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Registro Completo |
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Biblioteca(s): |
Embrapa Milho e Sorgo. |
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Data corrente: |
10/11/2016 |
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Data da última atualização: |
14/04/2021 |
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Tipo da produção científica: |
Resumo em Anais de Congresso |
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Autoria: |
SOUSA, S. M. de; OLIVEIRA-PAIVA, C. A.; GOMES, E. A.; LANA, U. G. de P.; SANTOS, N. G.; OLIVEIRA, L. B.; BATISTA, F. de C. |
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Afiliação: |
SYLVIA MORAIS DE SOUSA TINOCO, CNPMS; CHRISTIANE ABREU DE OLIVEIRA PAIVA, CNPMS; ELIANE APARECIDA GOMES, CNPMS; UBIRACI GOMES DE PAULA LANA, CNPMS; NATALIA GOÇALVES SANTOS, ETMSL, Sete Lagoas, MG.; LUCIMARA BATISTA OLIVEIRA, ETMSL, Sete Lagoas, MG.; FERNANDA DE CASSIA BATISTA, UNIFEMM, Sete Lagoas, MG. |
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Título: |
Ação de bioestimulantes à base de microrganismos em plântulas de milho crescidas em solução nutritiva. |
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Ano de publicação: |
2016 |
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Fonte/Imprenta: |
In: REUNIÃO BRASILEIRA DE FERTILIDADE DO SOLO E NUTRIÇÃO DE PLANTAS, 32.; REUNIÃO BRASILEIRA SOBRE MICORRIZAS, 16.; SIMPÓSIO BRASILEIRO DE MICROBIOLOGIA DO SOLO, 14.; REUNIÃO BRASILEIRA DE BIOLOGIA DO SOLO, 11., 2016, Goiânia. Rumo aos novos desafios: [anais]. Viçosa, MG: Sociedade Brasileira de Ciência do Solo, 2016. |
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Páginas: |
p. 886. |
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Idioma: |
Português |
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Notas: |
FertBio 2016. |
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Palavras-Chave: |
Promotor de crescimento. |
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Thesagro: |
Raiz; Solução nutritiva. |
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Thesaurus Nal: |
Roots. |
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Categoria do assunto: |
S Ciências Biológicas |
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URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/item/149915/1/Acao-bioestimulantes.pdf
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Marc: |
LEADER 01016nam a2200241 a 4500
001 2056190
005 2021-04-14
008 2016 bl uuuu u00u1 u #d
100 1 $aSOUSA, S. M. de
245 $aAção de bioestimulantes à base de microrganismos em plântulas de milho crescidas em solução nutritiva.$h[electronic resource]
260 $aIn: REUNIÃO BRASILEIRA DE FERTILIDADE DO SOLO E NUTRIÇÃO DE PLANTAS, 32.; REUNIÃO BRASILEIRA SOBRE MICORRIZAS, 16.; SIMPÓSIO BRASILEIRO DE MICROBIOLOGIA DO SOLO, 14.; REUNIÃO BRASILEIRA DE BIOLOGIA DO SOLO, 11., 2016, Goiânia. Rumo aos novos desafios: [anais]. Viçosa, MG: Sociedade Brasileira de Ciência do Solo$c2016
300 $ap. 886.
500 $aFertBio 2016.
650 $aRoots
650 $aRaiz
650 $aSolução nutritiva
653 $aPromotor de crescimento
700 1 $aOLIVEIRA-PAIVA, C. A.
700 1 $aGOMES, E. A.
700 1 $aLANA, U. G. de P.
700 1 $aSANTOS, N. G.
700 1 $aOLIVEIRA, L. B.
700 1 $aBATISTA, F. de C.
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Registro original: |
Embrapa Milho e Sorgo (CNPMS) |
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Registro Completo
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
05/10/2023 |
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Data da última atualização: |
15/01/2024 |
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Tipo da produção científica: |
Orientação de Tese de Pós-Graduação |
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Autoria: |
CRUZ, J. C. da. |
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Título: |
PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. |
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Ano de publicação: |
2023 |
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Fonte/Imprenta: |
2023. Tese ( Doutorado em Ciências, área de concentração: físico-química), Universidade Federal de São Carlos, Programa de Pós-Graduação em Química, São Carlos-SP. |
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Páginas: |
98 p. |
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Idioma: |
Inglês |
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Notas: |
Orientador: Caue Ribeiro de Oliveira
Coorientadora: Elaine Cristina Paris |
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Conteúdo: |
ABSTRACT PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. The CH4 partial oxidation into value-added chemicals by solar means has been discussed as alternative for emission abatement, a fundamental topic for sustainable production with lower global warming gas emissions in future. So far, various semiconductor photocatalysts have been developed. However, the understanding of the main factors influencing photocatalysts' activities on controlled oxidation of methane to methanol is still an issue, especially due to methane overoxidation to CO2. Thus, we propose that the semiconductor must have a valence band (VB) favorable to produce hydroxyl radicals (?OH) and a conduction band (CB) not advantageous to superoxide radical (O2). Furthermore, the concentration of the hydroxyl radicals is fundamental and should be fine-tuned for selectively oxidize methane. O2 also is the key oxidant for process control, since O2 may scavenging methyl radicals (?CH3) that further react with ?OH to form methanol. Our results showed that the required band edge positions for photocatalysts (e.g., Bi2O3) seems correct to obtain significant amounts of desirable chemical products, taking as main products methanol (3700 μmol g-1 ) and acetic acid acetic acid (~2036 μmol g -1 h -1 ) from pure CH4 at room temperature and atmospheric pressure. Moreover, longer hydrocarbons (e.g., ethanol and acetone) could be produced depending on the reaction condition. ESR experiments proved the formation of ?CH3 and ?OH, and isotope labeling experiment with 13CH4 asthe reactant also was conducted, confirming that CH3OH comes from CH4 photooxidation.Another sustainable route to control the CH4 oxidation driven by chloride intermediates in solution using Bismuth-based semiconductors excited in visible light was investigated. BiOCl, a perovskite layered material, exhibited promising photocatalytic performance for methane conversion to methanol (1300 µmol g-1 ), acetic acid (435 µmol g-1 ), and ethanol (57 µmol g-1 ) without foreign radicals to control the reaction. Our findings are significant to new level of understanding in methane?s efficient partial photooxidation, which opens a way to control competitive reactions by appropriate band edge positions in photocatalysts to greater selectivity and avoid its overoxidation to CO2 MenosABSTRACT PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. The CH4 partial oxidation into value-added chemicals by solar means has been discussed as alternative for emission abatement, a fundamental topic for sustainable production with lower global warming gas emissions in future. So far, various semiconductor photocatalysts have been developed. However, the understanding of the main factors influencing photocatalysts' activities on controlled oxidation of methane to methanol is still an issue, especially due to methane overoxidation to CO2. Thus, we propose that the semiconductor must have a valence band (VB) favorable to produce hydroxyl radicals (?OH) and a conduction band (CB) not advantageous to superoxide radical (O2). Furthermore, the concentration of the hydroxyl radicals is fundamental and should be fine-tuned for selectively oxidize methane. O2 also is the key oxidant for process control, since O2 may scavenging methyl radicals (?CH3) that further react with ?OH to form methanol. Our results showed that the required band edge positions for photocatalysts (e.g., Bi2O3) seems correct to obtain significant amounts of desirable chemical products, taking as main products methanol (3700 μmol g-1 ) and acetic acid acetic acid (~2036 μmol g -1 h -1 ) from pure CH4 at room temperature and atmospheric pressure. Moreover, longer hydrocarbons (e.g., ethanol and acetone) could be produced depending on the reaction condition. ESR experiments proved the formatio... Mostrar Tudo |
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Palavras-Chave: |
Superoxidação em CO2. |
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Categoria do assunto: |
-- |
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URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/doc/1157124/1/TS-PHOTOCATALYTIC-CONTROLLED-OXIDATION.pdf
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Marc: |
LEADER 02955nam a2200145 a 4500
001 2157124
005 2024-01-15
008 2023 bl uuuu m 00u1 u #d
100 1 $aCRUZ, J. C. da
245 $aPHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE.$h[electronic resource]
260 $a2023. Tese ( Doutorado em Ciências, área de concentração: físico-química), Universidade Federal de São Carlos, Programa de Pós-Graduação em Química, São Carlos-SP.$c2023
300 $a98 p.
500 $aOrientador: Caue Ribeiro de Oliveira Coorientadora: Elaine Cristina Paris
520 $aABSTRACT PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. The CH4 partial oxidation into value-added chemicals by solar means has been discussed as alternative for emission abatement, a fundamental topic for sustainable production with lower global warming gas emissions in future. So far, various semiconductor photocatalysts have been developed. However, the understanding of the main factors influencing photocatalysts' activities on controlled oxidation of methane to methanol is still an issue, especially due to methane overoxidation to CO2. Thus, we propose that the semiconductor must have a valence band (VB) favorable to produce hydroxyl radicals (?OH) and a conduction band (CB) not advantageous to superoxide radical (O2). Furthermore, the concentration of the hydroxyl radicals is fundamental and should be fine-tuned for selectively oxidize methane. O2 also is the key oxidant for process control, since O2 may scavenging methyl radicals (?CH3) that further react with ?OH to form methanol. Our results showed that the required band edge positions for photocatalysts (e.g., Bi2O3) seems correct to obtain significant amounts of desirable chemical products, taking as main products methanol (3700 μmol g-1 ) and acetic acid acetic acid (~2036 μmol g -1 h -1 ) from pure CH4 at room temperature and atmospheric pressure. Moreover, longer hydrocarbons (e.g., ethanol and acetone) could be produced depending on the reaction condition. ESR experiments proved the formation of ?CH3 and ?OH, and isotope labeling experiment with 13CH4 asthe reactant also was conducted, confirming that CH3OH comes from CH4 photooxidation.Another sustainable route to control the CH4 oxidation driven by chloride intermediates in solution using Bismuth-based semiconductors excited in visible light was investigated. BiOCl, a perovskite layered material, exhibited promising photocatalytic performance for methane conversion to methanol (1300 µmol g-1 ), acetic acid (435 µmol g-1 ), and ethanol (57 µmol g-1 ) without foreign radicals to control the reaction. Our findings are significant to new level of understanding in methane?s efficient partial photooxidation, which opens a way to control competitive reactions by appropriate band edge positions in photocatalysts to greater selectivity and avoid its overoxidation to CO2
653 $aSuperoxidação em CO2
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