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Registro Completo |
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Biblioteca(s): |
Embrapa Meio Ambiente. |
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Data corrente: |
05/04/2017 |
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Data da última atualização: |
29/06/2017 |
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Tipo da produção científica: |
Resumo em Anais de Congresso |
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Autoria: |
COA, F.; CLEMENTE, Z.; LOPES, J. R.; RODRIGUES NETO, L. L.; ALVES, O. L.; CASTRO, V. L. S. S. de; BARBIERI, E.; MARTINEZ, D. S. T. |
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Afiliação: |
F. COA, CNPEM; Z. CLEMENTE, Bolsista; J. R. LOPES, CNPEM; L. L. RODRIGUES NETO, Unicamp; O. L. ALVES, Unicamp; VERA LUCIA SCHERHOLZ S DE CASTRO, CNPMA; E. BARBIERI, Instituto de Pesca; D. S. T. MARTINEZ, CNPEM. |
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Título: |
Green mecanochemical process for carbon nanotubes coating with humic acid: application and ecotoxicity evaluation. |
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Ano de publicação: |
2016 |
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Fonte/Imprenta: |
In: ENCONTRO ANUAL DA SOCIEDADE BRASILEIRA DE PESQUISA EM MATERIAIS, 15., 2016, Campinas. [Abstracts...] Rio de Janeiro: Sociedade Brasileira de Pesquisas em Materiais, 2016. Resumo B6SZ. |
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Idioma: |
Inglês |
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Conteúdo: |
Nanomaterials (NM) are promising for environmental remediation due to their unreleased properties such as high surface area and reactivity. Chemical oxidations (H2SO4/HNO3) have been applied to carbon NM in order to favor their application, but these are expensive and hazardous. In this work, industrial grade multiwalled carbon nanotubes (raw-MWCNT) were coated with humic acid (HA) by a ball milling processing (solid state). The aim was to apply a green mechanochemical process to improve the colloidal stability of MWCNTs and their removal capacity of metals. The HA-MWCNT complex was studied by atomic force microscope (AFM), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), dynamic light scattering (DLS), electrophoretic light scattering (ELS) and ultraviolet-visible spectroscopy (UV-Vis). Cu2+ sorption from water by HA-MWCNT, MWCNT-COOH and milledMWCNT were compared. Acute bioassays (96h) were performed with Daphnia magna exposed to 0.0; 0.1; 1.0; 5.0 and 10.0 mg/L of HA-MWCNT. Our results showed that the coating process enhanced the zeta potential of raw-MWCNT of -25.4±0.2 mV to -37.4±0.7 mV and reduced their hydrodynamic diameter of 393.2±27.3 nm to 212.5±5.6 nm in ultrapure water. AFM images of HA-MWCNT showed that it has an irregular surface, due to the humic acid coating. The complex was 4 times (84±1.8%) more efficient to remove Cu2+ than MWCNTCOOH (20.0±1.4%) and 11 times compared to milled-MWCNT (7.6±3.1%). The increases in Oxygen and the reductions in Carbon on surface of HA-MWCNT relative to raw-MWCNT and milled-MWCNT indicated the introduction of functional oxygenated groups on MWCNT. The HA-MWCNT did not show acute toxicity against D. magna. These results suggest that the coating changes the MWCNT surface, resulting in a material with potential to metal remediation, prepared without oxidizing acids and that did not show toxicity on D. magna. MenosNanomaterials (NM) are promising for environmental remediation due to their unreleased properties such as high surface area and reactivity. Chemical oxidations (H2SO4/HNO3) have been applied to carbon NM in order to favor their application, but these are expensive and hazardous. In this work, industrial grade multiwalled carbon nanotubes (raw-MWCNT) were coated with humic acid (HA) by a ball milling processing (solid state). The aim was to apply a green mechanochemical process to improve the colloidal stability of MWCNTs and their removal capacity of metals. The HA-MWCNT complex was studied by atomic force microscope (AFM), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), dynamic light scattering (DLS), electrophoretic light scattering (ELS) and ultraviolet-visible spectroscopy (UV-Vis). Cu2+ sorption from water by HA-MWCNT, MWCNT-COOH and milledMWCNT were compared. Acute bioassays (96h) were performed with Daphnia magna exposed to 0.0; 0.1; 1.0; 5.0 and 10.0 mg/L of HA-MWCNT. Our results showed that the coating process enhanced the zeta potential of raw-MWCNT of -25.4±0.2 mV to -37.4±0.7 mV and reduced their hydrodynamic diameter of 393.2±27.3 nm to 212.5±5.6 nm in ultrapure water. AFM images of HA-MWCNT showed that it has an irregular surface, due to the humic acid coating. The complex was 4 times (84±1.8%) more efficient to remove Cu2+ than MWCNTCOOH (20.0±1.4%) and 11 times compared to milled-MWCNT (7.6±3.1%). ... Mostrar Tudo |
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Palavras-Chave: |
Ecotoxicologia; Nantubes. |
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Categoria do assunto: |
W Química e Física |
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URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/item/161193/1/2016RA-040.pdf
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Marc: |
LEADER 02763nam a2200217 a 4500
001 2068138
005 2017-06-29
008 2016 bl uuuu u00u1 u #d
100 1 $aCOA, F.
245 $aGreen mecanochemical process for carbon nanotubes coating with humic acid$bapplication and ecotoxicity evaluation.$h[electronic resource]
260 $aIn: ENCONTRO ANUAL DA SOCIEDADE BRASILEIRA DE PESQUISA EM MATERIAIS, 15., 2016, Campinas. [Abstracts...] Rio de Janeiro: Sociedade Brasileira de Pesquisas em Materiais, 2016. Resumo B6SZ.$c2016
520 $aNanomaterials (NM) are promising for environmental remediation due to their unreleased properties such as high surface area and reactivity. Chemical oxidations (H2SO4/HNO3) have been applied to carbon NM in order to favor their application, but these are expensive and hazardous. In this work, industrial grade multiwalled carbon nanotubes (raw-MWCNT) were coated with humic acid (HA) by a ball milling processing (solid state). The aim was to apply a green mechanochemical process to improve the colloidal stability of MWCNTs and their removal capacity of metals. The HA-MWCNT complex was studied by atomic force microscope (AFM), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), dynamic light scattering (DLS), electrophoretic light scattering (ELS) and ultraviolet-visible spectroscopy (UV-Vis). Cu2+ sorption from water by HA-MWCNT, MWCNT-COOH and milledMWCNT were compared. Acute bioassays (96h) were performed with Daphnia magna exposed to 0.0; 0.1; 1.0; 5.0 and 10.0 mg/L of HA-MWCNT. Our results showed that the coating process enhanced the zeta potential of raw-MWCNT of -25.4±0.2 mV to -37.4±0.7 mV and reduced their hydrodynamic diameter of 393.2±27.3 nm to 212.5±5.6 nm in ultrapure water. AFM images of HA-MWCNT showed that it has an irregular surface, due to the humic acid coating. The complex was 4 times (84±1.8%) more efficient to remove Cu2+ than MWCNTCOOH (20.0±1.4%) and 11 times compared to milled-MWCNT (7.6±3.1%). The increases in Oxygen and the reductions in Carbon on surface of HA-MWCNT relative to raw-MWCNT and milled-MWCNT indicated the introduction of functional oxygenated groups on MWCNT. The HA-MWCNT did not show acute toxicity against D. magna. These results suggest that the coating changes the MWCNT surface, resulting in a material with potential to metal remediation, prepared without oxidizing acids and that did not show toxicity on D. magna.
653 $aEcotoxicologia
653 $aNantubes
700 1 $aCLEMENTE, Z.
700 1 $aLOPES, J. R.
700 1 $aRODRIGUES NETO, L. L.
700 1 $aALVES, O. L.
700 1 $aCASTRO, V. L. S. S. de
700 1 $aBARBIERI, E.
700 1 $aMARTINEZ, D. S. T.
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Registro original: |
Embrapa Meio Ambiente (CNPMA) |
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 | Acesso ao texto completo restrito à biblioteca da Embrapa Recursos Genéticos e Biotecnologia. Para informações adicionais entre em contato com cenargen.biblioteca@embrapa.br. |
Registro Completo
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Biblioteca(s): |
Embrapa Acre; Embrapa Recursos Genéticos e Biotecnologia. |
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Data corrente: |
22/03/2006 |
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Data da última atualização: |
30/11/2023 |
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Tipo da produção científica: |
Artigo em Anais de Congresso |
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Autoria: |
FALEIRO, F. G.; ANDRADE, R. P.; KARIA, C. T.; VALENTIM, J. F.; ANDRADE, C. M. S. de; RAMOS, A. K. B.; BELLON, G.; PEÑALOZA, A. del P. de S.; VALLS, J. F. M. |
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Afiliação: |
Embrapa Acre; JUDSON FERREIRA VALENTIM, CPAF-AC; CARLOS MAURICIO SOARES DE ANDRADE, CPAF-AC. |
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Título: |
Variabilidade genética de acessos de Arachis pintoi avaliados em diferentes centros de pesquisa da Embrapa com base em marcadores RAPD. |
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Ano de publicação: |
2005 |
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Fonte/Imprenta: |
In: REUNIÃO ANUAL DA SOCIEDADE BRASILEIRA DE ZOOTECNIA, 42., 2005, Goiânia. A produção animal e o foco no agronegócio: anais. Goiânia: Sociedade Brasileira de Zootecnia, 2005. |
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Páginas: |
5 p. |
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Descrição Física: |
1 CD-ROM. |
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Idioma: |
Português |
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Palavras-Chave: |
Marcadores RAPD; Variabilidade genética. |
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Thesaurus NAL: |
Arachis pintoi. |
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Categoria do assunto: |
-- |
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Marc: |
LEADER 00924nam a2200241 a 4500
001 1506367
005 2023-11-30
008 2005 bl uuuu u00u1 u #d
100 1 $aFALEIRO, F. G.
245 $aVariabilidade genética de acessos de Arachis pintoi avaliados em diferentes centros de pesquisa da Embrapa com base em marcadores RAPD.$h[electronic resource]
260 $aIn: REUNIÃO ANUAL DA SOCIEDADE BRASILEIRA DE ZOOTECNIA, 42., 2005, Goiânia. A produção animal e o foco no agronegócio: anais. Goiânia: Sociedade Brasileira de Zootecnia$c2005
300 $a5 p.$c1 CD-ROM.
650 $aArachis pintoi
653 $aMarcadores RAPD
653 $aVariabilidade genética
700 1 $aANDRADE, R. P.
700 1 $aKARIA, C. T.
700 1 $aVALENTIM, J. F.
700 1 $aANDRADE, C. M. S. de
700 1 $aRAMOS, A. K. B.
700 1 $aBELLON, G.
700 1 $aPEÑALOZA, A. del P. de S.
700 1 $aVALLS, J. F. M.
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Embrapa Acre (CPAF-AC) |
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