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| 2. |  | SOUZA, C. M. de. Globalização e desenvolvimento rural sustentável: como construir identidades e capital social nos espaço rurais do Semi-Árido nordestino? In: MENEZES, A. H. N.; ARAÚJO, C. R. de; SOUZA, C. M. de; OLIVEIRA, L. M. S. R. de; OLIVEIRA, L. S. de; PIRAUX, M.; RAMOS, P. R.; AZEVEDO, S. G. de. Formação de agentes de desenvolvimento sustentàvel: diálogos entre o fazer técnico e o saber humanista. Juazeiro, BA: Franciscana; Petrolina: Embrapa Semi-Árido: CIRAD: UNIVASF, 2007. cap. 3, p. 67-108| Biblioteca(s): Embrapa Semiárido. |
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 | Acesso ao texto completo restrito à biblioteca da Embrapa Meio Ambiente. Para informações adicionais entre em contato com cnpma.biblioteca@embrapa.br. |
Registro Completo
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Biblioteca(s): |
Embrapa Meio Ambiente. |
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Data corrente: |
28/11/2022 |
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Data da última atualização: |
28/11/2022 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Circulação/Nível: |
A - 1 |
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Autoria: |
BARIZON, R. R. M.; KUMMROW, F.; ALBUQUERQUE, A. F.; ASSALIN, M. R.; ROSA, M. A.; SOUZA, D. R. C. de; PAZIANOTTO, R. A. A. |
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Afiliação: |
ROBSON ROLLAND MONTICELLI BARIZON, CNPMA; FÁBIO KUMMROW, UNIVERSIDADE FEDERAL DE SÃO PAULO; ANJAINA FERNANDES DE ALBUQUERQUE, UNIVERSIDADE ESTADUAL DE CAMPINAS; MARCIA REGINA ASSALIN, CNPMA; MARIA APARECIDA ROSA, CNPMA; DEBORA RENATA CASSOLI DE S DUTRA, CNPMA; RICARDO ANTONIO ALMEIDA PAZIANOTTO, CNPMA. |
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Título: |
Surface water contamination from pesticide mixtures and risks to aquatic life in a high-input agricultural region of Brazil. |
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Ano de publicação: |
2022 |
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Fonte/Imprenta: |
Chemosphere, v. 308, pt. 3, article 136400, 2022. |
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Páginas: |
p. 1-10. |
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DOI: |
https://doi.org/10.1016/j.chemosphere.2022.136400 |
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Idioma: |
Inglês |
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Conteúdo: |
Abstract: The environmental risks of pesticides found in surface waters of an important agricultural basin in Brazil were estimated by adopting two approaches: individual pesticides risk quotients (RQ) and concentration addition model for pesticide mixtures (RQs) contained in each water sample. Monitoring was carried out in the Mogi Guaçu River basin, Brazil, from October 2017 to May 2018. Four sampling points were selected in the Mogi Guaçu River and seven in its tributaries A multiresidue method with solid-phase extraction and subsequent analysis by UPLC-ESI-QqQ-MS/MS was developed to quantify 19 pesticides. Herbicides, except for simazine, presented the highest detection frequencies with values above 70%. Tebuthiuron was found in all 55 analyzed samples, presenting the highest concentration (6437 ng L-1) over the monitoring period. Fungicides and insecticides showed similar detection frequency (DF) values, ranging from 1.8% to 21.8%. Tebuconazole and carbofuran were the fungicides and insecticides most frequently detected, respectively. January 2018 sampling showed the highest total concentration of pesticides, differing from March 2018 and May 2018 (p < 0.05). The MG2 > TMG8 > MG1 > TMG6 sites showed the highest concentration total of pesticides while MG4 > TMG4 > TMG3 (p < 0.05) sites showed the lowest values: MG4 > TMG4 > TMG3 (p < 0.05). Most pesticide occurrences presented no risks to aquatic organisms. Only 19 out of the 175 pesticide occurrences > LOQ presented individual risks to aquatic biota. Contrary to the results obtained by the individual risk assessment, most pesticide mixtures presented risks to aquatic biota. In 36 out of the 55 samples analyzed during monitoring, pesticide mixtures presented risks to aquatic life. MenosAbstract: The environmental risks of pesticides found in surface waters of an important agricultural basin in Brazil were estimated by adopting two approaches: individual pesticides risk quotients (RQ) and concentration addition model for pesticide mixtures (RQs) contained in each water sample. Monitoring was carried out in the Mogi Guaçu River basin, Brazil, from October 2017 to May 2018. Four sampling points were selected in the Mogi Guaçu River and seven in its tributaries A multiresidue method with solid-phase extraction and subsequent analysis by UPLC-ESI-QqQ-MS/MS was developed to quantify 19 pesticides. Herbicides, except for simazine, presented the highest detection frequencies with values above 70%. Tebuthiuron was found in all 55 analyzed samples, presenting the highest concentration (6437 ng L-1) over the monitoring period. Fungicides and insecticides showed similar detection frequency (DF) values, ranging from 1.8% to 21.8%. Tebuconazole and carbofuran were the fungicides and insecticides most frequently detected, respectively. January 2018 sampling showed the highest total concentration of pesticides, differing from March 2018 and May 2018 (p < 0.05). The MG2 > TMG8 > MG1 > TMG6 sites showed the highest concentration total of pesticides while MG4 > TMG4 > TMG3 (p < 0.05) sites showed the lowest values: MG4 > TMG4 > TMG3 (p < 0.05). Most pesticide occurrences presented no risks to aquatic organisms. Only 19 out of the 175 pesticide occurrences > LOQ presented ind... Mostrar Tudo |
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Palavras-Chave: |
Aquatic life; Multiple exposure. |
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Thesagro: |
Agrotóxico; Águas Superficiais; Análise de Risco; Fungicida; Herbicida; Poluição da Água; Resíduo Quimico. |
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Thesaurus NAL: |
Agrochemicals; Pesticide mixtures; Pesticide residues; Pesticides; Risk assessment; Water pollution. |
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Categoria do assunto: |
P Recursos Naturais, Ciências Ambientais e da Terra |
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Marc: |
LEADER 02975naa a2200397 a 4500
001 2148843
005 2022-11-28
008 2022 bl uuuu u00u1 u #d
024 7 $ahttps://doi.org/10.1016/j.chemosphere.2022.136400$2DOI
100 1 $aBARIZON, R. R. M.
245 $aSurface water contamination from pesticide mixtures and risks to aquatic life in a high-input agricultural region of Brazil.$h[electronic resource]
260 $c2022
300 $ap. 1-10.
520 $aAbstract: The environmental risks of pesticides found in surface waters of an important agricultural basin in Brazil were estimated by adopting two approaches: individual pesticides risk quotients (RQ) and concentration addition model for pesticide mixtures (RQs) contained in each water sample. Monitoring was carried out in the Mogi Guaçu River basin, Brazil, from October 2017 to May 2018. Four sampling points were selected in the Mogi Guaçu River and seven in its tributaries A multiresidue method with solid-phase extraction and subsequent analysis by UPLC-ESI-QqQ-MS/MS was developed to quantify 19 pesticides. Herbicides, except for simazine, presented the highest detection frequencies with values above 70%. Tebuthiuron was found in all 55 analyzed samples, presenting the highest concentration (6437 ng L-1) over the monitoring period. Fungicides and insecticides showed similar detection frequency (DF) values, ranging from 1.8% to 21.8%. Tebuconazole and carbofuran were the fungicides and insecticides most frequently detected, respectively. January 2018 sampling showed the highest total concentration of pesticides, differing from March 2018 and May 2018 (p < 0.05). The MG2 > TMG8 > MG1 > TMG6 sites showed the highest concentration total of pesticides while MG4 > TMG4 > TMG3 (p < 0.05) sites showed the lowest values: MG4 > TMG4 > TMG3 (p < 0.05). Most pesticide occurrences presented no risks to aquatic organisms. Only 19 out of the 175 pesticide occurrences > LOQ presented individual risks to aquatic biota. Contrary to the results obtained by the individual risk assessment, most pesticide mixtures presented risks to aquatic biota. In 36 out of the 55 samples analyzed during monitoring, pesticide mixtures presented risks to aquatic life.
650 $aAgrochemicals
650 $aPesticide mixtures
650 $aPesticide residues
650 $aPesticides
650 $aRisk assessment
650 $aWater pollution
650 $aAgrotóxico
650 $aÁguas Superficiais
650 $aAnálise de Risco
650 $aFungicida
650 $aHerbicida
650 $aPoluição da Água
650 $aResíduo Quimico
653 $aAquatic life
653 $aMultiple exposure
700 1 $aKUMMROW, F.
700 1 $aALBUQUERQUE, A. F.
700 1 $aASSALIN, M. R.
700 1 $aROSA, M. A.
700 1 $aSOUZA, D. R. C. de
700 1 $aPAZIANOTTO, R. A. A.
773 $tChemosphere$gv. 308, pt. 3, article 136400, 2022.
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