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Registro Completo |
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
20/04/2023 |
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Data da última atualização: |
20/04/2023 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
GEOVO, J. D. C.; TORRES, J. A.; GIROTO, A. S.; ROCHA, F. C. N.; GARCIA, M. M.; SILVA, G. T. S. T.; SOUZA, J. R. C.; OLIVEIRA, J. A. de; RIBEIRO, C.; NOGUEIRA, A. E. |
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Afiliação: |
CAUE RIBEIRO DE OLIVEIRA, CNPDIA. |
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Título: |
Evaluation of the activity and selectivity of mesoporous composites of MCM-41 and CuO in the CO2 photoreduction process. |
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Ano de publicação: |
2023 |
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Fonte/Imprenta: |
Journal of Photochemistry & Photobiology, A: Chemistry, v. 439, 114631, 2023. |
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ISSN: |
1010-6030 |
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DOI: |
https://doi.org/10.1016/j.jphotochem.2023.114631 |
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Idioma: |
Inglês |
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Conteúdo: |
The conversion of CO2 into valuable chemical feedstock through photocatalysis is considered an effective strategy to mitigate global warming and energy supply problems. Among the challenges for CO2 photoreduction are the design and synthesis of active photocatalysts with high affinity for the CO2 molecule and suitable reduction potentials of valence and conduction bands to promote the reduction of the CO2 molecule. Molecular sieves (MCM-41) with semiconductors, such as copper oxide, are alternatives to the traditional semiconductors (TiO2 and ZnO) with high CO2 adsorption capacity, high specific surface area, and good stability, making them perfect candidates for photocatalysis. Therefore, in this work, mesoporous composite materials based on MCM-41 and CuO were synthesized via the impregnation method. The synthesized materials were chemically, structurally, and morphologically characterized by XRD, SEM, FTIR, XPS, DRS, N2 adsorption and desorption, and atomic absorption spectroscopy techniques, and the photocatalytic activity in the reduction of CO2 was evaluated under visible radiation. We show that MCM-41 and the composite MCM-41/CuO have significant potential for use in the CO2 photoreduction process, where the composition and different active sites in the photocatalysts play an important role in the activity and selectivity of the products formed. The results showed that the MCM-41 and the composite with 1 % (w/w%) CuO presented high selectivity and production of methanol, with 585.88 and 267.05 μmol.gcatalyst -1 , respectively. Thus, the findings demonstrated the versatility of the MCM-41 to form composites with semiconductors, as well as the need to comprehend the main aspects that influence CO2 photoreduction activities and the selectivity of the composites, including their surface, structural, and electrical features. MenosThe conversion of CO2 into valuable chemical feedstock through photocatalysis is considered an effective strategy to mitigate global warming and energy supply problems. Among the challenges for CO2 photoreduction are the design and synthesis of active photocatalysts with high affinity for the CO2 molecule and suitable reduction potentials of valence and conduction bands to promote the reduction of the CO2 molecule. Molecular sieves (MCM-41) with semiconductors, such as copper oxide, are alternatives to the traditional semiconductors (TiO2 and ZnO) with high CO2 adsorption capacity, high specific surface area, and good stability, making them perfect candidates for photocatalysis. Therefore, in this work, mesoporous composite materials based on MCM-41 and CuO were synthesized via the impregnation method. The synthesized materials were chemically, structurally, and morphologically characterized by XRD, SEM, FTIR, XPS, DRS, N2 adsorption and desorption, and atomic absorption spectroscopy techniques, and the photocatalytic activity in the reduction of CO2 was evaluated under visible radiation. We show that MCM-41 and the composite MCM-41/CuO have significant potential for use in the CO2 photoreduction process, where the composition and different active sites in the photocatalysts play an important role in the activity and selectivity of the products formed. The results showed that the MCM-41 and the composite with 1 % (w/w%) CuO presented high selectivity and production of methan... Mostrar Tudo |
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Palavras-Chave: |
Artificial photosynthesis; CO2 photoreduction; Mechanism; Molecular sieves. |
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Categoria do assunto: |
-- |
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Marc: |
LEADER 02825naa a2200301 a 4500
001 2153292
005 2023-04-20
008 2023 bl uuuu u00u1 u #d
022 $a1010-6030
024 7 $ahttps://doi.org/10.1016/j.jphotochem.2023.114631$2DOI
100 1 $aGEOVO, J. D. C.
245 $aEvaluation of the activity and selectivity of mesoporous composites of MCM-41 and CuO in the CO2 photoreduction process.$h[electronic resource]
260 $c2023
520 $aThe conversion of CO2 into valuable chemical feedstock through photocatalysis is considered an effective strategy to mitigate global warming and energy supply problems. Among the challenges for CO2 photoreduction are the design and synthesis of active photocatalysts with high affinity for the CO2 molecule and suitable reduction potentials of valence and conduction bands to promote the reduction of the CO2 molecule. Molecular sieves (MCM-41) with semiconductors, such as copper oxide, are alternatives to the traditional semiconductors (TiO2 and ZnO) with high CO2 adsorption capacity, high specific surface area, and good stability, making them perfect candidates for photocatalysis. Therefore, in this work, mesoporous composite materials based on MCM-41 and CuO were synthesized via the impregnation method. The synthesized materials were chemically, structurally, and morphologically characterized by XRD, SEM, FTIR, XPS, DRS, N2 adsorption and desorption, and atomic absorption spectroscopy techniques, and the photocatalytic activity in the reduction of CO2 was evaluated under visible radiation. We show that MCM-41 and the composite MCM-41/CuO have significant potential for use in the CO2 photoreduction process, where the composition and different active sites in the photocatalysts play an important role in the activity and selectivity of the products formed. The results showed that the MCM-41 and the composite with 1 % (w/w%) CuO presented high selectivity and production of methanol, with 585.88 and 267.05 μmol.gcatalyst -1 , respectively. Thus, the findings demonstrated the versatility of the MCM-41 to form composites with semiconductors, as well as the need to comprehend the main aspects that influence CO2 photoreduction activities and the selectivity of the composites, including their surface, structural, and electrical features.
653 $aArtificial photosynthesis
653 $aCO2 photoreduction
653 $aMechanism
653 $aMolecular sieves
700 1 $aTORRES, J. A.
700 1 $aGIROTO, A. S.
700 1 $aROCHA, F. C. N.
700 1 $aGARCIA, M. M.
700 1 $aSILVA, G. T. S. T.
700 1 $aSOUZA, J. R. C.
700 1 $aOLIVEIRA, J. A. de
700 1 $aRIBEIRO, C.
700 1 $aNOGUEIRA, A. E.
773 $tJournal of Photochemistry & Photobiology, A: Chemistry$gv. 439, 114631, 2023.
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Embrapa Instrumentação (CNPDIA) |
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| Registros recuperados : 66 | |
| 5. |  | JUSTINO, G. C.; CAMBRAIA, J.; OLIVA, M. A.; OLIVEIRA, J. A. de. Absorção e redução de nitrato em duas cultivares de arroz na presença de alumínio. Pesquisa Agropecuária Brasileira, Brasília, DF, v. 41, n. 8, p. 1285-1290, ago. 2006 Título em inglês: Uptake and reduction of nitrate in two rice cultivars in the presence of aluminum.| Biblioteca(s): Embrapa Unidades Centrais. |
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| 6. | | MENDONÇA, R. J. de; CAMBRAIA, J.; OLIVA, M. A.; OLIVEIRA, J. A. de. Capacidade de cultivares de arroz de modificar o pH de soluções nutritivas na presença de alumínio. Pesquisa Agropecuária Brasileira, Brasília, DF, v. 40, n. 5, p. 447-452, maio 2005 Título em inglês: Rice cultivars ability to change nutrient solution pH in the presence of aluminum.| Biblioteca(s): Embrapa Unidades Centrais. |
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| 9. | | ALVES, R. M. M.; CAMBRAIA, J.; CANO, M. A. O.; OLIVEIRA, J. A. de. Exsudação de ácidos orgânicos por dois cultivares de arroz (Oryza sativa L.), submetidos a níveis tóxicos de alumínio. In: CONGRESSO BRASILEIRO DE FISIOLOGIA VEGETAL, 10.; CONGRESSO LATINO AMERICANO DE FISIOLOGIA VEGETAL, 12., 2005, Recife. Anais... Recife: SBFV, 2005. 1 CD-ROM.| Tipo: Artigo em Anais de Congresso |
| Biblioteca(s): Embrapa Amapá. |
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| 10. | | MENDONÇA, R. J. de; CAMBRAIA, J.; OLIVEIRA, J. A. de; OLIVA, M. A. Efeito do alumínio na absorção e na utilização de macronutrientes em duas cultivares de arroz. Pesquisa Agropecuária Brasileira, Brasília, DF, v. 38, n. 7, p. 843-848, jul. 2003 Título em inglês: Aluminum effects on the uptake and utilization of macronutrients in two rice cultivars.| Biblioteca(s): Embrapa Unidades Centrais. |
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| 11. | | ALVES, R. M. M.; CAMBRAIA, J.; CANO, M. A. O.; OLIVEIRA, J. A. de; RIBEIRO, C. Efeito do alumínio sobre a produção de ácidos orgânicos em dois cultivares de arroz (Oryza sativa L.). In: CONGRESSO BRASILEIRO DE FISIOLOGIA VEGETAL, 10.; CONGRESSO LATINO AMERICANO DE FISIOLOGIA VEGETAL, 12., 2005, Recife. Anais... Recife: SBFV, 2005. 1 CD-ROM.| Tipo: Artigo em Anais de Congresso |
| Biblioteca(s): Embrapa Amapá. |
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| 12. | | SILVEIRA, F. T.; MORO, J. R.; SILVA, H. P. da; OLIVEIRA, J. A. de; PERECIN, D. Herança da resistência ao enfezamento em milho. Pesquisa Agropecuária Brasileira, Brasília, DF, v. 43, n. 12, p. 1717-1723, dez. 2008. Título em inglês: Inheritance of the resistance to corn stunt.| Biblioteca(s): Embrapa Unidades Centrais. |
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| 16. | | CASTRO, I. A. de; OLIVEIRA, J. A. de; PARIS, E. C.; GIRALDI, T. R.; RIBEIRO, C. Production of heterostructured TiO2/WO3 nanoparticulated photocatalysts through a simple one pot method. Ceramics international, [S. l.], v. 41, n. 3, p. 3502-3510, 2015.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Instrumentação. |
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| Registros recuperados : 66 | |
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| Nenhum registro encontrado para a expressão de busca informada. |
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