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Registro Completo |
Biblioteca(s): |
Embrapa Instrumentação. |
Data corrente: |
21/06/2021 |
Data da última atualização: |
10/06/2022 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Autoria: |
PARRA, G. G.; CORREA, D. S.; SILVEIRA-ALVES JUNIOR, E.; ALMEIDA, L. M.; SOUZA, M. A. R.; DE BONI, L.; MISOGUTI, L.; MENDONÇA, C. R.; ZÍLIO, S. C.; BARBOSA NETO, N. M.; BORISSEVITCH, I. E.; GONÇALVES, P. J. |
Afiliação: |
DANIEL SOUZA CORREA, CNPDIA. |
Título: |
Effects of meso-tetrakis (4-sulfonatophenyl) porphyrin (TPPS4) aggregation on its spectral and kinetic characteristics and singlet oxygen production. |
Ano de publicação: |
2021 |
Fonte/Imprenta: |
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, v. 261, e120063, 2021. |
Páginas: |
1-7 |
ISSN: |
1386-1425 |
DOI: |
https://doi.org/10.1016/j.saa.2021.120063 |
Idioma: |
Inglês |
Conteúdo: |
The present work reports the effects of meso-tetrakis (4-sulfonatophenyl) porphyrin (TPPS4) aggregation on its excited states absorption spectra, triplet states quenching by molecular oxygen and singlet oxygen production. Experimental techniques such as optical absorption, Z-scan with a white light continuum source and the Laser Flash Photolysis were used to fulfil the study. J-aggregates possess reverse saturable absorption in the 505–660 nm spectral range with a peak centered close to 540 nm. These facts together with their fast relaxation time suggest that they can be employed as material for ultrafast optical limiting and switching. Even though aggregation reduces the porphyrin excited-state lifetimes and quantum yields, it does not reduce the probability of the contact between the quencher and the excited aggregate. Aggregation does not change the contribution of energy transfer mechanisms to triplet state quenching by molecular oxygen. The production of singlet oxygen, the intense absorption in the phototherapeutic window and the high efficiency of conversion of light energy into heat, allow consider J-aggregates as a theranostic agent for photomedicine. It is proposed to use J-aggregates for diagnostics by photoacoustic images and in combination with a near-infrared photodynamic/photothermal dual mode therapy, thus improving synergistically the therapeutic response. |
Palavras-Chave: |
Photodynamic therapy; Photophysical characterization; Photothermal therapy; Theranostics. |
Categoria do assunto: |
-- |
Marc: |
LEADER 02503naa a2200337 a 4500 001 2132447 005 2022-06-10 008 2021 bl uuuu u00u1 u #d 022 $a1386-1425 024 7 $ahttps://doi.org/10.1016/j.saa.2021.120063$2DOI 100 1 $aPARRA, G. G. 245 $aEffects of meso-tetrakis (4-sulfonatophenyl) porphyrin (TPPS4) aggregation on its spectral and kinetic characteristics and singlet oxygen production.$h[electronic resource] 260 $c2021 300 $a1-7 520 $aThe present work reports the effects of meso-tetrakis (4-sulfonatophenyl) porphyrin (TPPS4) aggregation on its excited states absorption spectra, triplet states quenching by molecular oxygen and singlet oxygen production. Experimental techniques such as optical absorption, Z-scan with a white light continuum source and the Laser Flash Photolysis were used to fulfil the study. J-aggregates possess reverse saturable absorption in the 505–660 nm spectral range with a peak centered close to 540 nm. These facts together with their fast relaxation time suggest that they can be employed as material for ultrafast optical limiting and switching. Even though aggregation reduces the porphyrin excited-state lifetimes and quantum yields, it does not reduce the probability of the contact between the quencher and the excited aggregate. Aggregation does not change the contribution of energy transfer mechanisms to triplet state quenching by molecular oxygen. The production of singlet oxygen, the intense absorption in the phototherapeutic window and the high efficiency of conversion of light energy into heat, allow consider J-aggregates as a theranostic agent for photomedicine. It is proposed to use J-aggregates for diagnostics by photoacoustic images and in combination with a near-infrared photodynamic/photothermal dual mode therapy, thus improving synergistically the therapeutic response. 653 $aPhotodynamic therapy 653 $aPhotophysical characterization 653 $aPhotothermal therapy 653 $aTheranostics 700 1 $aCORREA, D. S. 700 1 $aSILVEIRA-ALVES JUNIOR, E. 700 1 $aALMEIDA, L. M. 700 1 $aSOUZA, M. A. R. 700 1 $aDE BONI, L. 700 1 $aMISOGUTI, L. 700 1 $aMENDONÇA, C. R. 700 1 $aZÍLIO, S. C. 700 1 $aBARBOSA NETO, N. M. 700 1 $aBORISSEVITCH, I. E. 700 1 $aGONÇALVES, P. J. 773 $tSpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy$gv. 261, e120063, 2021.
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Embrapa Instrumentação (CNPDIA) |
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Biblioteca(s): |
Embrapa Trigo. |
Data corrente: |
07/02/2014 |
Data da última atualização: |
07/02/2014 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Circulação/Nível: |
A - 1 |
Autoria: |
DRESCHER, M. S.; ELTZ, F. L. F.; DENARDIN, J. E.; FAGANELLO, A.; DRESCHER, G. L. |
Afiliação: |
MARTA SANDRA DRESCHER, DOUTORANDA UFSM; FLÁVIO LUIZ FOLETTO ELTZ, UFSM; JOSE ELOIR DENARDIN, CNPT; ANTONIO FAGANELLO, CNPT; GERSON LAERSON DRESCHER, GRADUANDO UFSM. |
Título: |
Resistência à penetração e rendimento da soja após intervenção mecânica em latossolo vermelho sob plantio direto. |
Ano de publicação: |
2012 |
Fonte/Imprenta: |
Revista Brasileira de Ciência do Solo, Viçosa, MG, v. 36, n. 6, p. 1836-1844, Nov./Dez. 2012. |
ISSN: |
0100-0683 |
DOI: |
http://dx.doi.org/10.1590/S0100-06832012000600018 |
Idioma: |
Português |
Palavras-Chave: |
Densidade do solo; Preparo do solo; Soil preparation. |
Thesagro: |
Compactação do Solo. |
Thesaurus NAL: |
soil compaction; soil density. |
Categoria do assunto: |
-- |
URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/item/96738/1/2013-revista-brasileira-ciencia-solo-v36n6p1836.pdf
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Marc: |
LEADER 00868naa a2200253 a 4500 001 1979126 005 2014-02-07 008 2012 bl uuuu u00u1 u #d 022 $a0100-0683 024 7 $ahttp://dx.doi.org/10.1590/S0100-06832012000600018$2DOI 100 1 $aDRESCHER, M. S. 245 $aResistência à penetração e rendimento da soja após intervenção mecânica em latossolo vermelho sob plantio direto.$h[electronic resource] 260 $c2012 650 $asoil compaction 650 $asoil density 650 $aCompactação do Solo 653 $aDensidade do solo 653 $aPreparo do solo 653 $aSoil preparation 700 1 $aELTZ, F. L. F. 700 1 $aDENARDIN, J. E. 700 1 $aFAGANELLO, A. 700 1 $aDRESCHER, G. L. 773 $tRevista Brasileira de Ciência do Solo, Viçosa, MG$gv. 36, n. 6, p. 1836-1844, Nov./Dez. 2012.
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