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Registro Completo |
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Biblioteca(s): |
Embrapa Solos. |
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Data corrente: |
31/08/2018 |
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Data da última atualização: |
10/11/2021 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
BELTRAME, K. K.; SOUZA, A. M. de; COELHO, M. R.; WINKLER, T. C. B.; SOUZA, W. E.; VALDERRAMA, P. |
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Afiliação: |
KARLA K. BELTRAME, UTFPR; ANDRE MARCELO DE SOUZA, CNPS; MAURICIO RIZZATO COELHO, CNPS; THAYANE C. B. WINKLER; WYRLLEN E. SOUZA, UTFPR; PATRÍCIA VALDERRAMA, UTFPR. |
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Título: |
Soil organic carbon determination using NIRS: evaluation of dichromate oxidation and dry combustion analysis as reference methods in multivariate calibration. |
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Ano de publicação: |
2016 |
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Fonte/Imprenta: |
Journal of the Brazilian Chemical Society, v. 27, n. 9, p. 1527-1532, 2016. |
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DOI: |
http://dx.doi.org/10.5935/0103-5053.20160031 |
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Idioma: |
Inglês |
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Conteúdo: |
Dichromate oxidation and dry combustion analysis were evaluated as reference methods to determine organic carbon in Brazilian soils using near infrared spectroscopy (NIRS) as an alternative. The main objective of this study was to evaluate which of the reference methods could provide a calibration model with higher predictive ability. A total of 161 soil samples obtained from horizons in full profiles (Parque Estadual da Mata Seca, Minas Gerais State, Brazil) were used. Models were mean centered and built from partial least squares. The dichromate oxidation method presented a lower accuracy when compared to dry combustion analysis as reference for NIRS. Figures of merit such as sensitivity, analytical sensitivity, detection and quantification limits, adjust and linearity presented results very similar. A paired t-test was applied to the figures of merit results and with 95% confidence did not show significant differences between the two methods used as reference for NIRS. The non-parametric Mann Whitney test showed that the samples provided with the partial least squares (PLS) model when the reference method was the dichromate oxidation or dry combustion analysis come from the same population, indicating that the reference methods employed for multivariate calibration from NIRS provide the same results practically. |
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Thesagro: |
Análise do Solo; Carbono. |
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Thesaurus Nal: |
Soil analysis; Soil organic carbon. |
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Categoria do assunto: |
P Recursos Naturais, Ciências Ambientais e da Terra |
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URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/item/182275/1/2016-175.pdf
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Marc: |
LEADER 02163naa a2200241 a 4500
001 2094899
005 2021-11-10
008 2016 bl uuuu u00u1 u #d
024 7 $ahttp://dx.doi.org/10.5935/0103-5053.20160031$2DOI
100 1 $aBELTRAME, K. K.
245 $aSoil organic carbon determination using NIRS$bevaluation of dichromate oxidation and dry combustion analysis as reference methods in multivariate calibration.$h[electronic resource]
260 $c2016
520 $aDichromate oxidation and dry combustion analysis were evaluated as reference methods to determine organic carbon in Brazilian soils using near infrared spectroscopy (NIRS) as an alternative. The main objective of this study was to evaluate which of the reference methods could provide a calibration model with higher predictive ability. A total of 161 soil samples obtained from horizons in full profiles (Parque Estadual da Mata Seca, Minas Gerais State, Brazil) were used. Models were mean centered and built from partial least squares. The dichromate oxidation method presented a lower accuracy when compared to dry combustion analysis as reference for NIRS. Figures of merit such as sensitivity, analytical sensitivity, detection and quantification limits, adjust and linearity presented results very similar. A paired t-test was applied to the figures of merit results and with 95% confidence did not show significant differences between the two methods used as reference for NIRS. The non-parametric Mann Whitney test showed that the samples provided with the partial least squares (PLS) model when the reference method was the dichromate oxidation or dry combustion analysis come from the same population, indicating that the reference methods employed for multivariate calibration from NIRS provide the same results practically.
650 $aSoil analysis
650 $aSoil organic carbon
650 $aAnálise do Solo
650 $aCarbono
700 1 $aSOUZA, A. M. de
700 1 $aCOELHO, M. R.
700 1 $aWINKLER, T. C. B.
700 1 $aSOUZA, W. E.
700 1 $aVALDERRAMA, P.
773 $tJournal of the Brazilian Chemical Society$gv. 27, n. 9, p. 1527-1532, 2016.
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Registro original: |
Embrapa Solos (CNPS) |
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| Registros recuperados : 10 | |
| 3. |  | SANTOS, L. R. dos; ZANGIROLAMI, M. de S.; SILVA, N. O.; VALDERRAMA, P.; MARÇO, P. H. Rapid non-invasive assessment of quality parameters in ground soybean using near-infrared spectroscopy. Pesquisa Agropecuária Brasileira, Brasília, DF, v. 53, n. 1, p. 97-104, jan. 2018. Título em português: Avaliação rápida não invasiva de parâmetros de qualidade em soja triturada com uso de espectroscopia de infravermelho próximo.| Biblioteca(s): Embrapa Unidades Centrais. |
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| 5. | | BELTRAME, K. K.; SOUZA, A. M. de; COELHO, M. R.; WINKLER, T. C. B.; SOUZA, W. E.; VALDERRAMA, P. Soil organic carbon determination using NIRS: evaluation of dichromate oxidation and dry combustion analysis as reference methods in multivariate calibration. Journal of the Brazilian Chemical Society, v. 27, n. 9, p. 1527-1532, 2016.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 2 |
| Biblioteca(s): Embrapa Solos. |
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| 7. | | SOUZA, A. M. de; FILGUEIRAS, P. R.; COELHO, M. R.; FONTANA, A.; WINKLER, T. C. B.; VALDERRAMA, P.; POPPI, R. J. Validation of the near infrared spectroscopy method for determining soil organic carbon by employing a proficiency assay for fertility laboratories. Journal of Near Infrared Spectroscopy, v. 24, n. 3, p. 293-303, 2016.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 1 |
| Biblioteca(s): Embrapa Solos. |
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| 8. | | SOUZA, A. M. de; COELHO, M. R.; FONTANA, A.; WINKLER, T. C. B.; JUCÁ, N. M. C.; CASTRO, T. B. de; SHIMIDT, G. B.; VALDERRAMA, P.; POPPIA, R. J. Analytical validation of a multivariate calibration method for determination of soil organic carbon by near infrared spectroscopy. In: CHEMOMETRICS IN ANALYTICAL CHEMISTRY CONFERENCE, 2014, Richmond, VA. Resumo... Richmond, VA: Virginia Commonweath University, 2014. 1 p.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Solos. |
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| 9. | | BAQUETA, M. R.; VALDERRAMA, P.; MANDRONE, M.; POLI, F.; COQUEIRO, A.; COSTA-SANTOS, A. C.; REBELLATO. A. A.; LUZ, G. M.; ROCHA, R. B.; PALLONE, J. A. L.; MARINI, F. H NMR, FAAS, portable NIR, benchtop NIR, and ATR-FTIR-MIR spectroscopies for characterizing and discriminating new Brazilian Canephora coffees in a multi-block analysis perspective. Chemometrics and Intelligent Laboratory Systems, v. 240, 2023.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Rondônia. |
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| 10. | | FOLLMAN, H. D. M.; MARTINS, A. F.; NOBRE, T. M.; MELO, J. D. B.; CELLET, T. S. P.; VALDERRAMA, P.; CORREA, D. S.; MUNIZ, E. C.; OLIVEIRA JUNIOR, O. N. Extent of shielding by counterions determines the bactericidal activity of N,N,N,-trimethyl chitosan salts. Carbohydrate polymers, [S. l.], v. 137, p. 418-425, 2016.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Instrumentação. |
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| Registros recuperados : 10 | |
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