| |
|
|
|
Registro Completo |
|
Biblioteca(s): |
Embrapa Semiárido. |
|
Data corrente: |
22/09/2004 |
|
Data da última atualização: |
24/07/2023 |
|
Tipo da produção científica: |
Documentos |
|
Autoria: |
PORTO, E. R.; ARAÚJO, O. J. de; ARAUJO, G. G. L. de; AMORIM, M. C. C.; PAULINO, R. V.; MATOS, A. N. B. |
|
Afiliação: |
EVERALDO ROCHA PORTO, CPATSA; ODILON JUVINO DE ARAÚJO, CODEVASF; GHERMAN GARCIA LEAL DE ARAUJO, CPATSA; MIRIAM CLEIDE CAVALCANTE AMORIM, COMPESA; RENATA VALE PAULINO ANA NERY BARBOSA MATOS, Bolsista da Fundação Banco do Brasil; ANA NERY BARBOSA MATOS. |
|
Título: |
Sistema de produção integrado usando efluentes da dessalinização. |
|
Ano de publicação: |
2004 |
|
Fonte/Imprenta: |
Petrolina: Embrapa Semi-Árido, 2004. |
|
Páginas: |
22 p. |
|
Descrição Física: |
il. |
|
Série: |
(Embrapa Semi-Árido. Documentos, 187). |
|
Idioma: |
Português |
|
Conteúdo: |
O potencial; Os componentes: Obtenção de água potável para o consumo humano; Produção de tilápia rosa; Produção de forragem irrigada; Engorda de caprinos/ovinos; Custos e benefícios do sistema. |
|
Palavras-Chave: |
Alimentação animal; Consumo humano; Cultivo de erva-sal; Oreochromis sp; Reuso da água; Sistema de produção integrado; Tilápia rosa. |
|
Thesagro: |
Água Potável; Água Salobra; Caprino; Dessalinização; Feno; Irrigação; Nutrição Animal; Ovino; Planta Forrageira; Produção; Produção animal. |
|
Thesaurus Nal: |
Animal production; Atriplex nummularia. |
|
Categoria do assunto: |
L Ciência Animal e Produtos de Origem Animal |
|
URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/CPATSA/30457/1/SDC187.pdf
|
|
Marc: |
LEADER 01391nam a2200433 a 4500
001 1154726
005 2023-07-24
008 2004 bl uuuu u0uu1 u #d
100 1 $aPORTO, E. R.
245 $aSistema de produção integrado usando efluentes da dessalinização.
260 $aPetrolina: Embrapa Semi-Árido$c2004
300 $a22 p.$cil.
490 $a(Embrapa Semi-Árido. Documentos, 187).
520 $aO potencial; Os componentes: Obtenção de água potável para o consumo humano; Produção de tilápia rosa; Produção de forragem irrigada; Engorda de caprinos/ovinos; Custos e benefícios do sistema.
650 $aAnimal production
650 $aAtriplex nummularia
650 $aÁgua Potável
650 $aÁgua Salobra
650 $aCaprino
650 $aDessalinização
650 $aFeno
650 $aIrrigação
650 $aNutrição Animal
650 $aOvino
650 $aPlanta Forrageira
650 $aProdução
650 $aProdução animal
653 $aAlimentação animal
653 $aConsumo humano
653 $aCultivo de erva-sal
653 $aOreochromis sp
653 $aReuso da água
653 $aSistema de produção integrado
653 $aTilápia rosa
700 1 $aARAÚJO, O. J. de
700 1 $aARAUJO, G. G. L. de
700 1 $aAMORIM, M. C. C.
700 1 $aPAULINO, R. V.
700 1 $aMATOS, A. N. B.
Download
Esconder MarcMostrar Marc Completo |
|
Registro original: |
Embrapa Semiárido (CPATSA) |
|
|
Biblioteca |
ID |
Origem |
Tipo/Formato |
Classificação |
Cutter |
Registro |
Volume |
Status |
URL |
Voltar
|
|
|
Registro Completo
|
Biblioteca(s): |
Embrapa Instrumentação. |
|
Data corrente: |
05/10/2023 |
|
Data da última atualização: |
15/01/2024 |
|
Tipo da produção científica: |
Orientação de Tese de Pós-Graduação |
|
Autoria: |
CRUZ, J. C. da. |
|
Título: |
PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. |
|
Ano de publicação: |
2023 |
|
Fonte/Imprenta: |
2023. Tese ( Doutorado em Ciências, área de concentração: físico-química), Universidade Federal de São Carlos, Programa de Pós-Graduação em Química, São Carlos-SP. |
|
Páginas: |
98 p. |
|
Idioma: |
Inglês |
|
Notas: |
Orientador: Caue Ribeiro de Oliveira
Coorientadora: Elaine Cristina Paris |
|
Conteúdo: |
ABSTRACT PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. The CH4 partial oxidation into value-added chemicals by solar means has been discussed as alternative for emission abatement, a fundamental topic for sustainable production with lower global warming gas emissions in future. So far, various semiconductor photocatalysts have been developed. However, the understanding of the main factors influencing photocatalysts' activities on controlled oxidation of methane to methanol is still an issue, especially due to methane overoxidation to CO2. Thus, we propose that the semiconductor must have a valence band (VB) favorable to produce hydroxyl radicals (?OH) and a conduction band (CB) not advantageous to superoxide radical (O2). Furthermore, the concentration of the hydroxyl radicals is fundamental and should be fine-tuned for selectively oxidize methane. O2 also is the key oxidant for process control, since O2 may scavenging methyl radicals (?CH3) that further react with ?OH to form methanol. Our results showed that the required band edge positions for photocatalysts (e.g., Bi2O3) seems correct to obtain significant amounts of desirable chemical products, taking as main products methanol (3700 μmol g-1 ) and acetic acid acetic acid (~2036 μmol g -1 h -1 ) from pure CH4 at room temperature and atmospheric pressure. Moreover, longer hydrocarbons (e.g., ethanol and acetone) could be produced depending on the reaction condition. ESR experiments proved the formation of ?CH3 and ?OH, and isotope labeling experiment with 13CH4 asthe reactant also was conducted, confirming that CH3OH comes from CH4 photooxidation.Another sustainable route to control the CH4 oxidation driven by chloride intermediates in solution using Bismuth-based semiconductors excited in visible light was investigated. BiOCl, a perovskite layered material, exhibited promising photocatalytic performance for methane conversion to methanol (1300 µmol g-1 ), acetic acid (435 µmol g-1 ), and ethanol (57 µmol g-1 ) without foreign radicals to control the reaction. Our findings are significant to new level of understanding in methane?s efficient partial photooxidation, which opens a way to control competitive reactions by appropriate band edge positions in photocatalysts to greater selectivity and avoid its overoxidation to CO2 MenosABSTRACT PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. The CH4 partial oxidation into value-added chemicals by solar means has been discussed as alternative for emission abatement, a fundamental topic for sustainable production with lower global warming gas emissions in future. So far, various semiconductor photocatalysts have been developed. However, the understanding of the main factors influencing photocatalysts' activities on controlled oxidation of methane to methanol is still an issue, especially due to methane overoxidation to CO2. Thus, we propose that the semiconductor must have a valence band (VB) favorable to produce hydroxyl radicals (?OH) and a conduction band (CB) not advantageous to superoxide radical (O2). Furthermore, the concentration of the hydroxyl radicals is fundamental and should be fine-tuned for selectively oxidize methane. O2 also is the key oxidant for process control, since O2 may scavenging methyl radicals (?CH3) that further react with ?OH to form methanol. Our results showed that the required band edge positions for photocatalysts (e.g., Bi2O3) seems correct to obtain significant amounts of desirable chemical products, taking as main products methanol (3700 μmol g-1 ) and acetic acid acetic acid (~2036 μmol g -1 h -1 ) from pure CH4 at room temperature and atmospheric pressure. Moreover, longer hydrocarbons (e.g., ethanol and acetone) could be produced depending on the reaction condition. ESR experiments proved the formatio... Mostrar Tudo |
|
Palavras-Chave: |
Superoxidação em CO2. |
|
Categoria do assunto: |
-- |
|
URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/doc/1157124/1/TS-PHOTOCATALYTIC-CONTROLLED-OXIDATION.pdf
|
|
Marc: |
LEADER 02955nam a2200145 a 4500
001 2157124
005 2024-01-15
008 2023 bl uuuu m 00u1 u #d
100 1 $aCRUZ, J. C. da
245 $aPHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE.$h[electronic resource]
260 $a2023. Tese ( Doutorado em Ciências, área de concentração: físico-química), Universidade Federal de São Carlos, Programa de Pós-Graduação em Química, São Carlos-SP.$c2023
300 $a98 p.
500 $aOrientador: Caue Ribeiro de Oliveira Coorientadora: Elaine Cristina Paris
520 $aABSTRACT PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. The CH4 partial oxidation into value-added chemicals by solar means has been discussed as alternative for emission abatement, a fundamental topic for sustainable production with lower global warming gas emissions in future. So far, various semiconductor photocatalysts have been developed. However, the understanding of the main factors influencing photocatalysts' activities on controlled oxidation of methane to methanol is still an issue, especially due to methane overoxidation to CO2. Thus, we propose that the semiconductor must have a valence band (VB) favorable to produce hydroxyl radicals (?OH) and a conduction band (CB) not advantageous to superoxide radical (O2). Furthermore, the concentration of the hydroxyl radicals is fundamental and should be fine-tuned for selectively oxidize methane. O2 also is the key oxidant for process control, since O2 may scavenging methyl radicals (?CH3) that further react with ?OH to form methanol. Our results showed that the required band edge positions for photocatalysts (e.g., Bi2O3) seems correct to obtain significant amounts of desirable chemical products, taking as main products methanol (3700 μmol g-1 ) and acetic acid acetic acid (~2036 μmol g -1 h -1 ) from pure CH4 at room temperature and atmospheric pressure. Moreover, longer hydrocarbons (e.g., ethanol and acetone) could be produced depending on the reaction condition. ESR experiments proved the formation of ?CH3 and ?OH, and isotope labeling experiment with 13CH4 asthe reactant also was conducted, confirming that CH3OH comes from CH4 photooxidation.Another sustainable route to control the CH4 oxidation driven by chloride intermediates in solution using Bismuth-based semiconductors excited in visible light was investigated. BiOCl, a perovskite layered material, exhibited promising photocatalytic performance for methane conversion to methanol (1300 µmol g-1 ), acetic acid (435 µmol g-1 ), and ethanol (57 µmol g-1 ) without foreign radicals to control the reaction. Our findings are significant to new level of understanding in methane?s efficient partial photooxidation, which opens a way to control competitive reactions by appropriate band edge positions in photocatalysts to greater selectivity and avoid its overoxidation to CO2
653 $aSuperoxidação em CO2
Download
Esconder MarcMostrar Marc Completo |
|
Registro original: |
Embrapa Instrumentação (CNPDIA) |
|
|
Biblioteca |
ID |
Origem |
Tipo/Formato |
Classificação |
Cutter |
Registro |
Volume |
Status |
Fechar
|
| Expressão de busca inválida. Verifique!!! |
|
|
