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 | Acesso ao texto completo restrito à biblioteca da Embrapa Instrumentação. Para informações adicionais entre em contato com cnpdia.biblioteca@embrapa.br. |
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
05/07/2023 |
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Data da última atualização: |
05/07/2023 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
SILVA, G. T. S. T. da; LOPES, O. F.; CATTO, A. C.; PATROCÍNIO, A. O. T.; RODRIGUES, J. E. F. S.; MESQUITA, A.; RIBEIRO, C.; AVANSI JR, W.; SILVA, L. F. da. |
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Afiliação: |
CAUE RIBEIRO DE OLIVEIRA, CNPDIA. |
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Título: |
Long-and short-range structure of SnO2 nanoparticles: Synthesis and photo (electro)catalytic activity. |
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Ano de publicação: |
2023 |
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Fonte/Imprenta: |
Materials Chemistry and Physics, v. 305, 127989, 2023. |
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Páginas: |
1 - 9 |
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ISSN: |
0254-0584 |
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DOI: |
https://doi.org/10.1016/j.matchemphys.2023.127989 |
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Idioma: |
Inglês |
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Conteúdo: |
We report herein a detailed study on the influence of hydrothermal treatment temperature on both long- and short-range structures of SnO2 nanoparticles (NPs) applied as photocatalysts for the discoloration of organic pollutants and as photoanodes for water splitting. Synchrotron X-ray diffraction and X-ray absorption near-edge spectroscopy measurements confirmed the enhancement of the structural order of SnO2 NPs as a function of hydrothermal temperature. Fourier transform infrared spectroscopy revealed that the hydrothermal treatment increased the amount of hydroxyl groups on the SnO2 NPs surface. Regarding the photocatalytic activity, the NPs were able to promote the discoloration of different dyes that can act as potential organic pollutants. The photoelectrocatalytic performance of the samples depended on the hydrothermal treatment temperature, with the degree of crystallinity and surface hydroxyl groups playing a significant role in their performance as photoanodes. In particular, the NPs treated at a higher temperature presented a better degree of crystallinity, in addition to many hydroxyls on their surface, leading to increased mobility of the photogenerated charge carriers and improving the interaction between the molecules degraded and the material surface. The results demonstrated that the hydroxyls adsorbed on the SnO2 surface favor the formation of hydroxyl radicals, a species that indirectly participate in the photocatalytic oxidation of rhodamine B dye. The photoelectrocatalytic tests showed that the NPs treated at 200 ?C increased oxygen evolution reaction performance. MenosWe report herein a detailed study on the influence of hydrothermal treatment temperature on both long- and short-range structures of SnO2 nanoparticles (NPs) applied as photocatalysts for the discoloration of organic pollutants and as photoanodes for water splitting. Synchrotron X-ray diffraction and X-ray absorption near-edge spectroscopy measurements confirmed the enhancement of the structural order of SnO2 NPs as a function of hydrothermal temperature. Fourier transform infrared spectroscopy revealed that the hydrothermal treatment increased the amount of hydroxyl groups on the SnO2 NPs surface. Regarding the photocatalytic activity, the NPs were able to promote the discoloration of different dyes that can act as potential organic pollutants. The photoelectrocatalytic performance of the samples depended on the hydrothermal treatment temperature, with the degree of crystallinity and surface hydroxyl groups playing a significant role in their performance as photoanodes. In particular, the NPs treated at a higher temperature presented a better degree of crystallinity, in addition to many hydroxyls on their surface, leading to increased mobility of the photogenerated charge carriers and improving the interaction between the molecules degraded and the material surface. The results demonstrated that the hydroxyls adsorbed on the SnO2 surface favor the formation of hydroxyl radicals, a species that indirectly participate in the photocatalytic oxidation of rhodamine B dye. The ph... Mostrar Tudo |
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Palavras-Chave: |
Photoelectrocalysis; Synchrotron XRD; Water splitting; XANES. |
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Categoria do assunto: |
-- |
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Marc: |
LEADER 02517naa a2200301 a 4500
001 2154814
005 2023-07-05
008 2023 bl uuuu u00u1 u #d
022 $a0254-0584
024 7 $ahttps://doi.org/10.1016/j.matchemphys.2023.127989$2DOI
100 1 $aSILVA, G. T. S. T. da
245 $aLong-and short-range structure of SnO2 nanoparticles$bSynthesis and photo (electro)catalytic activity.$h[electronic resource]
260 $c2023
300 $a1 - 9
520 $aWe report herein a detailed study on the influence of hydrothermal treatment temperature on both long- and short-range structures of SnO2 nanoparticles (NPs) applied as photocatalysts for the discoloration of organic pollutants and as photoanodes for water splitting. Synchrotron X-ray diffraction and X-ray absorption near-edge spectroscopy measurements confirmed the enhancement of the structural order of SnO2 NPs as a function of hydrothermal temperature. Fourier transform infrared spectroscopy revealed that the hydrothermal treatment increased the amount of hydroxyl groups on the SnO2 NPs surface. Regarding the photocatalytic activity, the NPs were able to promote the discoloration of different dyes that can act as potential organic pollutants. The photoelectrocatalytic performance of the samples depended on the hydrothermal treatment temperature, with the degree of crystallinity and surface hydroxyl groups playing a significant role in their performance as photoanodes. In particular, the NPs treated at a higher temperature presented a better degree of crystallinity, in addition to many hydroxyls on their surface, leading to increased mobility of the photogenerated charge carriers and improving the interaction between the molecules degraded and the material surface. The results demonstrated that the hydroxyls adsorbed on the SnO2 surface favor the formation of hydroxyl radicals, a species that indirectly participate in the photocatalytic oxidation of rhodamine B dye. The photoelectrocatalytic tests showed that the NPs treated at 200 ?C increased oxygen evolution reaction performance.
653 $aPhotoelectrocalysis
653 $aSynchrotron XRD
653 $aWater splitting
653 $aXANES
700 1 $aLOPES, O. F.
700 1 $aCATTO, A. C.
700 1 $aPATROCÍNIO, A. O. T.
700 1 $aRODRIGUES, J. E. F. S.
700 1 $aMESQUITA, A.
700 1 $aRIBEIRO, C.
700 1 $aAVANSI JR, W.
700 1 $aSILVA, L. F. da
773 $tMaterials Chemistry and Physics$gv. 305, 127989, 2023.
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Registro original: |
Embrapa Instrumentação (CNPDIA) |
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| Acesso ao texto completo restrito à biblioteca da Embrapa Gado de Corte. Para informações adicionais entre em contato com cnpgc.biblioteca@embrapa.br. |
Registro Completo
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Biblioteca(s): |
Embrapa Gado de Corte. |
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Data corrente: |
18/01/2012 |
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Data da última atualização: |
18/01/2012 |
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Tipo da produção científica: |
Resumo em Anais de Congresso |
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Autoria: |
ANDRADE, M. L. M.; EUCLIDES, V. P. B.; MONTAGNER, D. B.; NANTES, N. N.; ZIMMER, K. A.; ECHEVERRIA, D. M. S. |
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Afiliação: |
MÁRCIA LUANE MARQUES ANDRADE, Graduando em Zootecnia – FESAR; VALERIA PACHECO BATISTA EUCLIDES, CNPGC; DENISE BAPTAGLIN MONTAGNER, CNPGC; Bolsista de Apoio Técnico – CNPq.; Bolsista de Apoio Técnico – CNPq.; Universidade Federal da Grande Dourados – Bolsista Capes. |
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Título: |
Características estruturais do dossel de capim-piatã sob lotação contínua |
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Ano de publicação: |
2011 |
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Fonte/Imprenta: |
In: JORNADA CIENTÍFICA EMBRAPA GADO DE CORTE, 7., 2011, CAMPO GRANDE, MS. [Anais da]... Campo Grande, MS: Embrapa Gado de Corte, 2011. |
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Idioma: |
Português |
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Conteúdo: |
O objetivo deste trabalho foi avaliar a massa de forragem total de capim-piatã durante as estações do ano. |
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Palavras-Chave: |
Capim-piatã. |
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Thesagro: |
Outono; Primavera; Verão. |
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Categoria do assunto: |
-- |
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Marc: |
LEADER 00839naa a2200229 a 4500
001 1912868
005 2012-01-18
008 2011 bl uuuu u00u1 u #d
100 1 $aANDRADE, M. L. M.
245 $aCaracterísticas estruturais do dossel de capim-piatã sob lotação contínua$h[electronic resource]
260 $c2011
520 $aO objetivo deste trabalho foi avaliar a massa de forragem total de capim-piatã durante as estações do ano.
650 $aOutono
650 $aPrimavera
650 $aVerão
653 $aCapim-piatã
700 1 $aEUCLIDES, V. P. B.
700 1 $aMONTAGNER, D. B.
700 1 $aNANTES, N. N.
700 1 $aZIMMER, K. A.
700 1 $aECHEVERRIA, D. M. S.
773 $tIn: JORNADA CIENTÍFICA EMBRAPA GADO DE CORTE, 7., 2011, CAMPO GRANDE, MS. [Anais da]... Campo Grande, MS: Embrapa Gado de Corte, 2011.
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