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| Registros recuperados : 9 | |
| 4. |  | LOPES, O. F.; CARVALHO, K. T. G.; MACEDO, G. K.; MENDONÇA, V. R. de; AVANSI JR, W.; RIBEIRO, C. Synthesis of BiVO4 via oxidant peroxo-method: insights into the photocatalytic performance and degradation mechanism of pollutants. New journal of chemistry, [Inglaterra], v. 39, n. 8, p. 6231-6237, 2015.| Biblioteca(s): Embrapa Instrumentação. |
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| 6. | | SILVA, L. F. da; AVANSI JR, W.; ANDRÉS, J.; RIBEIRO, C.; MOREIRA, M. L.; LONGO, E.; MASTELARO, V. R. Long-range and short-range structures of cube-like shape SrTiO3 powders: microwave-assisted hydrothermal synthesis and photocatalytic activity. Physical Chemistry Chemical Physics, Cambridge, v. 15, n. 29, p. 12386-12393, 2013.| Biblioteca(s): Embrapa Instrumentação. |
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| 7. | | GUIMARÃES, G. G. F.; KLAIC, R.; GIROTO. A. S.; MAJARON, V. F.; AVANSI JR, W.; FARINAS, C. S.; OLIVEIRA, C. R. de. Smart fertilization based on sulfur-phosphate composites: synergy among materials in a structure with multiple fertilization roles. ACS Sustainable Chemistry & Engineering, v. 6, n. 9, p. 12187-12196, 2018. 12187-12196| Biblioteca(s): Embrapa Instrumentação. |
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| 8. | | FERREIRA, M. A.; SILVA, G. T. S. T. da; LOPES, O. F.; MASTELARO, V. R.; RIBEIRO, C.; PIRES, M. J. M.; MALAGUTTI, A. R.; AVANSI JR, W.; MOURÃO, H. A. J. L. Fabrication of SrTiO3/g-C3N4 heterostructures for visible light-induced photocatalysis. Materials Science in Semiconductor Processing, n. 108, a. 104887, 2020. 1-10| Biblioteca(s): Embrapa Instrumentação. |
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| 9. | | SILVA, G. T. S. T. da; LOPES, O. F.; CATTO, A. C.; PATROCÍNIO, A. O. T.; RODRIGUES, J. E. F. S.; MESQUITA, A.; RIBEIRO, C.; AVANSI JR, W.; SILVA, L. F. da. Long-and short-range structure of SnO2 nanoparticles: Synthesis and photo (electro)catalytic activity. Materials Chemistry and Physics, v. 305, 127989, 2023. 1 - 9| Biblioteca(s): Embrapa Instrumentação. |
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| Registros recuperados : 9 | |
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 | Acesso ao texto completo restrito à biblioteca da Embrapa Instrumentação. Para informações adicionais entre em contato com cnpdia.biblioteca@embrapa.br. |
Registro Completo
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
05/07/2023 |
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Data da última atualização: |
05/07/2023 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Circulação/Nível: |
A - 2 |
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Autoria: |
SILVA, G. T. S. T. da; LOPES, O. F.; CATTO, A. C.; PATROCÍNIO, A. O. T.; RODRIGUES, J. E. F. S.; MESQUITA, A.; RIBEIRO, C.; AVANSI JR, W.; SILVA, L. F. da. |
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Afiliação: |
CAUE RIBEIRO DE OLIVEIRA, CNPDIA. |
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Título: |
Long-and short-range structure of SnO2 nanoparticles: Synthesis and photo (electro)catalytic activity. |
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Ano de publicação: |
2023 |
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Fonte/Imprenta: |
Materials Chemistry and Physics, v. 305, 127989, 2023. |
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Páginas: |
1 - 9 |
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ISSN: |
0254-0584 |
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DOI: |
https://doi.org/10.1016/j.matchemphys.2023.127989 |
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Idioma: |
Inglês |
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Conteúdo: |
We report herein a detailed study on the influence of hydrothermal treatment temperature on both long- and short-range structures of SnO2 nanoparticles (NPs) applied as photocatalysts for the discoloration of organic pollutants and as photoanodes for water splitting. Synchrotron X-ray diffraction and X-ray absorption near-edge spectroscopy measurements confirmed the enhancement of the structural order of SnO2 NPs as a function of hydrothermal temperature. Fourier transform infrared spectroscopy revealed that the hydrothermal treatment increased the amount of hydroxyl groups on the SnO2 NPs surface. Regarding the photocatalytic activity, the NPs were able to promote the discoloration of different dyes that can act as potential organic pollutants. The photoelectrocatalytic performance of the samples depended on the hydrothermal treatment temperature, with the degree of crystallinity and surface hydroxyl groups playing a significant role in their performance as photoanodes. In particular, the NPs treated at a higher temperature presented a better degree of crystallinity, in addition to many hydroxyls on their surface, leading to increased mobility of the photogenerated charge carriers and improving the interaction between the molecules degraded and the material surface. The results demonstrated that the hydroxyls adsorbed on the SnO2 surface favor the formation of hydroxyl radicals, a species that indirectly participate in the photocatalytic oxidation of rhodamine B dye. The photoelectrocatalytic tests showed that the NPs treated at 200 ?C increased oxygen evolution reaction performance. MenosWe report herein a detailed study on the influence of hydrothermal treatment temperature on both long- and short-range structures of SnO2 nanoparticles (NPs) applied as photocatalysts for the discoloration of organic pollutants and as photoanodes for water splitting. Synchrotron X-ray diffraction and X-ray absorption near-edge spectroscopy measurements confirmed the enhancement of the structural order of SnO2 NPs as a function of hydrothermal temperature. Fourier transform infrared spectroscopy revealed that the hydrothermal treatment increased the amount of hydroxyl groups on the SnO2 NPs surface. Regarding the photocatalytic activity, the NPs were able to promote the discoloration of different dyes that can act as potential organic pollutants. The photoelectrocatalytic performance of the samples depended on the hydrothermal treatment temperature, with the degree of crystallinity and surface hydroxyl groups playing a significant role in their performance as photoanodes. In particular, the NPs treated at a higher temperature presented a better degree of crystallinity, in addition to many hydroxyls on their surface, leading to increased mobility of the photogenerated charge carriers and improving the interaction between the molecules degraded and the material surface. The results demonstrated that the hydroxyls adsorbed on the SnO2 surface favor the formation of hydroxyl radicals, a species that indirectly participate in the photocatalytic oxidation of rhodamine B dye. The ph... Mostrar Tudo |
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Palavras-Chave: |
Photoelectrocalysis; Synchrotron XRD; Water splitting; XANES. |
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Categoria do assunto: |
-- |
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Marc: |
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001 2154814
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022 $a0254-0584
024 7 $ahttps://doi.org/10.1016/j.matchemphys.2023.127989$2DOI
100 1 $aSILVA, G. T. S. T. da
245 $aLong-and short-range structure of SnO2 nanoparticles$bSynthesis and photo (electro)catalytic activity.$h[electronic resource]
260 $c2023
300 $a1 - 9
520 $aWe report herein a detailed study on the influence of hydrothermal treatment temperature on both long- and short-range structures of SnO2 nanoparticles (NPs) applied as photocatalysts for the discoloration of organic pollutants and as photoanodes for water splitting. Synchrotron X-ray diffraction and X-ray absorption near-edge spectroscopy measurements confirmed the enhancement of the structural order of SnO2 NPs as a function of hydrothermal temperature. Fourier transform infrared spectroscopy revealed that the hydrothermal treatment increased the amount of hydroxyl groups on the SnO2 NPs surface. Regarding the photocatalytic activity, the NPs were able to promote the discoloration of different dyes that can act as potential organic pollutants. The photoelectrocatalytic performance of the samples depended on the hydrothermal treatment temperature, with the degree of crystallinity and surface hydroxyl groups playing a significant role in their performance as photoanodes. In particular, the NPs treated at a higher temperature presented a better degree of crystallinity, in addition to many hydroxyls on their surface, leading to increased mobility of the photogenerated charge carriers and improving the interaction between the molecules degraded and the material surface. The results demonstrated that the hydroxyls adsorbed on the SnO2 surface favor the formation of hydroxyl radicals, a species that indirectly participate in the photocatalytic oxidation of rhodamine B dye. The photoelectrocatalytic tests showed that the NPs treated at 200 ?C increased oxygen evolution reaction performance.
653 $aPhotoelectrocalysis
653 $aSynchrotron XRD
653 $aWater splitting
653 $aXANES
700 1 $aLOPES, O. F.
700 1 $aCATTO, A. C.
700 1 $aPATROCÍNIO, A. O. T.
700 1 $aRODRIGUES, J. E. F. S.
700 1 $aMESQUITA, A.
700 1 $aRIBEIRO, C.
700 1 $aAVANSI JR, W.
700 1 $aSILVA, L. F. da
773 $tMaterials Chemistry and Physics$gv. 305, 127989, 2023.
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