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| 84. |  | PARRA, A.; LEMOS, S. G.; NOGUEIRA, A. R. de A.; TORRE NETO, A.; ALONSO, J. ATP determination using a flow injection potentiometric cobalt electrode. In: RENCONTRE TRANSFRONTALIÈRE CAPTEURS ET BIOCAPTEURS, 8., 2003, Ceret, FR: Université de Perpignan, 2003.| Biblioteca(s): Embrapa Pecuária Sudeste. |
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| 88. | | SÁ, I. P.; BANHOS, S.; ANDRADE, M. S.; NHAMUE, P. F.; NOGUEIRA, A. R. de A. Chemical speciation of hexavalent chromium in organic fertilizer by LC-ICP-MS and spectrophotometry. In: BRAZILIAN MEETING ON CHEMICAL SPECIATION, 7.; RIO SYMPOSIUM ON ATOMIC SPECTROMETRY, 16., 2023, Bento Gonçalves, RS. Abstracts... 2023.| Biblioteca(s): Embrapa Pecuária Sudeste. |
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| 95. | | MACHADO, R. C.; ARAMENDIA, M.; NOGUEIRA, A. R. de A.; RESANO, M. Interference-free determination of Ca in ultrapure water, concentrated acids and hydrogen peroxide using isotope dilution, ICP-MS and CH3F as a reaction gas. In: JORNADA DE JÓVENES INVESTIGADORES DEL I3A, 6., Zaragoza, España. Anales... Zaragoza, España: University of Zaragoza, 2017. v. 5.| Biblioteca(s): Embrapa Pecuária Sudeste. |
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| 99. | | MOTTA, A. V. C.; LEMOS, S. G.; NOGUEIRA, A. R. de A.; PARRA, A.; ALONSO, J. Avaliação de eletrodo metálico de cobalto na determinação de adenosina trifosfato (ATP). In: REUNIÃO ANUAL DA SOCIEDADE DE QUÍMICA, 27.; CONGRESO LATINO AMERICANO DE QUÍMICA, 26., 2004, Salvador, BA. Anais... Salvador: SBQ, 2004. EQ-137.| Biblioteca(s): Embrapa Pecuária Sudeste. |
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 | Acesso ao texto completo restrito à biblioteca da Embrapa Pecuária Sudeste. Para informações adicionais entre em contato com cppse.biblioteca@embrapa.br. |
Registro Completo
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Biblioteca(s): |
Embrapa Instrumentação; Embrapa Pecuária Sudeste. |
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Data corrente: |
14/12/2017 |
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Data da última atualização: |
14/12/2017 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Circulação/Nível: |
A - 1 |
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Autoria: |
PEREIRA, E. I.; NOGUEIRA, A. R. de A.; CRUZ, C. C. T. da; GUIMARAES, G. G. F.; FOSCHINI, M. M.; BERNARDI, A. C. de C.; OLIVEIRA, C. R. de. |
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Afiliação: |
Elaine Inacio Pereira, Bolsista/Embrapa Pecuária Sudeste; ANA RITA DE ARAUJO NOGUEIRA, CPPSE; Camila Conceição Tomé da Cruz, UFSCar; Gelton Geraldo Fernandes Guimarães, Bolsista/Embrapa Instrumentação; Milene Mitsuyuki Foschini, Bolsista/Embrapa Instrumentação; ALBERTO CARLOS DE CAMPOS BERNARDI, CPPSE; CAUE RIBEIRO DE OLIVEIRA, CNPDIA. |
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Título: |
Controlled urea release employing nanocomposites increases the efficiency of nitrogen use by forage. |
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Ano de publicação: |
2017 |
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Fonte/Imprenta: |
ACS Sustainable Chemistry & Engineering, v. 5, n. 11, p. 9993-10001, 2017. |
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ISSN: |
2168-0485 |
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DOI: |
10.1021/acssuschemeng.7b01919 |
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Idioma: |
Inglês |
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Conteúdo: |
The rapid hydrolysis of urea applied to the soil surface causes high rates of NH3 volatilization, leading to adverse environmental impacts and decreased uptake of N by crops. One approach that can be used to improve the efficiency of urea use involves strategies to control its release, such as the coating of granules with polymers. However, the effectiveness of this method can be limited by poor interaction between the coating and the granule surface. We, therefore, propose a novel class of nanocomposite fertilizers, based on clay exfoliation in urea matrices, with or without polymerization using formaldehyde as a strategy to increase the interaction between urea and the additives. A comparative study was performed using various slow-release fertilizers, determining the amounts of volatilized ammonia, dry matter production, and efficiency of urea-N uptake by ryegrass, in a trial carried out in a greenhouse. Interaction, such as solubility, thickness and chemical composition of the composites revealed aspects of the interaction that affected the slow%release behavior of urea in soil and the availability of N for plants. It could be concluded that the controlled release of urea from the nanocomposites decreased NH3 volatilization, resulting in a more constant N availability in the soil and better synchronization with the nutritional demands of the plants. The new fertilizers offer a practical option for increasing urea%N efficiency, reducing environmental impacts caused by NH3 loss, and improving the quality of forage grown on low fertility soils such as Oxisols. MenosThe rapid hydrolysis of urea applied to the soil surface causes high rates of NH3 volatilization, leading to adverse environmental impacts and decreased uptake of N by crops. One approach that can be used to improve the efficiency of urea use involves strategies to control its release, such as the coating of granules with polymers. However, the effectiveness of this method can be limited by poor interaction between the coating and the granule surface. We, therefore, propose a novel class of nanocomposite fertilizers, based on clay exfoliation in urea matrices, with or without polymerization using formaldehyde as a strategy to increase the interaction between urea and the additives. A comparative study was performed using various slow-release fertilizers, determining the amounts of volatilized ammonia, dry matter production, and efficiency of urea-N uptake by ryegrass, in a trial carried out in a greenhouse. Interaction, such as solubility, thickness and chemical composition of the composites revealed aspects of the interaction that affected the slow%release behavior of urea in soil and the availability of N for plants. It could be concluded that the controlled release of urea from the nanocomposites decreased NH3 volatilization, resulting in a more constant N availability in the soil and better synchronization with the nutritional demands of the plants. The new fertilizers offer a practical option for increasing urea%N efficiency, reducing environmental impacts caused by NH3... Mostrar Tudo |
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Palavras-Chave: |
Ammonia loss; Urea controlled release. |
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Thesaurus NAL: |
forage. |
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Categoria do assunto: |
W Química e Física |
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Marc: |
LEADER 02391naa a2200253 a 4500
001 2082569
005 2017-12-14
008 2017 bl uuuu u00u1 u #d
022 $a2168-0485
024 7 $a10.1021/acssuschemeng.7b01919$2DOI
100 1 $aPEREIRA, E. I.
245 $aControlled urea release employing nanocomposites increases the efficiency of nitrogen use by forage.$h[electronic resource]
260 $c2017
520 $aThe rapid hydrolysis of urea applied to the soil surface causes high rates of NH3 volatilization, leading to adverse environmental impacts and decreased uptake of N by crops. One approach that can be used to improve the efficiency of urea use involves strategies to control its release, such as the coating of granules with polymers. However, the effectiveness of this method can be limited by poor interaction between the coating and the granule surface. We, therefore, propose a novel class of nanocomposite fertilizers, based on clay exfoliation in urea matrices, with or without polymerization using formaldehyde as a strategy to increase the interaction between urea and the additives. A comparative study was performed using various slow-release fertilizers, determining the amounts of volatilized ammonia, dry matter production, and efficiency of urea-N uptake by ryegrass, in a trial carried out in a greenhouse. Interaction, such as solubility, thickness and chemical composition of the composites revealed aspects of the interaction that affected the slow%release behavior of urea in soil and the availability of N for plants. It could be concluded that the controlled release of urea from the nanocomposites decreased NH3 volatilization, resulting in a more constant N availability in the soil and better synchronization with the nutritional demands of the plants. The new fertilizers offer a practical option for increasing urea%N efficiency, reducing environmental impacts caused by NH3 loss, and improving the quality of forage grown on low fertility soils such as Oxisols.
650 $aforage
653 $aAmmonia loss
653 $aUrea controlled release
700 1 $aNOGUEIRA, A. R. de A.
700 1 $aCRUZ, C. C. T. da
700 1 $aGUIMARAES, G. G. F.
700 1 $aFOSCHINI, M. M.
700 1 $aBERNARDI, A. C. de C.
700 1 $aOLIVEIRA, C. R. de
773 $tACS Sustainable Chemistry & Engineering$gv. 5, n. 11, p. 9993-10001, 2017.
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