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Biblioteca(s): |
Embrapa Florestas. |
Data corrente: |
04/01/2019 |
Data da última atualização: |
07/01/2019 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Autoria: |
VÉLEZ, D. C. P.; MAGALHAES, W. L. E.; CAPIBIANCO, G. |
Afiliação: |
Diana C. P. Vélez, Pós graduanda da UFPR; WASHINGTON LUIZ ESTEVES MAGALHAES, CNPF; G. Capobianco, UEPG. |
Título: |
Carbon fiber from fast pyrolysis bio-oil. |
Ano de publicação: |
2018 |
Fonte/Imprenta: |
Science and Technology of Materials, v. 30, Suppl. 1, p. 16-22, Dec. 2018. |
DOI: |
10.1016/j.stmat.2018.10.001 |
Idioma: |
Inglês |
Conteúdo: |
The fast pyrolysis bio-oil is a promising product to be used as fuel. It is produced by means of wood particles subjected to high heat rates for very little time. However, the resulting oil has a very high oxygen content, which to be used as fuel requires upgrading processes, which makes its costs higher than mineral oil. The aim of this paper is to study the fast pyrolysis bio-oil as a precursor of carbon fibers. A heat treatment in the bio-oil was used until the optimum softening point temperature was reached for the subsequent melt spinning process. Additives such as kraft lignin and furfuryl alcohol improved the spinning process and caused the fibers to resist the carbonization step. Characterization by Fourier-transformed infrared, 13C VACP-MAS NRM and Raman revealed that the heat-treated bio-oil presented a great amount of oxygenated groups and that mainly the aromatization of the samples was verified after the carbonization process. SEM images showed that the fibers diameters were too high. |
Palavras-Chave: |
Álcool furfurílico; Bio óleo; Bio-oil; Fast pyrolysis; Kraft lignin; Pirólise rápida. |
Thesagro: |
Lignina. |
Thesaurus Nal: |
Furfuryl alcohol; Heat treatment. |
Categoria do assunto: |
X Pesquisa, Tecnologia e Engenharia |
Marc: |
LEADER 01762naa a2200265 a 4500 001 2103035 005 2019-01-07 008 2018 bl uuuu u00u1 u #d 024 7 $a10.1016/j.stmat.2018.10.001$2DOI 100 1 $aVÉLEZ, D. C. P. 245 $aCarbon fiber from fast pyrolysis bio-oil.$h[electronic resource] 260 $c2018 520 $aThe fast pyrolysis bio-oil is a promising product to be used as fuel. It is produced by means of wood particles subjected to high heat rates for very little time. However, the resulting oil has a very high oxygen content, which to be used as fuel requires upgrading processes, which makes its costs higher than mineral oil. The aim of this paper is to study the fast pyrolysis bio-oil as a precursor of carbon fibers. A heat treatment in the bio-oil was used until the optimum softening point temperature was reached for the subsequent melt spinning process. Additives such as kraft lignin and furfuryl alcohol improved the spinning process and caused the fibers to resist the carbonization step. Characterization by Fourier-transformed infrared, 13C VACP-MAS NRM and Raman revealed that the heat-treated bio-oil presented a great amount of oxygenated groups and that mainly the aromatization of the samples was verified after the carbonization process. SEM images showed that the fibers diameters were too high. 650 $aFurfuryl alcohol 650 $aHeat treatment 650 $aLignina 653 $aÁlcool furfurílico 653 $aBio óleo 653 $aBio-oil 653 $aFast pyrolysis 653 $aKraft lignin 653 $aPirólise rápida 700 1 $aMAGALHAES, W. L. E. 700 1 $aCAPIBIANCO, G. 773 $tScience and Technology of Materials$gv. 30, Suppl. 1, p. 16-22, Dec. 2018.
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1. | | SCHNEIDER, M. P. C.; BATISTA, C. G.; CARVALHO, D. de; CERQUEIRA, R.; CIAMPI, A. Y.; FRANCESCHINELLI, E. V.; GENTILE, R.; GONÇALVES, E. C.; GRATIVOL, A. D.; NASCIMENTO, M. T.; POVOA, J. R.; VASCONCELOS, G. M. P.; WADT, L. H. de O.; WIEDERHECKER, H. C. Genética de populações naturais. In: RAMBALDI, D. M.; OLIVEIRA, D. A. (org.). Fragmentação de ecossistemas: causas, efeitos sobre a biodiversidade e recomendações de políticas públicas. Brasília, DF: Ministério do Meio Ambiente, 2003. p. 297-315.Tipo: Capítulo em Livro Técnico-Científico |
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