|
|
| Acesso ao texto completo restrito à biblioteca da Embrapa Florestas. Para informações adicionais entre em contato com cnpf.biblioteca@embrapa.br. |
Registro Completo |
Biblioteca(s): |
Embrapa Florestas. |
Data corrente: |
12/09/2019 |
Data da última atualização: |
03/10/2019 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Autoria: |
LAZZAROTTO, M.; NACHTIGALL, F. F.; SIQUEIRA, G. L. de A. de; LAZZAROTTO, S. R. da S.; LAZZAROTTO, M. |
Afiliação: |
Márcio Lazzarotto, UFRGS; Francine Furtado Nachtigall, Inmetro SUR-RS; Geisa Liandra de Andrade de Siqueira, Mestranda da UEPG; Simone Rosa da Silveira Lazzarotto, Doutoranda da UEPG; MARCELO LAZZAROTTO, CNPF. |
Título: |
Thermal analysis of salts from 4-nitrophenol and aliphatic amines. |
Ano de publicação: |
2019 |
Fonte/Imprenta: |
Journal of Thermal Analysis and Calorimetry, v. 138, n. 1, p. 351-357, Oct. 2019. |
DOI: |
10.1007/s10973-019-08205-9 |
Idioma: |
Inglês |
Conteúdo: |
Solid samples obtained from 4-nitrophenol and aliphatic amines, in excess of amine, were submitted to thermal analysis. The TGA/DTA showed two endothermic events, with exception of tert-butylamine, which showed three endothermic peaks. The first event was the melting of the ionic salt, which temperature does not follow a pattern, and is maxim for ethylammonium minimal for butylammonium salt. For methylammonium and ethylammonium, the fusion is followed by mass loss corresponding to one amine by 4-nitrophenol, while for the others ammonium salts, this event marks the beginning of the mass variation, that is maintained until the decomposition of the 4-nitrophenol at 485 K. The temperature of the event depends of the length of the chain of the amine, while the second occurs at the same temperature for all amines. |
Palavras-Chave: |
x. |
Categoria do assunto: |
X Pesquisa, Tecnologia e Engenharia |
Marc: |
LEADER 01427naa a2200193 a 4500 001 2112147 005 2019-10-03 008 2019 bl uuuu u00u1 u #d 024 7 $a10.1007/s10973-019-08205-9$2DOI 100 1 $aLAZZAROTTO, M. 245 $aThermal analysis of salts from 4-nitrophenol and aliphatic amines.$h[electronic resource] 260 $c2019 520 $aSolid samples obtained from 4-nitrophenol and aliphatic amines, in excess of amine, were submitted to thermal analysis. The TGA/DTA showed two endothermic events, with exception of tert-butylamine, which showed three endothermic peaks. The first event was the melting of the ionic salt, which temperature does not follow a pattern, and is maxim for ethylammonium minimal for butylammonium salt. For methylammonium and ethylammonium, the fusion is followed by mass loss corresponding to one amine by 4-nitrophenol, while for the others ammonium salts, this event marks the beginning of the mass variation, that is maintained until the decomposition of the 4-nitrophenol at 485 K. The temperature of the event depends of the length of the chain of the amine, while the second occurs at the same temperature for all amines. 653 $ax 700 1 $aNACHTIGALL, F. F. 700 1 $aSIQUEIRA, G. L. de A. de 700 1 $aLAZZAROTTO, S. R. da S. 700 1 $aLAZZAROTTO, M. 773 $tJournal of Thermal Analysis and Calorimetry$gv. 138, n. 1, p. 351-357, Oct. 2019.
Download
Esconder MarcMostrar Marc Completo |
Registro original: |
Embrapa Florestas (CNPF) |
|
Biblioteca |
ID |
Origem |
Tipo/Formato |
Classificação |
Cutter |
Registro |
Volume |
Status |
URL |
Voltar
|
|
| Acesso ao texto completo restrito à biblioteca da Embrapa Instrumentação. Para informações adicionais entre em contato com cnpdia.biblioteca@embrapa.br. |
Registro Completo
Biblioteca(s): |
Embrapa Instrumentação. |
Data corrente: |
23/11/2022 |
Data da última atualização: |
23/11/2022 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Circulação/Nível: |
A - 1 |
Autoria: |
VALLE, S. F.; GIROTO, A. S.; KLAIC, R.; BEVILAQUA, D.; RIBEIRO, C. |
Afiliação: |
CAUE RIBEIRO DE OLIVEIRA, CNPDIA. |
Título: |
Co-application of porous polysulfde pellets with acidithiobacillus thiooxidans improves sulfate availability in soil. |
Ano de publicação: |
2022 |
Fonte/Imprenta: |
Journal of Polymers and the Environment, v. 30, 2022. |
Páginas: |
4571?4579 |
DOI: |
https://doi.org/10.1007/s10924-022-02520-3 |
Idioma: |
Inglês |
Conteúdo: |
Sulfur (S) fertilization is necessary to overcome the low availability of this essential nutrient in agricultural soils. Although elemental sulfur (S8) pellets are often used, they tend to be poorly efective due to their low oxidation rate to sulfate, the form assimilated by plants. Here we designed highly porous polysulfde pellets (PolyS-porous) as S fertilizers with higher surface area for oxidation, aiming to improve sulfate delivery. A porosity of nearly 50% was achieved via inverse vulcanization of soybean oil and S8 in the presence of a salt porogen. A culture medium test with S-oxidizing bacterium Acidithiobacillus thiooxidans revealed PolyS-porous had a faster initial oxidation than S8-pellet, reaching respectively 57% and 20% at the end of 10 days. Sulfate released from PolyS-porous in soil was 3 times higher than from S8-pellet in 30 days, and PolyS-porous co-application with A. thiooxidans achieved twice as much. Overall, the results from this study demonstrated the potential of porous polysulfde pellets as sulfur fertilizers with improved efciency, especially when combined with A. thiooxidans. |
Palavras-Chave: |
Macronutrient; Salt porogen. |
Categoria do assunto: |
-- |
Marc: |
LEADER 01801naa a2200217 a 4500 001 2148641 005 2022-11-23 008 2022 bl uuuu u00u1 u #d 024 7 $ahttps://doi.org/10.1007/s10924-022-02520-3$2DOI 100 1 $aVALLE, S. F. 245 $aCo-application of porous polysulfde pellets with acidithiobacillus thiooxidans improves sulfate availability in soil.$h[electronic resource] 260 $c2022 300 $a4571?4579 520 $aSulfur (S) fertilization is necessary to overcome the low availability of this essential nutrient in agricultural soils. Although elemental sulfur (S8) pellets are often used, they tend to be poorly efective due to their low oxidation rate to sulfate, the form assimilated by plants. Here we designed highly porous polysulfde pellets (PolyS-porous) as S fertilizers with higher surface area for oxidation, aiming to improve sulfate delivery. A porosity of nearly 50% was achieved via inverse vulcanization of soybean oil and S8 in the presence of a salt porogen. A culture medium test with S-oxidizing bacterium Acidithiobacillus thiooxidans revealed PolyS-porous had a faster initial oxidation than S8-pellet, reaching respectively 57% and 20% at the end of 10 days. Sulfate released from PolyS-porous in soil was 3 times higher than from S8-pellet in 30 days, and PolyS-porous co-application with A. thiooxidans achieved twice as much. Overall, the results from this study demonstrated the potential of porous polysulfde pellets as sulfur fertilizers with improved efciency, especially when combined with A. thiooxidans. 653 $aMacronutrient 653 $aSalt porogen 700 1 $aGIROTO, A. S. 700 1 $aKLAIC, R. 700 1 $aBEVILAQUA, D. 700 1 $aRIBEIRO, C. 773 $tJournal of Polymers and the Environment$gv. 30, 2022.
Download
Esconder MarcMostrar Marc Completo |
Registro original: |
Embrapa Instrumentação (CNPDIA) |
|
Biblioteca |
ID |
Origem |
Tipo/Formato |
Classificação |
Cutter |
Registro |
Volume |
Status |
Fechar
|
Expressão de busca inválida. Verifique!!! |
|
|