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Registro Completo |
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
29/03/2022 |
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Data da última atualização: |
24/11/2022 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
FACURE, M. H. M.; SCHNEIDER, R.; MERCANTE, L. A.; CORREA, D. S. |
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Afiliação: |
DANIEL SOUZA CORREA, CNPDIA. |
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Título: |
Rational hydrothermal synthesis of graphene quantum dots with optimized luminescent properties for sensing applications. |
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Ano de publicação: |
2022 |
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Fonte/Imprenta: |
Materials Today Chemistry, v. 23, 100, 2022. |
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Páginas: |
1 - 12 |
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ISSN: |
2468-5194 |
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DOI: |
https://doi.org/10.1016/j.mtchem.2021.100755 |
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Idioma: |
Inglês |
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Conteúdo: |
Hydrothermal synthesis using graphene oxide (GO) as a precursor has been used to produce luminescent graphene quantum dots (GQDs). However, such a method usually requires many reagents and multistep pretreatments, while can give rise to GQDs with low quantum yield (QY). Here, we investigated the concentration, the temperature of synthesis, and the pH of the GO solution used in the hydrothermal method through factorial design experiments aiming to optimize the QY of GQDs to reach a better control of their luminescent properties. The best synthesis condition (2 mg/mL, 175 C, and pH ¼ 8.0) yielded GQDs with a relatively high QY (8.9%) without the need of using laborious steps or dopants. GQDs synthesized under different conditions were characterized to understand the role of each synthesis parameter in the materials' structure and luminescence properties. It was found that the control of the synthesis parameters enables the tailoring of the amount of specific oxygen functionalities onto the surface of the GQDs. By changing the synthesis' conditions, it was possible to prioritize the production of GQDs with more hydroxyl or carboxyl groups, which influence their luminescent properties. The asdeveloped GQDs with tailored composition were used as luminescent probes to detect Fe3þ. The lowest limit of detection (0.136 mM) was achieved using GQDs with higher amounts of carboxylic groups, while wider linear range was obtained by GQDs with superior QY. Thus, our findings contribute to rationally produce GQDs with tailored properties for varied applications by simply adjusting the synthesis conditions and suggest a pathway to understand the mechanism of detection of GQDs-based optical sensors. MenosHydrothermal synthesis using graphene oxide (GO) as a precursor has been used to produce luminescent graphene quantum dots (GQDs). However, such a method usually requires many reagents and multistep pretreatments, while can give rise to GQDs with low quantum yield (QY). Here, we investigated the concentration, the temperature of synthesis, and the pH of the GO solution used in the hydrothermal method through factorial design experiments aiming to optimize the QY of GQDs to reach a better control of their luminescent properties. The best synthesis condition (2 mg/mL, 175 C, and pH ¼ 8.0) yielded GQDs with a relatively high QY (8.9%) without the need of using laborious steps or dopants. GQDs synthesized under different conditions were characterized to understand the role of each synthesis parameter in the materials' structure and luminescence properties. It was found that the control of the synthesis parameters enables the tailoring of the amount of specific oxygen functionalities onto the surface of the GQDs. By changing the synthesis' conditions, it was possible to prioritize the production of GQDs with more hydroxyl or carboxyl groups, which influence their luminescent properties. The asdeveloped GQDs with tailored composition were used as luminescent probes to detect Fe3þ. The lowest limit of detection (0.136 mM) was achieved using GQDs with higher amounts of carboxylic groups, while wider linear range was obtained by GQDs with superior QY. Thus, our findings contribute to... Mostrar Tudo |
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Palavras-Chave: |
Factorial design; Fe3þ detection; GQDs; Hydrothermal method; Quantum yield. |
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Categoria do assunto: |
-- |
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Marc: |
LEADER 02486naa a2200253 a 4500
001 2141567
005 2022-11-24
008 2022 bl uuuu u00u1 u #d
022 $a2468-5194
024 7 $ahttps://doi.org/10.1016/j.mtchem.2021.100755$2DOI
100 1 $aFACURE, M. H. M.
245 $aRational hydrothermal synthesis of graphene quantum dots with optimized luminescent properties for sensing applications.$h[electronic resource]
260 $c2022
300 $a1 - 12
520 $aHydrothermal synthesis using graphene oxide (GO) as a precursor has been used to produce luminescent graphene quantum dots (GQDs). However, such a method usually requires many reagents and multistep pretreatments, while can give rise to GQDs with low quantum yield (QY). Here, we investigated the concentration, the temperature of synthesis, and the pH of the GO solution used in the hydrothermal method through factorial design experiments aiming to optimize the QY of GQDs to reach a better control of their luminescent properties. The best synthesis condition (2 mg/mL, 175 C, and pH ¼ 8.0) yielded GQDs with a relatively high QY (8.9%) without the need of using laborious steps or dopants. GQDs synthesized under different conditions were characterized to understand the role of each synthesis parameter in the materials' structure and luminescence properties. It was found that the control of the synthesis parameters enables the tailoring of the amount of specific oxygen functionalities onto the surface of the GQDs. By changing the synthesis' conditions, it was possible to prioritize the production of GQDs with more hydroxyl or carboxyl groups, which influence their luminescent properties. The asdeveloped GQDs with tailored composition were used as luminescent probes to detect Fe3þ. The lowest limit of detection (0.136 mM) was achieved using GQDs with higher amounts of carboxylic groups, while wider linear range was obtained by GQDs with superior QY. Thus, our findings contribute to rationally produce GQDs with tailored properties for varied applications by simply adjusting the synthesis conditions and suggest a pathway to understand the mechanism of detection of GQDs-based optical sensors.
653 $aFactorial design
653 $aFe3þ detection
653 $aGQDs
653 $aHydrothermal method
653 $aQuantum yield
700 1 $aSCHNEIDER, R.
700 1 $aMERCANTE, L. A.
700 1 $aCORREA, D. S.
773 $tMaterials Today Chemistry$gv. 23, 100, 2022.
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Embrapa Instrumentação (CNPDIA) |
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| 6. |  | SILVA, G. O. da; BORTOLETTO, A. C.; FELDBERG, N. P.; NASCIMENTO, W. M. Importância da utilização de mudas sadias em hortaliças de propagação vegetativa. Revista Batata Show, p. 68-74, mar. 2022. Artigo publicado também em Seed News, Ano 24, n. 5, p. 38-42, 2021.| Tipo: Artigo de Divulgação na Mídia |
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| 7. | | SILVA, G. O. da; BORTOLETTO, A. C.; FELDBERG, N. P.; NASCIMENTO, W. M. Importância da utilização de mudas sadias em hortaliças de propagação vegetativa. Revista Batata Show, v. 22, n. 62, p. 68-74, mar. 2022. Artigo publicado também em Seed News, Ano 24, n. 5, p. 38-42, 2021.| Tipo: Artigo de Divulgação na Mídia |
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| 14. | | FONSECA, K, G. da; FALEIRO, F. G.; JUNQUEIRA, N. T. V.; BARTH, M.; FELDBERG, N. P. Morphoagronomic and molecular characterization of ornamental passion fruit cultivars. Pesquisa Agropecuária Brasileira, Brasília, DF, v. 52, n. 10, p. 849-860, out. 2017. Título em português: Caracterização morfoagronômica e molecular de cultivares de maracujazeiro ornamental.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 2 |
| Biblioteca(s): Embrapa Cerrados; Embrapa Unidades Centrais. |
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| 16. | | BETTONI, J. C.; FELDBERG, N. P.; NAVA, G.; VEIGA, M. da; WILDNER, L. do P. Vegetative, productive and qualitative performance of grapevine "Cabernet Sauvignon" according to the use of winter cover crops¹. Revista Ceres, Viçosa, v. 63, n.4, p. 538-544, jul/ago, 2016.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 1 |
| Biblioteca(s): Embrapa Clima Temperado. |
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| 17. | | FELDBERG, N. P.; BARBOSA, W.; MAYER, N. A.; SANTOS, F. M. da C. Propagação vegetativa de porta-exertos de pereira por estacas semi-lenhosas. Revista Ceres, Viçosa, v. 57, n. 6, p. 810-816, nov/dez, 2010.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 3 |
| Biblioteca(s): Embrapa Clima Temperado. |
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| 18. | | RASEIRA, M. do C. B.; FRANZON, R. C.; SCARANARI, C.; FELDBERG, N.; PEREIRA, J. F. M. Programa de melhoramento genético de frutas de caroço da Embrapa. In: ENCUENTRO LATINOAMERICANO PRUNUS SIN FRONTERAS, 6., 2015, Pelotas. Anais... Brasília, DF: Embrapa, 2015. p. 74-76| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Clima Temperado. |
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| 19. | | DECONTI, G.; MARAN, B.; RITSCHEL, P. S.; GROHS, D. S.; FELDBERG, N. P.; NACHTIGAL, J. C.; MARTINS, C. R. Avaliação de clones de videira "Bordô" para elaboração de sucos tintos. In:ENCONTRO DE INICIAÇÃO CIENTÍFICA, 19., ENCONTRO DE PÓS-GRADUAÇÃO, 15., 2022, Bento Gonçalves. Anais... Bento Gonçalves: Embrapa Uva e Vinho, 2023. p. 13. (Embrapa Uva e Vinho. Eventos Técnicos & Científicos, 1)| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Clima Temperado; Embrapa Uva e Vinho. |
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| Registros recuperados : 63 | |
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