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Registro Completo |
Biblioteca(s): |
Embrapa Pecuária Sudeste. |
Data corrente: |
21/06/2016 |
Data da última atualização: |
08/03/2017 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Autoria: |
AMARAL, C. D. B. do; MACHADO, R. C.; VIRGILIO, A.; SCHIAVO, D.; NOGUEIRA, A. R. de A.; NOBREGA, J. de A. |
Afiliação: |
Clarice Dias Britto do Amaral, UFSCar; Raquel Cardoso Machado, UFSCar; Alex Virgilio, UFSCar; Daniela Schiavo, Agilent Technologies; ANA RITA DE ARAUJO NOGUEIRA, CPPSE; Joaquim de Araújo Nóbrega, UFSCar. |
Título: |
Critical evaluation of internal standardization in ICP tandem mass spectrometry and feasibility of the oxygen reaction for boron determination in plants. |
Ano de publicação: |
2016 |
Fonte/Imprenta: |
In: Journal of Analytical Atomic Spectrometry, v.31, issue 6, p. 1179-1184, 2016 |
ISSN: |
1364-5544 |
DOI: |
10.1039/c6ja00133e |
Idioma: |
Inglês |
Conteúdo: |
The feasibility of internal standardization and the oxygen reaction in ICP-MS was studied for accurate determination of boron. Lithium, Be and Rh were systematically evaluated as internal standards (I.S.) for B determination in plants by ICP-MS/MS using a single quadrupole mode and MS/MS mode with O2 into a cell, where B and internal standard signal intensities were processed either after both or only one of them reacted. Carbon is a source of spectral and matrix interferences in B determination by ICP-MS. The use of instrumental strategies such as tandem mass spectrometry (MS/MS) concomitantly with internal standardization demands further investigation about the I.S. behaviour regarding the gas phase reaction with oxygen. The behaviours of B and Be, as well as their oxides, were quite similar in an octopole reaction system containing O2. The coexistence of spectral and non-spectral interferences was evidenced by increasing carbon concentrations in samples and checking positive errors caused for 11B+. Recoveries for B determination in plant certified reference materials without I.S. ranged from 98 to 145% and with Be as an internal standard ranged from 98 to 108%. Beryllium presented favourable characteristics as an internal standard for B due to its mass closeness, similar ionization energy, and reactivity with oxygen. |
Palavras-Chave: |
ICP; Plants; Spectometry. |
Thesaurus Nal: |
boron. |
Categoria do assunto: |
F Plantas e Produtos de Origem Vegetal |
Marc: |
LEADER 02146naa a2200253 a 4500 001 2047538 005 2017-03-08 008 2016 bl uuuu u00u1 u #d 022 $a1364-5544 024 7 $a10.1039/c6ja00133e$2DOI 100 1 $aAMARAL, C. D. B. do 245 $aCritical evaluation of internal standardization in ICP tandem mass spectrometry and feasibility of the oxygen reaction for boron determination in plants.$h[electronic resource] 260 $c2016 520 $aThe feasibility of internal standardization and the oxygen reaction in ICP-MS was studied for accurate determination of boron. Lithium, Be and Rh were systematically evaluated as internal standards (I.S.) for B determination in plants by ICP-MS/MS using a single quadrupole mode and MS/MS mode with O2 into a cell, where B and internal standard signal intensities were processed either after both or only one of them reacted. Carbon is a source of spectral and matrix interferences in B determination by ICP-MS. The use of instrumental strategies such as tandem mass spectrometry (MS/MS) concomitantly with internal standardization demands further investigation about the I.S. behaviour regarding the gas phase reaction with oxygen. The behaviours of B and Be, as well as their oxides, were quite similar in an octopole reaction system containing O2. The coexistence of spectral and non-spectral interferences was evidenced by increasing carbon concentrations in samples and checking positive errors caused for 11B+. Recoveries for B determination in plant certified reference materials without I.S. ranged from 98 to 145% and with Be as an internal standard ranged from 98 to 108%. Beryllium presented favourable characteristics as an internal standard for B due to its mass closeness, similar ionization energy, and reactivity with oxygen. 650 $aboron 653 $aICP 653 $aPlants 653 $aSpectometry 700 1 $aMACHADO, R. C. 700 1 $aVIRGILIO, A. 700 1 $aSCHIAVO, D. 700 1 $aNOGUEIRA, A. R. de A. 700 1 $aNOBREGA, J. de A. 773 $tIn: Journal of Analytical Atomic Spectrometry$gv.31, issue 6, p. 1179-1184, 2016
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Embrapa Pecuária Sudeste (CPPSE) |
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| Acesso ao texto completo restrito à biblioteca da Embrapa Gado de Corte. Para informações adicionais entre em contato com cnpgc.biblioteca@embrapa.br. |
Registro Completo
Biblioteca(s): |
Embrapa Gado de Corte. |
Data corrente: |
14/11/1996 |
Data da última atualização: |
14/11/1996 |
Autoria: |
MADRUGA, C. R.; SCHENK, M. A. M.; SILVA, R. A. M.; SILVA, J. A. |
Afiliação: |
EMBRAPA. Centro Nacional de Pesquisa de Gado de Corte (Campo Grande, MS). |
Título: |
Isolamento de Trypanosoma vivax em bovinos na sub-regiao de Pocone do Pantanal de Mato Grosso, Brasil. |
Ano de publicação: |
1996 |
Fonte/Imprenta: |
In : CONGRESSO PANAMERICANO DE CIENCIAS VETERINARIAS, 15., 1996, Campo Grande. Resumos. [S.l.] : Associacao Panamericana de Ciencias Veterinarias, [1996?]. |
Páginas: |
p.326. (PN11.252). |
Idioma: |
Português |
Notas: |
CNPGC. PANVET. |
Palavras-Chave: |
Brasil; Health; Mato Grosso; Pocone; Sanidade. |
Thesagro: |
Bovino; Isolamento; Trypanosoma Vivax. |
Thesaurus NAL: |
cattle; Pantanal. |
Categoria do assunto: |
-- |
Marc: |
LEADER 00879naa a2200289 a 4500 001 1319357 005 1996-11-14 008 1996 bl uuuu u00u1 u #d 100 1 $aMADRUGA, C. R. 245 $aIsolamento de Trypanosoma vivax em bovinos na sub-regiao de Pocone do Pantanal de Mato Grosso, Brasil. 260 $c1996 300 $ap.326. (PN11.252). 500 $aCNPGC. PANVET. 650 $acattle 650 $aPantanal 650 $aBovino 650 $aIsolamento 650 $aTrypanosoma Vivax 653 $aBrasil 653 $aHealth 653 $aMato Grosso 653 $aPocone 653 $aSanidade 700 1 $aSCHENK, M. A. M. 700 1 $aSILVA, R. A. M. 700 1 $aSILVA, J. A. 773 $tIn : CONGRESSO PANAMERICANO DE CIENCIAS VETERINARIAS, 15., 1996, Campo Grande. Resumos. [S.l.] : Associacao Panamericana de Ciencias Veterinarias, [1996?].
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