de CO2. In: WORKSHOP DA REDE DE NANOTECNOLOGIA APLICADA AO AGRONEGÓCIO, 9., 2017, São Carlos. Anais ... São Carlos: Embrapa Instrumentação, 2017. p.495-498. Editores: Caue Ribeiro de Oliveira, Elaine Cristina Paris, Luiz Henrique Capparelli Mattoso, Marcelo Porto Bemquerer, Maria Alice Martins, Odílio Benedito Garrido de Assis. Biblioteca(s): Embrapa Instrumentação. |
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13. | | RIBEIRO, C.; SILVA, G. T. S. T.; NOGUEIRA, A. E.; TORRES, J. A.; OLIVEIRA, J. A.; LOPES, O. F.; CARMO, M. From environmental applications to renewable energy production: an overview about Nb2O5 and related materials. In: SPRING MEETING OF THE EUROPEAN MATERIALS RESEARCH SOCIETY, 37. 2019, Nice, França, 2019. Biblioteca(s): Embrapa Instrumentação. |
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14. | | FARIA, A. L. A.; CENTURION, H. A.; TORRES, J. A.; GONÇALVES, R. V.; RIBEIRO, L. S.; RIBEIRO, C.; CRUZ, J. C. da; NOGUEIRA, F. G. E. Enhancing Nb2O5 activity for CO2 photoreduction through Cu nanoparticles cocatalyst deposited by DC-magnetron sputtering. Journal of CO2 Utilization, v. 53, 101739, 2021. 1 - 8 Biblioteca(s): Embrapa Instrumentação. |
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17. | | OLIVEIRA, J. A.; SILVA, R. R. M.; SILVA, G. T. S. T. da; TORRES, J. A.; VALI, A.; RIBEIRO, C.; KRISHNAN, R.; RUOTOLO, L. A. M. Copper vanadates: Targeted synthesis of two pure phases and use in a photoanode/cathode setup for selective photoelectrochemical conversion .of carbon dioxide to liquid fuel. Materials Research Bulletin, v 149, 111716, 2022. Biblioteca(s): Embrapa Instrumentação. |
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18. | | PEIXOTO, J. C.; NOGUEIRA, A. E.; DIAS, A.; TORRES, J. A.; CRUZ, J. C. da; RIBEIRO, C.; SIQUEIRA, K. P. F. Experimental evaluation of the activity and selectivity of pure MnWO4 and doped with rare earth ions in the CO2 photoreduction process. Materials Research Bulletin,, v. 153, 111912, 2022. 1 - 10 Biblioteca(s): Embrapa Instrumentação. |
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20. | | RIBEIRO, L. S.; PINATTI, I. M.; TORRES, J. A.; GIROTO, A. S.; LESSE, F.; LONGO, E.; RIBEIRO, C.; NOGUEIRA, A. E. Rapid microwave-assisted hydrothermal synthesis of CuBi2O4 and its application for the artificial photosynthesis. Materials Letters, v. 275, a.128165, 2020 1 - 4 Biblioteca(s): Embrapa Instrumentação. |
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Registros recuperados : 26 | |
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Registro Completo
Biblioteca(s): |
Embrapa Instrumentação. |
Data corrente: |
08/06/2022 |
Data da última atualização: |
08/06/2022 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Circulação/Nível: |
A - 1 |
Autoria: |
PEIXOTO, J. C.; NOGUEIRA, A. E.; DIAS, A.; TORRES, J. A.; CRUZ, J. C. da; RIBEIRO, C.; SIQUEIRA, K. P. F. |
Afiliação: |
CAUE RIBEIRO DE OLIVEIRA, CNPDIA. |
Título: |
Experimental evaluation of the activity and selectivity of pure MnWO4 and doped with rare earth ions in the CO2 photoreduction process. |
Ano de publicação: |
2022 |
Fonte/Imprenta: |
Materials Research Bulletin,, v. 153, 111912, 2022. |
Páginas: |
1 - 10 |
ISSN: |
0025-5408 |
DOI: |
https://doi.org/10.1016/j.materresbull.2022.111912 |
Idioma: |
Inglês |
Conteúdo: |
The reduction of CO2 to produce useful carbon compounds offers a way to manage the emissions from various industrial sectors. However, selecting efficient systems remain a crucial issue, especially considering the low selectivity of the photocatalysts traditionally used in CO2 photoreduction processes. Here we demonstrate that the modification of MnWO4 with rare earth ions (Europium and Terbium) synthesized by the coprecipitation method can tune the activity and selectivity of the products formed in the process of CO2 photoreduction under UV irradiation. The CO2 photoreduction assays indicated that the photocatalysts presented good activity, resulting in acetate, acetone, acetic acid, ethanol, methane, and methanol products. Doping provided selectivity near 100% for CO2 conversion to methanol and increased the capacity of C2 (e.g., ethanol) production, opening the way for a better understanding of the activity and selectivity of tungstates in the CO2 photoreduction process. |
Palavras-Chave: |
Doping; Manganese tungstate; Rare earth; Selectivity. |
Categoria do assunto: |
-- |
URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/doc/1143863/1/p-Experimental-evaluation-of-the-activity-and-selectivity-of-pure-MnWO4-and.pdf
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Marc: |
LEADER 01838naa a2200277 a 4500 001 2143863 005 2022-06-08 008 2022 bl uuuu u00u1 u #d 022 $a0025-5408 024 7 $ahttps://doi.org/10.1016/j.materresbull.2022.111912$2DOI 100 1 $aPEIXOTO, J. C. 245 $aExperimental evaluation of the activity and selectivity of pure MnWO4 and doped with rare earth ions in the CO2 photoreduction process.$h[electronic resource] 260 $c2022 300 $a1 - 10 520 $aThe reduction of CO2 to produce useful carbon compounds offers a way to manage the emissions from various industrial sectors. However, selecting efficient systems remain a crucial issue, especially considering the low selectivity of the photocatalysts traditionally used in CO2 photoreduction processes. Here we demonstrate that the modification of MnWO4 with rare earth ions (Europium and Terbium) synthesized by the coprecipitation method can tune the activity and selectivity of the products formed in the process of CO2 photoreduction under UV irradiation. The CO2 photoreduction assays indicated that the photocatalysts presented good activity, resulting in acetate, acetone, acetic acid, ethanol, methane, and methanol products. Doping provided selectivity near 100% for CO2 conversion to methanol and increased the capacity of C2 (e.g., ethanol) production, opening the way for a better understanding of the activity and selectivity of tungstates in the CO2 photoreduction process. 653 $aDoping 653 $aManganese tungstate 653 $aRare earth 653 $aSelectivity 700 1 $aNOGUEIRA, A. E. 700 1 $aDIAS, A. 700 1 $aTORRES, J. A. 700 1 $aCRUZ, J. C. da 700 1 $aRIBEIRO, C. 700 1 $aSIQUEIRA, K. P. F. 773 $tMaterials Research Bulletin,$gv. 153, 111912, 2022.
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